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Screening Support of Bimetallic Ruthenium-Tin Catalysts for Aqueous Phase Hydrogenolysis of Furfuryl Alcohol to 1,5-Pentanediol

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2025) · hlm. 293–306

DOI
10.9767/bcrec.20357
ISSN
1978-2993
Terbit
2025-08-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

The selective aqueous phase hydrogenolysis of furfuryl alcohol (FFalc) to 1,5-pentanediol (1,5-PeD) using supported bimetallic ruthenium-tin (Ru-Sn) catalysts on various metal oxide supports (e.g., TiO2, ZnO, ZrO2, Nb2O5, g-Al2O3) and its combination were investigated systematically. The catalysts were prepared via coprecipitation-hydrothermal at 150 oC for 24 h, followed by reduction with H2 at 400 oC for 2 h. Supported Ru-Sn on TiO2(A), g-Al2O3, and ZrO2 catalysts exhibited higher yield of 1,5-PeD (55-69%) than that other catalysts at 180 oC, H2 10-30 bar for 3-5 h. However, those supported catalysts showed poor recyclability after the first reaction run, and therefore further examination on g-Al2O3 supported Ru-Sn was performed. The Ru-Sn catalyst supported on g-Al2O3-metal oxide composites (metal oxides: ZrO2, TiO2(A), TiO2(R), ZnO, Nb2O5, and C) afforded higher FFalc conversion and yield of 1,5-PeD than that of unmodified g-Al2O3 at 180 oC, H2 30 bar for 3 h. Among them, the Ru-Sn/g-Al2O3-TiO2(A) (33%) catalyst could afford the highest yield of 1,5-PeD (80%) at 99% conversion FFalc at 180 oC, H2 10 bar for 5 h. Around 95% of this catalyst can be recycled after the second reaction run and the activity can be restored to initial after reactivation with H2 at 400 oC for 2 h with a 69% yield of 1,5-PeD at 97% FFalc conversion. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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  • Lambung Mangkurat University
  • National Research and Innovation Agency
  • Universitas Muhammadiyah Malang
  • Chiba University
  • Sultan Ageng Tirtayasa University
  • Tanjungpura University
  • Afiliasi tidak diketahui
  • Organisasi berbeda
  • Organisasi sama
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Tampilkan sebagai tabel
Rekan penulisOrganisasiArtikel bersama
Sadang HusainLambung Mangkurat University7
Maria Dewi AstutiLambung Mangkurat University6
Gagus Ketut SunnardiantoNational Research and Innovation Agency6
Iryanti Fatyasari NataLambung Mangkurat University3
Kiky Corneliasari SembiringNational Research and Innovation Agency3
Heny Puspita DewiLambung Mangkurat University3
Jayanudin JayanudinSultan Ageng Tirtayasa University3
Indri Badri AdilinaAfiliasi tidak diketahui3
Utami IrawatiLambung Mangkurat University3
Shauqi Aulia RifwandaLambung Mangkurat University3
Ferensa OemryNational Research and Innovation Agency3
Takayoshi HaraChiba University3
Shogo ShimazuChiba University2
Agung NugrohoLambung Mangkurat University2
Elisa HayatiLambung Mangkurat University2
Kamilia MustikasariLambung Mangkurat University2
Sutomo SutomoLambung Mangkurat University2
Andinusa RahmandhikaUniversitas Muhammadiyah Malang1
Ali SaifullahUniversitas Muhammadiyah Malang1
Ali MokhtarUniversitas Muhammadiyah Malang1
Muhammad Iqbal PratamaLambung Mangkurat University1
Abdullah AbdullahLambung Mangkurat University1
Susi SusiLambung Mangkurat University1
Kurnia PutriLambung Mangkurat University1
Annisa AnnisaLambung Mangkurat University1
Sutomo SutomoLambung Mangkurat University1
Ditya KristinaLambung Mangkurat University1
Dwi Rasy MujiyantiLambung Mangkurat University1
Syahrul KhairiTanjungpura University1
Gusti Atika UrfaLambung Mangkurat University1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Screening Support of Bimetallic Ruthenium-Tin Catalysts for Aqueous Phase Hydrogenolysis of Furfuryl Alcohol to 1,5-Pentanediol</dc:title>
	<dc:creator>Rodiansono, Rodiansono</dc:creator>
	<dc:creator>Azzahra, Atina Sabila</dc:creator>
	<dc:creator>Mikrianto, Edi</dc:creator>
	<dc:creator>Ridhoni, Arif</dc:creator>
	<dc:creator>Mustari, Ikhsan</dc:creator>
	<dc:creator>Nurfitriani, Anggita</dc:creator>
	<dc:creator>Bodoi, Thea Seventina Desiani</dc:creator>
	<dc:creator>Sanjaya, Rahmat Eko</dc:creator>
	<dc:creator>Suarso, Eka</dc:creator>
	<dc:creator>Ansyah, Pathur Razi</dc:creator>
	<dc:subject xml:lang="en-US">Bimetallic Ru-Sn; aqueous phase hydrogenolysis; furfuryl alcohol; 1,5-pentanediol</dc:subject>
	<dc:description xml:lang="en-US">The selective aqueous phase hydrogenolysis of furfuryl alcohol (FFalc) to 1,5-pentanediol (1,5-PeD) using supported bimetallic ruthenium-tin (Ru-Sn) catalysts on various metal oxide supports (e.g., TiO2, ZnO, ZrO2, Nb2O5, g-Al2O3) and its combination were investigated systematically. The catalysts were prepared via coprecipitation-hydrothermal at 150 oC for 24 h, followed by reduction with H2 at 400 oC for 2 h. Supported Ru-Sn on TiO2(A), g-Al2O3, and ZrO2 catalysts exhibited higher yield of 1,5-PeD (55-69%) than that other catalysts at 180 oC, H2 10-30 bar for 3-5 h. However, those supported catalysts showed poor recyclability after the first reaction run, and therefore further examination on g-Al2O3 supported Ru-Sn was performed. The Ru-Sn catalyst supported on g-Al2O3-metal oxide composites (metal oxides: ZrO2, TiO2(A), TiO2(R), ZnO, Nb2O5, and C) afforded higher FFalc conversion and yield of 1,5-PeD than that of unmodified g-Al2O3 at 180 oC, H2 30 bar for 3 h. Among them, the Ru-Sn/g-Al2O3-TiO2(A) (33%) catalyst could afford the highest yield of 1,5-PeD (80%) at 99% conversion FFalc at 180 oC, H2 10 bar for 5 h. Around 95% of this catalyst can be recycled after the second reaction run and the activity can be restored to initial after reactivation with H2 at 400 oC for 2 h with a 69% yield of 1,5-PeD at 97% FFalc conversion. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2025-08-30</dc:date>
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	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/20357</dc:identifier>
	<dc:identifier>10.9767/bcrec.20357</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2025: BCREC Volume 20 Issue 2 Year 2025 (August 2025); 293-306</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/20357/9808</dc:relation>
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	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/20357/5646</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/20357/5670</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2025 by Authors, Published by BCREC Publishing Group</dc:rights>
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