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Effect of Additional Polyethylene Glycol and Citric Acid on Characteristics of NiMo/g-Al2O3 Catalyst in Light Cycle Gas Oil Hydrodesulfurisation

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2023) · hlm. 162–172

DOI
10.9767/bcrec.17036
ISSN
1978-2993
Terbit
2023-04-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Sulfur is an impurity in diesel that causes low product quality and environmental pollution. Therefore, a catalyst is needed in the profound hydrodesulfurization (HDS) reaction to produce diesel fuel with low sulfur content. The catalyst synthesized in this work was NiMo/g-Al2O3 with the addition of PEG (2%, 4%, 6%) (w/w) and CA (1%, 2%, and 4%) (w/w). The catalyst was synthesized using the dry impregnation method with a metal concentration of 3% NiO and 15% MoO3. The obtained catalysts were characterized using X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), and Surface Area Analyzer (SAA). This work acquired the best catalyst characteristics for the HDS process by adding 2% PEG and 1% CA with a concentration of 3.19% NiO and 13.98% MoO3. The surface area, pore volume, and diameter are 181.655 m2/g, 0.50 cm3/g, and 110.51 Å, respectively. The catalyst activity satisfies Euro V standards at 345 ℃ with a sulfur content of 9.55 ppm, and the sulfur conversion (HDS) is 98.75%. The density and cetane index of the obtained diesel fuel was 0.798 g/mL and 53.6, respectively. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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  • Syarif Hidayatullah State Islamic University Jakarta
  • University of Indonesia
  • National Nuclear Energy Agency of Indonesia
  • Pertamina (Indonesia)
  • Badan Pengkajian dan Penerapan Teknologi
  • Universitas Mathla'ul Anwar Banten
  • Universitas Halu Oleo
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Rekan penulisOrganisasiArtikel bersama
Agustino ZulysUniversity of Indonesia13
Nanda SaridewiSyarif Hidayatullah State Islamic University Jakarta9
Siti NurbaytiSyarif Hidayatullah State Islamic University Jakarta7
Isalmi AzizSyarif Hidayatullah State Islamic University Jakarta6
Nani RadiastutiSyarif Hidayatullah State Islamic University Jakarta5
Sandra HermantoSyarif Hidayatullah State Islamic University Jakarta5
Anna MuawanahSyarif Hidayatullah State Islamic University Jakarta5
Nurhasni NurhasniSyarif Hidayatullah State Islamic University Jakarta5
Eka Rizki AmeliaSyarif Hidayatullah State Islamic University Jakarta4
La Ode SumarlinSyarif Hidayatullah State Islamic University Jakarta3
Muhammad Shofyan GunawanSyarif Hidayatullah State Islamic University Jakarta3
Sri KomalaSyarif Hidayatullah State Islamic University Jakarta3
Latifah TulhusnaSyarif Hidayatullah State Islamic University Jakarta3
Rizkha FadhillaSyarif Hidayatullah State Islamic University Jakarta3
Tarso RudianaUniversitas Mathla'ul Anwar Banten3
Yulyani Nur AzizahSyarif Hidayatullah State Islamic University Jakarta3
Ahmad FathoniSyarif Hidayatullah State Islamic University Jakarta2
Wulandari OktaviaSyarif Hidayatullah State Islamic University Jakarta2
Farhan Maulana AzharSyarif Hidayatullah State Islamic University Jakarta2
Risma Nur FitriaSyarif Hidayatullah State Islamic University Jakarta2
Jarnuzi GunlazuardiUniversity of Indonesia2
Muhammad Derry Luthfi YudhiUniversity of Indonesia2
Ira JayanegaraBadan Pengkajian dan Penerapan Teknologi2
Adeng HudayaSyarif Hidayatullah State Islamic University Jakarta2
Uly Fitria BaleSyarif Hidayatullah State Islamic University Jakarta2
Rizka FadhillaSyarif Hidayatullah State Islamic University Jakarta2
Teguh WahyonoNational Nuclear Energy Agency of Indonesia1
Widhi KurniawanUniversitas Halu Oleo1
Rista Kurnia DewiSyarif Hidayatullah State Islamic University Jakarta1
Sihono SihonoNational Nuclear Energy Agency of Indonesia1
Dwi Yuli RakhmawatiUniversitas Negeri Surabaya1
Fuady HaniefSyarif Hidayatullah State Islamic University Jakarta1
Lia PratiwiSyarif Hidayatullah State Islamic University Jakarta1
Selviana RustantiSyarif Hidayatullah State Islamic University Jakarta1
Amar Ariza KurniawanUniversity of Indonesia1
Muhammad IbadurrohmanUniversity of Indonesia1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en-US">Effect of Additional Polyethylene Glycol and Citric Acid on Characteristics of NiMo/g-Al2O3 Catalyst in Light Cycle Gas Oil Hydrodesulfurisation</dc:title>
	<dc:creator>Sukandar, Dede</dc:creator>
	<dc:creator>Badriyah, Lailatul</dc:creator>
	<dc:creator>Rustyawan, Wawan</dc:creator>
	<dc:creator>Adawiah, Adawiah</dc:creator>
	<dc:subject xml:lang="en-US">PEG; Polyethylene Glycol; Citric Acid; Hydrodesulfurization; NiMo/g-Al2O3; Light Cycle Gas Oil</dc:subject>
	<dc:description xml:lang="en-US">Sulfur is an impurity in diesel that causes low product quality and environmental pollution. Therefore, a catalyst is needed in the profound hydrodesulfurization (HDS) reaction to produce diesel fuel with low sulfur content. The catalyst synthesized in this work was NiMo/g-Al2O3 with the addition of PEG (2%, 4%, 6%) (w/w) and CA (1%, 2%, and 4%) (w/w). The catalyst was synthesized using the dry impregnation method with a metal concentration of 3% NiO and 15% MoO3. The obtained catalysts were characterized using X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), and Surface Area Analyzer (SAA). This work acquired the best catalyst characteristics for the HDS process by adding 2% PEG and 1% CA with a concentration of 3.19% NiO and 13.98% MoO3. The surface area, pore volume, and diameter are 181.655 m2/g, 0.50 cm3/g, and 110.51 Å, respectively. The catalyst activity satisfies Euro V standards at 345 ℃ with a sulfur content of 9.55 ppm, and the sulfur conversion (HDS) is 98.75%. The density and cetane index of the obtained diesel fuel was 0.798 g/mL and 53.6, respectively. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2023-04-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/17036</dc:identifier>
	<dc:identifier>10.9767/bcrec.17036</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2023: BCREC Volume 18 Issue 1 Year 2023 (April 2023); 162-172</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/17036/8787</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2023 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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