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Synthesize and Characterization of Pt-supported Co-ZIF for Catalytic Hydrocracking and Hydroisomerization of n-Hexadecane

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2024) · hlm. 171–180

DOI
10.9767/bcrec.20117
ISSN
1978-2993
Terbit
2024-04-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Zeolitic Imidazole Frameworks (ZIFs) are prospective porous materials as catalyst support due to their relatively large surface area, and tunability in size, structure, and porosity. Recent studies have also shown that ZIF is the best candidate for various catalytic redox reactions such as the oxidation of benzyl aromatic hydrocarbons. In this study, the synthesized Pt catalyst supported on Co-ZIF was varied by the organic ligands: imidazole, benzimidazole, and 1-(3-aminopropyl) imidazole, then followed by impregnation of Pt precursor. The catalysts were characterized its physical and chemicals properties such as Fourier Transform Infrared (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Brunauer Emmet Teller (BET), Temperature-Programmed Desorption (NH3-TPD and CO2-TPD). The prepared catalysts were evaluated for catalytic hydrocracking and hydroisomerization of n-hexadecane in a 100 ml-batch reactor. GC-MS analysis presented that the Pt/ZIF catalyst with imidazole ligands has better performance than others. Hence, the optimization of n-Hexadecane conversion was carried out by the Pt/ZIF-imidazole catalyst varying the amount of metal loading, time and temperature reaction. The results showed that the reaction temperature of 350 ºC using 20 bar H2 for 4 h and the addition of 15 wt% Pt successfully achieved 90.77% conversion and produced the highest yield of isomers and alkanes, 4.04% and 35.75%, respectively. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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  • National Research and Innovation Agency
  • Indonesian Institute of Sciences
  • Institut Teknologi Sepuluh Nopember
  • Universitas Pertamina
  • Syarif Hidayatullah State Islamic University Jakarta
  • National Nuclear Energy Agency of Indonesia
  • Universitas Prasetiya Mulya
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Rekan penulisOrganisasiArtikel bersama
Anis KristianiNational Research and Innovation Agency1
N. EffendiNational Nuclear Energy Agency of Indonesia1
Dyah StyariniIndonesian Institute of Sciences1
Yanni SudiyaniIndonesian Institute of Sciences1
Aditia Nur BaktiNational Research and Innovation Agency1
Holanda RamadhitaUniversitas Prasetiya Mulya1
Andreas AndreasNational Research and Innovation Agency1
Joni PrasetyoNational Research and Innovation Agency1
Huyen Tran DangKorea Research Institute of Chemical Technology1
Tri WidjajaInstitut Teknologi Sepuluh Nopember1
Ali AltwayInstitut Teknologi Sepuluh Nopember1
Treisnaning WidasgantriInstitut Teknologi Sepuluh Nopember1
Thasya LamhotmatuaInstitut Teknologi Sepuluh Nopember1
Kevin AntoniusInstitut Teknologi Sepuluh Nopember1
Dede SukandarSyarif Hidayatullah State Islamic University Jakarta1
Nino RinaldiNational Research and Innovation Agency1
Adid Adep DwiatmokoNational Research and Innovation Agency1
Rizky Achmad FauziSyarif Hidayatullah State Islamic University Jakarta1
Silvester TursiloadiIndonesian Institute of Sciences1
Sudiyarmanto SudiyarmantoIndonesian Institute of Sciences1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Synthesize and Characterization of Pt-supported Co-ZIF for Catalytic Hydrocracking and Hydroisomerization of n-Hexadecane</dc:title>
	<dc:creator>Hidayati, Luthfiana Nurul</dc:creator>
	<dc:creator>Aulia, Fauzan</dc:creator>
	<dc:creator>Napitupulu, Sebastian Ulido</dc:creator>
	<dc:creator>Adhyaksa, Gede Widia Pratama</dc:creator>
	<dc:creator>Dahnum, Deliana</dc:creator>
	<dc:subject xml:lang="en-US">Zeolitic Imidazole Frameworks; Metal-Organic Framework; Hydrocracking; Hydroisomerization; n-hexadecane.</dc:subject>
	<dc:description xml:lang="en-US">Zeolitic Imidazole Frameworks (ZIFs) are prospective porous materials as catalyst support due to their relatively large surface area, and tunability in size, structure, and porosity. Recent studies have also shown that ZIF is the best candidate for various catalytic redox reactions such as the oxidation of benzyl aromatic hydrocarbons. In this study, the synthesized Pt catalyst supported on Co-ZIF was varied by the organic ligands: imidazole, benzimidazole, and 1-(3-aminopropyl) imidazole, then followed by impregnation of Pt precursor. The catalysts were characterized its physical and chemicals properties such as Fourier Transform Infrared (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Brunauer Emmet Teller (BET), Temperature-Programmed Desorption (NH3-TPD and CO2-TPD). The prepared catalysts were evaluated for catalytic hydrocracking and hydroisomerization of n-hexadecane in a 100 ml-batch reactor. GC-MS analysis presented that the Pt/ZIF catalyst with imidazole ligands has better performance than others. Hence, the optimization of n-Hexadecane conversion was carried out by the Pt/ZIF-imidazole catalyst varying the amount of metal loading, time and temperature reaction. The results showed that the reaction temperature of 350 ºC using 20 bar H2 for 4 h and the addition of 15 wt% Pt successfully achieved 90.77% conversion and produced the highest yield of isomers and alkanes, 4.04% and 35.75%, respectively. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2024-04-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/20117</dc:identifier>
	<dc:identifier>10.9767/bcrec.20117</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2024: BCREC Volume 19 Issue 1 Year 2024 (April 2024); 171-180</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/20117/9694</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/20117/5126</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/20117/5127</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2024 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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