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Effects of Weight Hourly Space Velocity and Catalyst Diameter on Performance of Hybrid Catalytic-Plasma Reactor for Biodiesel Synthesis over Sulphated Zinc Oxide Acid Catalyst

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2017) · hlm. 227–234

DOI
10.9767/bcrec.12.2.775.227-234
ISSN
1978-2993
Terbit
2017-08-01
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Biodiesel synthesis through transesterification of soybean oil with methanol on hybrid catalytic-plasma reactor over sulphated zinc oxide (SO42-/ZnO) active acid catalyst was investigated. This research was aimed to study effects of Weight Hourly Space Velocity (WHSV) and the catalyst diameter on performance of the hybrid catalytic-plasma reactor for biodiesel synthesis. The amount (20.2 g) of active sulphated zinc oxide solid acid catalysts was loaded into discharge zone of the reactor. The WHSV and the catalyst diameter were varied between 0.89 to 1.55 min-1 and 3, 5, and 7 mm, respectively. The molar ratio of methanol to oil as reactants of 15:1 is fed to the reactor, while operating condition of the reactor was kept at reaction temperature of 65 oC and ambient pressure. The fatty acid methyl ester (FAME) component in biodiesel product was identified by Gas Chromatography - Mass Spectrometry (GC-MS). The results showed that the FAME yield decreases with increasing WHSV. It was found that the optimum FAME yield was achieved of 56.91 % at WHSV of 0.89 min-1 and catalyst diameter of 5 mm and reaction time of 1.25 min. It can be concluded that the biodiesel synthesis using the hybrid catalytic-plasma reactor system exhibited promising the FAME yield.

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  • Hasanuddin University
  • State University of Malang
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  • Universitas Muhammadiyah Metro
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Didi Dwi AnggoroAfiliasi tidak diketahui12
Didi D. AnggoroAfiliasi tidak diketahui6
Teguh RiyantoAfiliasi tidak diketahui6
Gunadi GunadiUniversitas Gajayana Malang4
Widyatmani Sih DewiAfiliasi tidak diketahui4
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Sri HartatiAfiliasi tidak diketahui4
Sudadi SudadiAfiliasi tidak diketahui3
Retno RosariastutiAfiliasi tidak diketahui3
Muhammad Isran RamliHasanuddin University2
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Indro SumantriAfiliasi tidak diketahui2
Widayat WidayatAfiliasi tidak diketahui2
Rosye H.R. TanjungCenderawasih University1
Suriani Br. SurbaktiCenderawasih University1
Dian Dwi Apriliyani ArsdinHasanuddin University1
Nuzul HidayatAfiliasi tidak diketahui1
SUDIRMAN SUDIRMANState University of Malang1
Nego LinuhungUniversitas Muhammadiyah Metro1
Sukoriyanto SukoriyantoState University of Malang1
Mohd Isha AwangUniversiti Utara Malaysia1
Agus Puji PrasetyonoAfiliasi tidak diketahui1
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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Effects of Weight Hourly Space Velocity and Catalyst Diameter on Performance of Hybrid Catalytic-Plasma Reactor for Biodiesel Synthesis over Sulphated Zinc Oxide Acid Catalyst</dc:title>
	<dc:creator>Buchori, Luqman</dc:creator>
	<dc:creator>Istadi, Istadi</dc:creator>
	<dc:creator>Purwanto, Purwanto</dc:creator>
	<dc:subject xml:lang="en-US">Biodiesel; Sulphated zinc oxide; Hybrid catalytic-plasma reactor; Transesterification</dc:subject>
	<dc:description xml:lang="en-US">Biodiesel synthesis through transesterification of soybean oil with methanol on hybrid catalytic-plasma reactor over sulphated zinc oxide (SO42-/ZnO) active acid catalyst was investigated. This research was aimed to study effects of Weight Hourly Space Velocity (WHSV) and the catalyst diameter on performance of the hybrid catalytic-plasma reactor for biodiesel synthesis. The amount (20.2 g) of active sulphated zinc oxide solid acid catalysts was loaded into discharge zone of the reactor. The WHSV and the catalyst diameter were varied between 0.89 to 1.55 min-1 and 3, 5, and 7 mm, respectively. The molar ratio of methanol to oil as reactants of 15:1 is fed to the reactor, while operating condition of the reactor was kept at reaction temperature of 65 oC and ambient pressure. The fatty acid methyl ester (FAME) component in biodiesel product was identified by Gas Chromatography - Mass Spectrometry (GC-MS). The results showed that the FAME yield decreases with increasing WHSV. It was found that the optimum FAME yield was achieved of 56.91 % at WHSV of 0.89 min-1 and catalyst diameter of 5 mm and reaction time of 1.25 min. It can be concluded that the biodiesel synthesis using the hybrid catalytic-plasma reactor system exhibited promising the FAME yield. </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US"></dc:contributor>
	<dc:date>2017-08-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/775</dc:identifier>
	<dc:identifier>10.9767/bcrec.12.2.775.227-234</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2017: BCREC Volume 12 Issue 2 Year 2017 (August 2017); 227-234</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/775/719</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/775/105</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2017 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>