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Optimization of Microwave-Assisted Alkali Pretreatment for Enhancement of Delignification Process of Cocoa Pod Husk

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2021) · hlm. 31–43

DOI
10.9767/bcrec.16.1.8872.31-43
ISSN
1978-2993
Terbit
2021-03-31
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

In this study, the optimization of microwave-assisted alkaline (MAA) pretreatment is performed to attain the optimal operating parameters for the delignification of cocoa pod husk (CPH). The MAA performance was examined by heating the CPH solid with different particle sizes (60–120 mesh) and NaOH solution with a different sample to a solvent (SS) ratio (0.02–0.05 g/L), for short irradiation time (1–4 min). Box-Behnken Design (BBD) was utilized to optimize the percentage of lignocellulose composition changes. The results show that by enlarging particle size, the content of lignin and cellulose decreased while hemicellulose increased. By prolong irradiation time, the content of lignin and hemicellulose decreased while cellulose elevated. On the other hand, increasing the SS ratio was not significant for hemicellulose content changes. From FTIR and SEM characterization, the MAA drove the removal of lignin and hemicellulose of CPH and increased cellulose slightly. Supported by kinetic study which conducted in this work, it was exhibited that MAA pretreatment technology is an effective delignification method of CPH which can tackle the bottleneck of its commercial biofuel production. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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  • Institut Teknologi Sepuluh Nopember
  • Universitas Jember
  • Politeknik Negeri Malang
  • University of Surabaya
  • Sriwijaya University
  • Bandung Institute of Technology
  • Kyushu University
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Tampilkan sebagai tabel
Rekan penulisOrganisasiArtikel bersama
Arief WidjajaInstitut Teknologi Sepuluh Nopember10
Nur FadhilahInstitut Teknologi Sepuluh Nopember7
Yukihiro TashiroKyushu University4
Tantular NurtonoInstitut Teknologi Sepuluh Nopember3
Siska Nuri FadilahSriwijaya University3
Dwina MoentamariaInstitut Teknologi Sepuluh Nopember3
Tri WidjajaInstitut Teknologi Sepuluh Nopember3
Candra WijayaInstitut Teknologi Sepuluh Nopember2
Tri WidjajaInstitut Teknologi Sepuluh Nopember2
Lieke RiadiUniversity of Surabaya2
Hanny F. SangianInstitut Teknologi Sepuluh Nopember2
Zakijah IrfinPoliteknik Negeri Malang2
Achmad ChumaidiPoliteknik Negeri Malang2
Muhammad RezaBandung Institute of Technology1
Jauhairiyah GailaniUniversitas Jember1
Tria SusantiUniversitas Jember1
Syarifa Aminatuz ZuhroUniversitas Jember1
Achmad SjaifullahUniversitas Jember1
Busroni BusroniUniversitas Jember1
Niki EtrulyInstitut Teknologi Sepuluh Nopember1
Dyah SawitriInstitut Teknologi Sepuluh Nopember1
Urania Noor Lintang PertiwiInstitut Teknologi Sepuluh Nopember1
Tabina Raissa ApolInstitut Teknologi Sepuluh Nopember1
Ika Putri Nikmatur RohmahInstitut Teknologi Sepuluh Nopember1
Doty Dewi RisantiInstitut Teknologi Sepuluh Nopember1
Ruri Agung WahyuonoInstitut Teknologi Sepuluh Nopember1
Dendy SatrioInstitut Teknologi Sepuluh Nopember1
Achri Isnan KhamilUniversitas Jember1
Ningsi Lick SangadjiInstitut Teknologi Sepuluh Nopember1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en-US">Optimization of Microwave-Assisted Alkali Pretreatment for Enhancement of Delignification Process of Cocoa Pod Husk</dc:title>
	<dc:creator>Muharja, Maktum</dc:creator>
	<dc:creator>Darmayanti, Rizki Fitria</dc:creator>
	<dc:creator>Palupi, Bekti</dc:creator>
	<dc:creator>Rahmawati, Istiqomah</dc:creator>
	<dc:creator>Fachri, Boy Arief</dc:creator>
	<dc:creator>Setiawan, Felix Arie</dc:creator>
	<dc:creator>Amini, Helda Wika</dc:creator>
	<dc:creator>Rizkiana, Meta Fitri</dc:creator>
	<dc:creator>Rahmawati, Atiqa</dc:creator>
	<dc:creator>Susanti, Ari</dc:creator>
	<dc:creator>Putri, Ditta Kharisma Yolanda</dc:creator>
	<dc:subject xml:lang="en-US">alkaline; biofuel; cocoa pod husk; delignification; microwave</dc:subject>
	<dc:description xml:lang="en-US">In this study, the optimization of microwave-assisted alkaline (MAA) pretreatment is performed to attain the optimal operating parameters for the delignification of cocoa pod husk (CPH). The MAA performance was examined by heating the CPH solid with different particle sizes (60–120 mesh) and NaOH solution with a different sample to a solvent (SS) ratio (0.02–0.05 g/L), for short irradiation time (1–4 min). Box-Behnken Design (BBD) was utilized to optimize the percentage of lignocellulose composition changes. The results show that by enlarging particle size, the content of lignin and cellulose decreased while hemicellulose increased. By prolong irradiation time, the content of lignin and hemicellulose decreased while cellulose elevated. On the other hand, increasing the SS ratio was not significant for hemicellulose content changes. From FTIR and SEM characterization, the MAA drove the removal of lignin and hemicellulose of CPH and increased cellulose slightly. Supported by kinetic study which conducted in this work, it was exhibited that MAA pretreatment technology is an effective delignification method of CPH which can tackle the bottleneck of its commercial biofuel production. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2021-03-31</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/8872</dc:identifier>
	<dc:identifier>10.9767/bcrec.16.1.8872.31-43</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2021: BCREC Volume 16 Issue 1 Year 2021 (March 2021); 31-43</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/8872/5139</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/8872/2044</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/8872/2045</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/8872/2046</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/8872/2047</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2021 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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