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Nanostructure and Magnetic Field Ordering in Aqueous Fe3O4 Ferrofluids: A Small-Angle Neutron Scattering Study

Atom Indonesia · Vol. 45 No. 3 (2019) · hlm. 165–172

DOI
10.17146/aij.2019.744
ISSN
2356-5322, 0126-1568
Terbit
2019-12-11
Penerbit
National Research and Innovation Agency
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-nc-sa/4.0

Abstrak

Despite the importance of reducing production costs, investigating the hierarchical nanostructure and magnetic field ordering of Fe3O4 ferrofluids is also important to improve its application performance. Therefore, we proposed an inexpensive synthesis method in producing the Fe3O4 ferrofluids and investigated their detailed nanostructure as the effect of liquid carrier composition as well as their magnetic field ordering. In the present work, the Fe3O4 ferrofluids were successfully prepared through a coprecipitation route using a central precursor of natural Fe3O4 from iron sand. The nanostructural behaviors of the Fe3O4 ferrofluids, as the effects of the dilution of the Fe3O4 particles with H2O as a carrier liquid, were examined using a small-angle neutron spectrometer (SANS). The Fe3O4 nanopowders were also prepared for comparison. A single lognormal spherical distribution and a mass fractal model were applied to fit the neutron scattering data of the Fe3O4 ferrofluids. The increasing carrier liquid composition of the fluids during dilution process was able to reduce the fractal dimension and led to a shorter length of aggregation chains. However, it did not change the size of the primary particles or building block (approximately 3.8 nm) of the Fe3O4 particles. The neutron scattering of the Fe3O4 ferrofluids under an external magnetic field in the range of 0 to 1 T exhibited in a standard way of anisotropic phenomenon originating from the nanostructural ordering of the Fe3O4 particles. On the other hand, the Fe3O4 powders did not show anisotropic scattering under an external field in the same range. Furthermore, the magnetization curve of the Fe3O4 ferrofluids and nanopowders exhibited a proper superparamagnetic character at room temperature with the respective saturation magnetization of 4.4 emu/g and 34.7 emu/g.

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  • State University of Malang
  • National Nuclear Energy Agency of Indonesia
  • Universitas Gadjah Mada
  • Institut Teknologi Sepuluh Nopember
  • Universitas Islam Negeri Maulana Malik Ibrahim
  • Lambung Mangkurat University
  • The University of Tokyo
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Rekan penulisOrganisasiArtikel bersama
Sutopo SutopoState University of Malang2
Maria Christina PrihatiningsihNational Nuclear Energy Agency of Indonesia2
Arum PatriatiNational Nuclear Energy Agency of Indonesia2
Siriwat SoontaranonSynchrotron Light Research Institute2
E. SantosoNational Nuclear Energy Agency of Indonesia2
Sri Rahayu LestariState University of Malang2
Dewi Sekar MiasihState University of Malang2
Alif Rosyidah El BarorohState University of Malang2
Soni PrayogiUniversitas Pertamina2
Yoyok CahyonoInstitut Teknologi Sepuluh Nopember2
Hendra SusantoState University of Malang2
Tsania Nur DiyanaState University of Malang1
Wildana WargadinataUniversitas Islam Negeri Maulana Malik Ibrahim1
Abdul RohmanUniversitas Islam Negeri Maulana Malik Ibrahim1
Ali MaksumUniversity of Brawijaya1
Supriyono Koes HandayantoState University of Malang1
Muhammad Iqbal SamanState University of Malang1
Samsul HadiLambung Mangkurat University1
Suryajaya SuryajayaLambung Mangkurat University1
I. WijayaNational Nuclear Energy Agency of Indonesia1
A. RahmandariNational Nuclear Energy Agency of Indonesia1
Imam PrasetyoUniversitas Gadjah Mada1
A.I.W.S. RamadaniNational Nuclear Energy Agency of Indonesia1
Niken Siwi PamungkasChulalongkorn University1
N.A. PutrisetyaNational Nuclear Energy Agency of Indonesia1
Mellya PermatasariUniversitas Gadjah Mada1
A.A. NugrohoUniversitas Gadjah Mada1
S. SuyantaUniversitas Gadjah Mada1
Bharoto BharotoNational Nuclear Energy Agency of Indonesia1
Nadi SuparnoNational Nuclear Energy Agency of Indonesia1
Sairun SairunNational Nuclear Energy Agency of Indonesia1

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Sumber metadata: OAI-PMH (metadata jurnal) https://atomindonesia.brin.go.id/index.php/aij/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en-US">Nanostructure and Magnetic Field Ordering in Aqueous Fe3O4 Ferrofluids: A Small-Angle Neutron Scattering Study</dc:title>
	<dc:creator>Taufiq, A.</dc:creator>
	<dc:creator>Sunaryono, S</dc:creator>
	<dc:creator>Hidayat, N.</dc:creator>
	<dc:creator>Putra, E.G.R</dc:creator>
	<dc:creator>Okazawa, A.</dc:creator>
	<dc:creator>Watanabe, I.</dc:creator>
	<dc:creator>Kojima, N.</dc:creator>
	<dc:creator>Pratapa, S.</dc:creator>
	<dc:creator>Darminto, D.</dc:creator>
	<dc:subject xml:lang="en-US">Ferrofluid; Fe3O4; SANS; Nanostructure;  Ordering; Superparamagnetic.</dc:subject>
	<dc:description xml:lang="en-US">Despite the importance of reducing production costs, investigating the hierarchical nanostructure and magnetic field ordering of Fe3O4 ferrofluids is also important to improve its application performance. Therefore, we proposed an inexpensive synthesis method in producing the Fe3O4 ferrofluids and investigated their detailed nanostructure as the effect of liquid carrier composition as well as their magnetic field ordering. In the present work, the Fe3O4 ferrofluids were successfully prepared through a coprecipitation route using a central precursor of natural Fe3O4 from iron sand. The nanostructural behaviors of the Fe3O4 ferrofluids, as the effects of the dilution of the Fe3O4 particles with H2O as a carrier liquid, were examined using a small-angle neutron spectrometer (SANS). The Fe3O4 nanopowders were also prepared for comparison. A single lognormal spherical distribution and a mass fractal model were applied to fit the neutron scattering data of the Fe3O4 ferrofluids. The increasing carrier liquid composition of the fluids during dilution process was able to reduce the fractal dimension and led to a shorter length of aggregation chains. However, it did not change the size of the primary particles or building block (approximately 3.8 nm) of the Fe3O4 particles. The neutron scattering of the Fe3O4 ferrofluids under an external magnetic field in the range of 0 to 1 T exhibited in a standard way of anisotropic phenomenon originating from the nanostructural ordering of the Fe3O4 particles. On the other hand, the Fe3O4 powders did not show anisotropic scattering under an external field in the same range. Furthermore, the magnetization curve of the Fe3O4 ferrofluids and nanopowders exhibited a proper superparamagnetic character at room temperature with the respective saturation magnetization of 4.4 emu/g and 34.7 emu/g. </dc:description>
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	<dc:date>2019-12-11</dc:date>
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	<dc:source xml:lang="en-US">Atom Indonesia; Vol 45, No 3 (2019): December 2019; 165-172</dc:source>
	<dc:source>2356-5322</dc:source>
	<dc:source>0126-1568</dc:source>
	<dc:source>10.55981/aij.v45i3</dc:source>
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	<dc:rights xml:lang="en-US">Copyright (c) 2019 Atom Indonesia</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-nc-sa/4.0</dc:rights>
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