Akses terbuka Jurnal SINTA 1
Electro-Catalysis System for Biodiesel Synthesis from Palm Oil over Dielectric-Barrier Discharge Plasma Reactor
Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2014) · hlm. 111–120
- ISSN
- 1978-2993
- Terbit
- 2014-08-30
- Penerbit
- Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
- Bahasa
- eng
Abstrak
Biodiesel synthesis reaction routes from palm oil using plasma electro-catalysis process over Dielectric-Barrier Discharge (DBD) plasma reactor were studied. The study was focused on finding possible reaction mechanism route during plasma electro-catalysis process. The prediction was performed based on the changes of Gas Chromatography Mass Spectrometer (GC-MS) and Fourier Transform Infra Red (FT-IR) analyses to the biodiesel products with respect to time length of plasma treatment. It was found that main reaction mechanism occurred in the plasma electro-catalysis system was non-thermal pyrolysis rather than transesterification. The main reactions within the plasma treatment were due to collision between high energetic electrons (supplied from high voltage power supply through high voltage electrode) and the reaction mixtures. The high energetic electrons affected the electrons pair of covalent bonding to be excited or dissociated even ionized at higher energy. Therefore, this plasma electro-catalysis system was promising for biodiesel synthesis from vegetable oils due to only very short time reaction was needed, even no need a catalyst, no soap formation, and no glycerol by-product. This system could produce fatty acid methyl ester yield of 75.65% at 120 seconds and other possible chemicals, such as alkynes, alkanes, esters, carboxylic acid, and aldehydes. However, during the plasma process, the reaction mechanisms were still difficult to be controlled due the action of available high energetic electrons. The advanced studies on how to control the reaction mechanism selectively in the plasma electro-catalysis will be published elsewhere. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
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- Diponegoro University
- Universiti Teknologi MARA
- University of Technology Malaysia
- Universitas PGRI Semarang
- Muhammadiyah University of Surakarta
- Organisasi berbeda
- Organisasi sama
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Tampilkan sebagai tabel
| Rekan penulis | Organisasi | Artikel bersama |
|---|---|---|
| Teguh Riyanto | Diponegoro University | 9 |
| Purwanto Purwanto | Diponegoro University | 7 |
| Nor Aishah Saidina Amin | University of Technology Malaysia | 4 |
| Brilliant Umara Le Monde | Diponegoro University | 4 |
| I. Istadi | Diponegoro University | 4 |
| Udin Mabruro | Diponegoro University | 3 |
| Bintang Ayu Kalimantini | Diponegoro University | 3 |
| Utami Inshani | Diponegoro University | 3 |
| Roikhatus Solikhah | Diponegoro University | 3 |
| Giveni Christina Silaen | Diponegoro University | 2 |
| Resti Nur Utami | Diponegoro University | 2 |
| Dorothy Hoo Wei Ling | University of Technology Malaysia | 2 |
| Nur Hidayati | Muhammadiyah University of Surakarta | 2 |
| Yayuk Mundriyastutik | Diponegoro University | 2 |
| Setia Budi Sasongko | Diponegoro University | 2 |
| Herawati Oktavianty | Diponegoro University | 2 |
| Indro Sumantri | Diponegoro University | 2 |
| Riko Rikardo Putra | Diponegoro University | 2 |
| Cokorda Satrya Pramana | Diponegoro University | 2 |
| Amalia Rizqi Ramadhani | Diponegoro University | 2 |
| Widayat Widayat | Diponegoro University | 2 |
| Hermawan Hermawan | Diponegoro University | 1 |
| Slamet Supriyadi | Universitas PGRI Semarang | 1 |
| Nurul Asyikin Yusof | Universiti Teknologi MARA | 1 |
| Aizah Jamarudin | Universiti Teknologi MARA | 1 |
| Muzakkir Mohammad Zainol | Universiti Teknologi MARA | 1 |
| Abdull Hafidz Hassan | Universiti Teknologi MARA | 1 |
| Siti Norazian Ismail | Universiti Teknologi MARA | 1 |
| Mohd Asmadi | University of Technology Malaysia | 1 |
| Kamarul Ridwan Zainuddin | Universiti Teknologi MARA | 1 |
| Suherman Suherman | Diponegoro University | 1 |
| Bambang Pramudono | Diponegoro University | 1 |
| Slamet Priyanto | Diponegoro University | 1 |
| Kamsi Nur Oktavia | Diponegoro University | 1 |
| New Pei Yee | University of Technology Malaysia | 1 |
| Heri Mulyanti | Diponegoro University | 1 |
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