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Catalytic CO Methanation over Mesoporous ZSM5 with Different Metal Promoters

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2019) · hlm. 228–237

DOI
10.9767/bcrec.14.1.3618.228-237
ISSN
1978-2993
Terbit
2019-04-15
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

The carbon monoxide methanation has possessed huge potential as an effective method to produce synthetic natural gas (SNG). The basic requirements such as high catalytic activity at low temperatures (<500 °C) and high stability throughout all temperatures is needed for an ideal methanation catalysts. The ultimate goal of the study is to examine the influential of different metal promoters towards catalytic properties and catalytic CO methanation performance. A series of metal promoters (Rh, Co, Pd and Zn) mesoporous ZSM5 were synthesized using an incipient-wetness impregnation method and evaluated for catalytic CO methanation. XRD analysis showed that only metal oxides and no metallic phase of Rh, Co, Pd, and Zn were observed. The nitrogen physisorption analysis showed that mZSM5 possessed high surface area and micro-mesoporosity with intra- and interparticle pores. FESEM analysis illustrated that mZSM5 had typical coffin-type morphology and Rh metal dispersed on the surface of the support was confirmed by EDX analysis. Moreover, Rh (CO conversion = 95%, CH4 yield = 82%) and Co (CO conversion = 91%, CH4 yield = 71%) promoters showed significant improvement in CO methanation. On the other hand, Pd (CO conversion = 18%, CH4 yield = 12%) and Zn (CO conversion = 10%, CH4 yield = 9%) promoters had only low benefit to the CO methanation. This study affirmed that the catalytic activity of CO methanation was influenced by the variation in the type of metal loading due to different nature of metallic phases and their synergistic interaction with the supporting material.

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  • Universiti Malaysia Pahang Al-Sultan Abdullah
  • Institut Teknologi Sepuluh Nopember
  • Diponegoro University
  • University of Technology Malaysia
  • Universiti Sains Malaysia
  • National University of Malaysia
  • Universiti Brunei Darussalam
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Rekan penulisOrganisasiArtikel bersama
Didik PrasetyokoInstitut Teknologi Sepuluh Nopember5
Suprapto SupraptoInstitut Teknologi Sepuluh Nopember4
Rosalyza HasanUniversiti Malaysia Pahang Al-Sultan Abdullah2
Chi Cheng ChongUniversiti Malaysia Pahang Al-Sultan Abdullah2
Rohayu JusohUniversiti Malaysia Pahang Al-Sultan Abdullah2
Nur Hidayatul Nazirah KamarudinNational University of Malaysia2
Siti Hazirah AdamUniversiti Sains Malaysia2
Nur Fatien Muhamad SallehUniversiti Sains Malaysia2
Tri WahyuniInstitut Teknologi Sepuluh Nopember2
Hasliza BahrujiUniversiti Brunei Darussalam2
Imroatul QoniahInstitut Teknologi Sepuluh Nopember2
Ahmad Anwarud DawamInstitut Teknologi Sepuluh Nopember2
Desy Tri KusumaningtyasInstitut Teknologi Sepuluh Nopember2
Afifah RosidahInstitut Teknologi Sepuluh Nopember2
Hartati HartatiUniversitas Airlangga1
Mardi SantosoInstitut Teknologi Sepuluh Nopember1
Nur Salsabila KamarudinUniversiti Malaysia Pahang Al-Sultan Abdullah1
Nurfatehah Wahyuny Che JusohUniversity of Technology Malaysia1
Nur Farhana JaafarUniversiti Sains Malaysia1
Nuramira Fateha SukorUniversiti Malaysia Pahang Al-Sultan Abdullah1
Amirul Hafiiz RuhaimiUniversity of Technology Malaysia1
C. C. TehUniversity of Technology Malaysia1
Mohammed Faraj SaeidTobruk University1
Bashir Abubakar AbdulkadirUniversiti Malaysia Pahang Al-Sultan Abdullah1
Nur Aida Farihin AhliyasahUniversiti Malaysia Pahang Al-Sultan Abdullah1
Dessy AriyantiDiponegoro University1
Fazlena HamzahUniversiti Teknologi MARA1
Aprilina PurbasariDiponegoro University1
Widayat WidayatDiponegoro University1
I Nyoman WidiasaDiponegoro University1
Viona SyifaDiponegoro University1
Farida Diyah HapsariDiponegoro University1
S. SilvianaDiponegoro University1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Catalytic CO Methanation over Mesoporous ZSM5 with Different Metal Promoters</dc:title>
	<dc:creator>Teh, Lee Peng</dc:creator>
	<dc:creator>Triwahyono, Sugeng</dc:creator>
	<dc:creator>Jalil, Aishah Abdul</dc:creator>
	<dc:creator>Setiabudi, Herma Dina</dc:creator>
	<dc:creator>Abdul Aziz, Muhammad Arif</dc:creator>
	<dc:subject xml:lang="en-US">Synthetic Natural Gas; CO Methanation; Mesoporous ZSM5; Metal Promoters; Rh</dc:subject>
	<dc:description xml:lang="en-US">The carbon monoxide methanation has possessed huge potential as an effective method to produce synthetic natural gas (SNG). The basic requirements such as high catalytic activity at low temperatures (&lt;500 °C) and high stability throughout all temperatures is needed for an ideal methanation catalysts. The ultimate goal of the study is to examine the influential of different metal promoters towards catalytic properties and catalytic CO methanation performance. A series of metal promoters (Rh, Co, Pd and Zn) mesoporous ZSM5 were synthesized using an incipient-wetness impregnation method and evaluated for catalytic CO methanation. XRD analysis showed that only metal oxides and no metallic phase of Rh, Co, Pd, and Zn were observed. The nitrogen physisorption analysis showed that mZSM5 possessed high surface area and micro-mesoporosity with intra- and interparticle pores. FESEM analysis illustrated that mZSM5 had typical coffin-type morphology and Rh metal dispersed on the surface of the support was confirmed by EDX analysis. Moreover, Rh (CO conversion = 95%, CH4 yield = 82%) and Co (CO conversion = 91%, CH4 yield = 71%) promoters showed significant improvement in CO methanation. On the other hand, Pd (CO conversion = 18%, CH4 yield = 12%) and Zn (CO conversion = 10%, CH4 yield = 9%) promoters had only low benefit to the CO methanation. This study affirmed that the catalytic activity of CO methanation was influenced by the variation in the type of metal loading due to different nature of metallic phases and their synergistic interaction with the supporting material. </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US">Young Researcher Incentive Grant (GGPM-2017-075) by Universiti Kebangsaan Malaysia and Post-doctoral Research Grant (No. 04E07) by Universiti Teknologi Malaysia</dc:contributor>
	<dc:date>2019-04-15</dc:date>
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	<dc:identifier>10.9767/bcrec.14.1.3618.228-237</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2019: BCREC Volume 14 Issue 1 Year 2019 (April 2019); 228-237</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
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	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/3618/832</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/3618/833</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/3618/834</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2019 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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