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Bio-kerosene and Bio-gasoil from Coconut Oils via Hydrocracking Process over Ni-Fe/HZSM-5 Catalyst

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2019) · hlm. 309–319

DOI
10.9767/bcrec.14.2.2669.309-319
ISSN
1978-2993
Terbit
2019-08-01
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

In this study, hydrocracking of coconut oil over Ni-Fe/HZSM-5 catalyst was carried out in a batch reactor under different reaction temperature. Coconut oil is proposed as one of the potential feedstock for biofuel production. The Ni-Fe/HZSM-5 catalyst was prepared by incipient wetness impregnation method. The characterization of Ni-Fe/HZSM-5 catalyst by X-Ray Diffraction (XRD), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDAX), and Brunauer-Emmett-Teller (BET). The chemical composition of biofuel was analyzed by Gas-Chromatography-Mass Spectrometry (GC-MS). The results from the GC-MS analysis showed that the hydrocracking reaction over 10 % (Ni-Fe)/HZSM-5 catalyst at temperature of 375 oC obtained the highest hydrocarbon content (contained 49.4% n-paraffin, 26.93 % isoparaffin, 3.58 % olefin) and the highest yield of bio-gasoil 38.6 % in the biofuel liquid hydrocarbon. Pentadecane (n-C15) and heptadecane (n-C17) were the most abundant hydrocarbon compounds in biofuel liquid hydrocarbon. Decarboxylation and/or decarbonylation was the dominant reaction pathways in this process. Based on the result, the reaction temperature had a significant effect on the distribution of biofuel composition and yield of biofuel from coconut oil.

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  • Institut Teknologi Sepuluh Nopember
  • National Research and Innovation Agency
  • Sriwijaya University
  • Indonesian Institute of Sciences
  • Institut Teknologi Kalimantan
  • Universitas Jambi
  • State University of Jakarta
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Rekan penulisOrganisasiArtikel bersama
Lenny MarlindaUniversitas Jambi10
Hasanudin HasanudinSriwijaya University4
Mahfud MahfudInstitut Teknologi Sepuluh Nopember4
Abdul AzizInstitut Teknologi Sepuluh Nopember4
Roni MaryanaIndonesian Institute of Sciences3
Wan Ryan AsriSriwijaya University3
Nino RinaldiNational Research and Innovation Agency3
Novia NoviaSriwijaya University3
Indri YatiNational Research and Innovation Agency3
Maja Pranata MarbunAfiliasi tidak diketahui3
Fahma RiyantiSriwijaya University2
Fitri HadiahSriwijaya University2
Peri OktiarmiUniversitas Jambi2
Sugeng PriyantoState University of Jakarta2
Sudibyo SudibyoNational Research and Innovation Agency2
Suprapto SupraptoInstitut Teknologi Sepuluh Nopember2
Nyoman Puspa AsriInstitut Teknologi Sepuluh Nopember2
Kusno BudikarjonoInstitut Teknologi Sepuluh Nopember2
Rismawati RasyidUniversitas Muslim Indonesia2
Yusup HendronursitoNational Research and Innovation Agency2
Kusno IsnugrohoIndonesian Institute of Sciences2
David Candra BirawidhaIndonesian Institute of Sciences2
Rahmawati RahmawatiSamudra University1
Erik Budi SantikoNational Research and Innovation Agency1
Sarah Nur FauziahUniversitas Muhammadiyah Jakarta1
Yustinah YustinahUniversitas Muhammadiyah Jakarta1
S. SudibyoNational Research and Innovation Agency1
Sugeng PriyantoState University of Jakarta1
Tri MaryaniUniversitas Semarang1
Triastuti SulistyaningsihState University of Semarang1
Andreas SibueaLampung University1
Wasinton SimanjuntakLampung University1
Fuad SyafaatInstitut Teknologi Kalimantan1
Havier Samuel Huttur Silalahi RajaInstitut Teknologi Kalimantan1
Riza AlvianyInstitut Teknologi Kalimantan1
Erik PrasetyoIndonesian Institute of Sciences1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en-US">Bio-kerosene and Bio-gasoil from Coconut Oils via Hydrocracking Process over Ni-Fe/HZSM-5 Catalyst</dc:title>
	<dc:creator>Al-Muttaqii, Muhammad</dc:creator>
	<dc:creator>Kurniawansyah, Firman</dc:creator>
	<dc:creator>Prajitno, Danawati Hari</dc:creator>
	<dc:creator>Roesyadi, Achmad</dc:creator>
	<dc:subject xml:lang="en-US">Hydrocracking; coconut oil; Ni-Fe/HZSM-5 catalyst; n-paraffin</dc:subject>
	<dc:description xml:lang="en-US">In this study, hydrocracking of coconut oil over Ni-Fe/HZSM-5 catalyst was carried out in a batch reactor under different reaction temperature. Coconut oil is proposed as one of the potential feedstock for biofuel production. The Ni-Fe/HZSM-5 catalyst was prepared by incipient wetness impregnation method. The characterization of Ni-Fe/HZSM-5 catalyst by X-Ray Diffraction (XRD), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDAX), and Brunauer-Emmett-Teller (BET). The chemical composition of biofuel was analyzed by Gas-Chromatography-Mass Spectrometry (GC-MS). The results from the GC-MS analysis showed that the hydrocracking reaction over 10 % (Ni-Fe)/HZSM-5 catalyst at temperature of 375 oC obtained the highest hydrocarbon content (contained 49.4% n-paraffin, 26.93 % isoparaffin, 3.58 % olefin) and the highest yield of bio-gasoil 38.6 % in the biofuel liquid hydrocarbon. Pentadecane (n-C15) and heptadecane (n-C17) were the most abundant hydrocarbon compounds in biofuel liquid hydrocarbon. Decarboxylation and/or decarbonylation was the dominant reaction pathways in this process. Based on the result, the reaction temperature had a significant effect on the distribution of biofuel composition and yield of biofuel from coconut oil.</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US">DRPM, Directorate General of Research and Development, the Ministry of research, Technology and Higher Education of Indonesia</dc:contributor>
	<dc:date>2019-08-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/2669</dc:identifier>
	<dc:identifier>10.9767/bcrec.14.2.2669.309-319</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2019: BCREC Volume 14 Issue 2 Year 2019 (August 2019); 309-319</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/2669/2422</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2019 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>