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Selective Production of Green Hydrocarbons from the Hydrotreatment of Waste Coconut Oil over Ni- and NiMo-supported on Amine-functionalized Mesoporous Silica

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2020) · hlm. 415–431

DOI
10.9767/bcrec.15.2.7136.415-431
ISSN
1978-2993
Terbit
2020-08-01
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

In order to overcome the depletion of energy resources, the production of fuel from a renewable source (green fuel) has aroused attention. The present work serves as a comparative study for green fuel production by utilizing monometallic Ni and bimetallic NiMo loaded on amine-functionalized mesoporous silica (MS). Two types of catalysts, denoted as Ni/NH2-MS and NiMo/NH2-MS, were prepared and evaluated for its catalytic activity in the hydrotreatment of waste coconut oil (WCO) at 450 ℃ under the flow of H2 gas (20 mL.min-1). Each catalysts were characterized by using X-ray Diffraction (XRD), Atomic Absorption Spectrometer (AAS), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), and Fourier Transform Infra Red (FTIR). Study of selectivity by GC-MS showed that gasoline-range hydrocarbon, especially n-undecane, was the major compound in the liquid products generated by the two amine-functionalized catalysts prepared in this study. The result showed that monometallic Ni/NH2-MS with surface area, total pore volume, nickel loading and average pore diameter 328.68 m2.g-1, 0.25 cm3.g-1, 1.90 wt%, 3.10 nm, respectively, exhibited the best performance in producing liquid hydrocarbon and generated higher level of liquid product (77.9 wt%) than bimetallic NiMo/NH2-MS (76.3 wt%). However, it is highlighted that adding 1.08 wt% of Mo in bimetallic NiMo/NH2-MS comprising 0.83 wt% of Ni improved the catalyst selectivity towards producing higher level of gasoline-range hydrocarbon (43 wt%). The bimetallic NiMo/NH2-MS prepared was found to have surface area, total pore volume, and average pore diameter of 325.13 m2.g-1, 0.14 cm3.g-1, 3.22 nm, respectively. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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  • Universitas Gadjah Mada
  • Muhammadiyah University of Surakarta
  • Universitas Airlangga
  • National Nuclear Energy Agency of Indonesia
  • Universitas Pendidikan Ganesha
  • National Research and Innovation Agency
  • State University of Semarang
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Rekan penulisOrganisasiArtikel bersama
Dyah Ayu FatmawatiUniversitas Gadjah Mada10
Sri SudionoUniversitas Gadjah Mada5
TriyonoAfiliasi tidak diketahui4
Suryo PurwonoUniversitas Gadjah Mada4
Endah SuarsihUniversitas Gadjah Mada4
Puspa Nindro MahayuwatiUniversitas Gadjah Mada3
Uswatul ChasanahUniversitas Gadjah Mada3
Karna WijayaUniversitas Gadjah Mada2
Iman SantosoUniversitas Gadjah Mada2
Ni Made WiratiniUniversitas Pendidikan Ganesha2
Agus KuncakaUniversitas Gadjah Mada2
Muh. Siddik IbrahimUniversitas Gadjah Mada2
Elizabeth Selia NandiniUniversitas Gadjah Mada2
Abdullah AbdullohAfiliasi tidak diketahui2
Didik Prasetyoko Didik PrasetyokoAfiliasi tidak diketahui2
Siti MaryamUniversitas Airlangga2
Nanik Siti AminahUniversitas Airlangga2
Mudasir MudasirUniversitas Gadjah Mada2
Noer SasongkoMuhammadiyah University of Surakarta1
Nurlita Arum SMuhammadiyah University of Surakarta1
Lulu HardinaMuhammadiyah University of Surakarta1
Jamasri JamasriUniversitas Gadjah Mada1
Mochammad Noer IlmanUniversitas Gadjah Mada1
Raden SoekrisnoUniversitas Gadjah Mada1
Sutiarso SutiarsoNational Nuclear Energy Agency of Indonesia1
Patrik ChandraUniversitas Gadjah Mada1
Aldino Javier SaviolaUniversitas Gadjah Mada1
Wangsa WangsaUniversitas Gadjah Mada1
Latifah HauliNational Research and Innovation Agency1
Riska Astin FitriaUniversitas Gadjah Mada1
Edy CahyonoState University of Semarang1
M. MuchalalUniversitas Gadjah Mada1
Harno Dwi PranowoUniversitas Gadjah Mada1
Indriyana KartiniAfiliasi tidak diketahui1
Siti SalamahUniversitas Ahmad Dahlan1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Selective Production of Green Hydrocarbons from the Hydrotreatment of Waste Coconut Oil over Ni- and NiMo-supported on Amine-functionalized Mesoporous Silica</dc:title>
	<dc:creator>Trisunaryanti, Wega</dc:creator>
	<dc:creator>Larasati, Savitri</dc:creator>
	<dc:creator>Triyono, Triyono</dc:creator>
	<dc:creator>Paramesti, Cahyarani</dc:creator>
	<dc:creator>Santoso, Nugroho Raka</dc:creator>
	<dc:subject xml:lang="en-US">hydrotreatment; biofuel production; amine-functionalized; bimetallic catalyst; mesoporous silica</dc:subject>
	<dc:description xml:lang="en-US">In order to overcome the depletion of energy resources, the production of fuel from a renewable source (green fuel) has aroused attention. The present work serves as a comparative study for green fuel production by utilizing monometallic Ni and bimetallic NiMo loaded on amine-functionalized mesoporous silica (MS). Two types of catalysts, denoted as Ni/NH2-MS and NiMo/NH2-MS, were prepared and evaluated for its catalytic activity in the hydrotreatment of waste coconut oil (WCO) at 450 ℃ under the flow of H2 gas (20 mL.min-1). Each catalysts were characterized by using X-ray Diffraction (XRD), Atomic Absorption Spectrometer (AAS), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), and Fourier Transform Infra Red (FTIR). Study of selectivity by GC-MS showed that gasoline-range hydrocarbon, especially n-undecane, was the major compound in the liquid products generated by the two amine-functionalized catalysts prepared in this study. The result showed that monometallic Ni/NH2-MS with surface area, total pore volume, nickel loading and average pore diameter 328.68 m2.g-1, 0.25 cm3.g-1, 1.90 wt%, 3.10 nm, respectively, exhibited the best performance in producing liquid hydrocarbon and generated higher level of liquid product (77.9 wt%) than bimetallic NiMo/NH2-MS (76.3 wt%). However, it is highlighted that adding 1.08 wt% of Mo in bimetallic NiMo/NH2-MS comprising 0.83 wt% of Ni improved the catalyst selectivity towards producing higher level of gasoline-range hydrocarbon (43 wt%). The bimetallic NiMo/NH2-MS prepared was found to have surface area, total pore volume, and average pore diameter of 325.13 m2.g-1, 0.14 cm3.g-1, 3.22 nm, respectively. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US">Universitas Gadjah Mada</dc:contributor>
	<dc:date>2020-08-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/7136</dc:identifier>
	<dc:identifier>10.9767/bcrec.15.2.7136.415-431</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2020: BCREC Volume 15 Issue 2 Year 2020 (August 2020); 415-431</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/7136/4020</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/7136/1692</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/7136/1693</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/7136/1694</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2020 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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