Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

Nurhasni, Nurhasni; Adawiah, Adawiah; Wahyudin, Wahyudin; Hadriyani, Rizka; Andriyani, Leni; Fadhilla, Rizkha; Zulys, Agustino; Sukandar, Dede

doi:10.9767/bcrec.20069

Akses terbuka Jurnal SINTA 1

Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2024) · hlm. 86–98

DOI: 10.9767/bcrec.20069
ISSN: 1978-2993
Terbit: 2024-04-30
Penerbit: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa: eng
Lisensi: creativecommons.org/licenses/by-sa/4.0

Abstrak

As an adsorbent material, Metal-Organic Framework (MOF) provides several advantages, such as large surface area and pore volume, as well as stability in aqueous systems both in acidic, basic, and neutral conditions. The research successfully made a metal organic framework (MOF) from chromium and perylene that was modulated by isonicotinic acid. This was done using three different methods: hydrothermal (Cr-PTC-HIna-HT), solvothermal (Cr-PTC-HIna-ST), and sonochemical (Cr-PTC-HIna-SC). The Cr-PTC-HIna-SC showed the greatest Pb2+ ion adsorption capacity. The optimum adsorption of Pb2+ ions occurred at 150 ppm Pb2+ ion concentration, pH 5, 90 minutes of contact time, and an adsorption capacity of 149.95 mg/g at 35 °C. The dominant adsorption isotherm model is the Langmuir isotherm model with R2 = 0.9867 and follows the pseudo-second-order. The selectivity test showed that Cr-PTC-HIna-SC MOF could adsorb more Cd2+ ions than Pb2+ ions, with 250 mg/g being the best amount.

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Syarif Hidayatullah State Islamic University Jakarta
University of Indonesia
National Nuclear Energy Agency of Indonesia
National Research and Innovation Agency
Pertamina (Indonesia)
Badan Pengkajian dan Penerapan Teknologi
Universitas Mathla'ul Anwar Banten
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Rekan penulis	Organisasi	Artikel bersama
Nanda Saridewi	Syarif Hidayatullah State Islamic University Jakarta	16
Siti Nurbayti	Syarif Hidayatullah State Islamic University Jakarta	11
Isalmi Aziz	Syarif Hidayatullah State Islamic University Jakarta	9
Nani Radiastuti	Syarif Hidayatullah State Islamic University Jakarta	5
Sandra Hermanto	Syarif Hidayatullah State Islamic University Jakarta	5
Anna Muawanah	Syarif Hidayatullah State Islamic University Jakarta	5
La Ode Sumarlin	Syarif Hidayatullah State Islamic University Jakarta	5
Sri Komala	Syarif Hidayatullah State Islamic University Jakarta	5
Latifah Tulhusna	Syarif Hidayatullah State Islamic University Jakarta	5
Hendrawati Hendrawati	Syarif Hidayatullah State Islamic University Jakarta	4
Eka Rizki Amelia	Syarif Hidayatullah State Islamic University Jakarta	4
Muhammad Shofyan Gunawan	Syarif Hidayatullah State Islamic University Jakarta	4
Jarnuzi Gunlazuardi	University of Indonesia	4
Muhammad Derry Luthfi Yudhi	University of Indonesia	4
Yulyani Nur Azizah	Syarif Hidayatullah State Islamic University Jakarta	4
Nubzah Saniyyah	Syarif Hidayatullah State Islamic University Jakarta	3
Ahmad Fathoni	Syarif Hidayatullah State Islamic University Jakarta	3
Wulandari Oktavia	Syarif Hidayatullah State Islamic University Jakarta	3
Farhan Maulana Azhar	Syarif Hidayatullah State Islamic University Jakarta	3
Risma Nur Fitria	Syarif Hidayatullah State Islamic University Jakarta	3
Tarso Rudiana	Universitas Mathla'ul Anwar Banten	3
Wawan Rustyawan	Pertamina (Indonesia)	3
Ira Jayanegara	Badan Pengkajian dan Penerapan Teknologi	2
Adeng Hudaya	Syarif Hidayatullah State Islamic University Jakarta	2
Sofnie M. Chairul	National Nuclear Energy Agency of Indonesia	2
Ade Candra	Syarif Hidayatullah State Islamic University Jakarta	1
Nur Ernita	Syarif Hidayatullah State Islamic University Jakarta	1
Teguh Wahyono	National Nuclear Energy Agency of Indonesia	1
Widhi Kurniawan	Universitas Halu Oleo	1
Rista Kurnia Dewi	Syarif Hidayatullah State Islamic University Jakarta	1
Sihono Sihono	National Nuclear Energy Agency of Indonesia	1
Fuady Hanief	Syarif Hidayatullah State Islamic University Jakarta	1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.

Metadata asli (oai_dc)

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	<dc:title xml:lang="en-US">Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption</dc:title>
	<dc:creator>Nurhasni, Nurhasni</dc:creator>
	<dc:creator>Adawiah, Adawiah</dc:creator>
	<dc:creator>Wahyudin, Wahyudin</dc:creator>
	<dc:creator>Hadriyani, Rizka</dc:creator>
	<dc:creator>Andriyani, Leni</dc:creator>
	<dc:creator>Fadhilla, Rizkha</dc:creator>
	<dc:creator>Zulys, Agustino</dc:creator>
	<dc:creator>Sukandar, Dede</dc:creator>
	<dc:subject xml:lang="en-US">Adsorbent; Cd2+; Pb2+; Cr-PTC-HIna; sonochemical</dc:subject>
	<dc:description xml:lang="en-US">As an adsorbent material, Metal-Organic Framework (MOF) provides several advantages, such as large surface area and pore volume, as well as stability in aqueous systems both in acidic, basic, and neutral conditions. The research successfully made a metal organic framework (MOF) from chromium and perylene that was modulated by isonicotinic acid. This was done using three different methods: hydrothermal (Cr-PTC-HIna-HT), solvothermal (Cr-PTC-HIna-ST), and sonochemical (Cr-PTC-HIna-SC). The Cr-PTC-HIna-SC showed the greatest Pb2+ ion adsorption capacity. The optimum adsorption of Pb2+ ions occurred at 150 ppm Pb2+ ion concentration, pH 5, 90 minutes of contact time, and an adsorption capacity of 149.95 mg/g at 35 °C. The dominant adsorption isotherm model is the Langmuir isotherm model with R2 = 0.9867 and follows the pseudo-second-order. The selectivity test showed that Cr-PTC-HIna-SC MOF could adsorb more Cd2+ ions than Pb2+ ions, with 250 mg/g being the best amount.</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2024-04-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/20069</dc:identifier>
	<dc:identifier>10.9767/bcrec.20069</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2024: BCREC Volume 19 Issue 1 Year 2024 (April 2024); 86-98</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/20069/9684</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2024 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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