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Electro-Catalysis System for Biodiesel Synthesis from Palm Oil over Dielectric-Barrier Discharge Plasma Reactor

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2014) · hlm. 111–120

DOI
10.9767/bcrec.9.2.6090.111-120
ISSN
1978-2993
Terbit
2014-08-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Biodiesel synthesis reaction routes from palm oil using plasma electro-catalysis process over Dielectric-Barrier Discharge (DBD) plasma reactor were studied. The study was focused on finding possible reaction mechanism route during plasma electro-catalysis process. The prediction was performed based on the changes of Gas Chromatography Mass Spectrometer (GC-MS) and Fourier Transform Infra Red (FT-IR) analyses to the biodiesel products with respect to time length of plasma treatment. It was found that main reaction mechanism occurred in the plasma electro-catalysis system was non-thermal pyrolysis rather than transesterification. The main reactions within the plasma treatment were due to collision between high energetic electrons (supplied from high voltage power supply through high voltage electrode) and the reaction mixtures. The high energetic electrons affected the electrons pair of covalent bonding to be excited or dissociated even ionized at higher energy. Therefore, this plasma electro-catalysis system was promising for biodiesel synthesis from vegetable oils due to only very short time reaction was needed, even no need a catalyst, no soap formation, and no glycerol by-product. This system could produce fatty acid methyl ester yield of 75.65% at 120 seconds and other possible chemicals, such as alkynes, alkanes, esters, carboxylic acid, and aldehydes. However, during the plasma process, the reaction mechanisms were still difficult to be controlled due the action of available high energetic electrons. The advanced studies on how to control the reaction mechanism selectively in the plasma electro-catalysis will be published elsewhere. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

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  • Diponegoro University
  • Universiti Teknologi MARA
  • University of Technology Malaysia
  • Universitas PGRI Semarang
  • Muhammadiyah University of Surakarta
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Rekan penulisOrganisasiArtikel bersama
Teguh RiyantoDiponegoro University9
Purwanto PurwantoDiponegoro University7
Nor Aishah Saidina AminUniversity of Technology Malaysia4
Brilliant Umara Le MondeDiponegoro University4
I. IstadiDiponegoro University4
Udin MabruroDiponegoro University3
Bintang Ayu KalimantiniDiponegoro University3
Utami InshaniDiponegoro University3
Roikhatus SolikhahDiponegoro University3
Giveni Christina SilaenDiponegoro University2
Resti Nur UtamiDiponegoro University2
Dorothy Hoo Wei LingUniversity of Technology Malaysia2
Nur HidayatiMuhammadiyah University of Surakarta2
Yayuk MundriyastutikDiponegoro University2
Setia Budi SasongkoDiponegoro University2
Herawati OktaviantyDiponegoro University2
Indro SumantriDiponegoro University2
Riko Rikardo PutraDiponegoro University2
Cokorda Satrya PramanaDiponegoro University2
Amalia Rizqi RamadhaniDiponegoro University2
Widayat WidayatDiponegoro University2
Hermawan HermawanDiponegoro University1
Slamet SupriyadiUniversitas PGRI Semarang1
Nurul Asyikin YusofUniversiti Teknologi MARA1
Aizah JamarudinUniversiti Teknologi MARA1
Muzakkir Mohammad ZainolUniversiti Teknologi MARA1
Abdull Hafidz HassanUniversiti Teknologi MARA1
Siti Norazian IsmailUniversiti Teknologi MARA1
Mohd AsmadiUniversity of Technology Malaysia1
Kamarul Ridwan ZainuddinUniversiti Teknologi MARA1
Suherman SuhermanDiponegoro University1
Bambang PramudonoDiponegoro University1
Slamet PriyantoDiponegoro University1
Kamsi Nur OktaviaDiponegoro University1
New Pei YeeUniversity of Technology Malaysia1
Heri MulyantiDiponegoro University1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en-US">Electro-Catalysis System for Biodiesel Synthesis from Palm Oil over Dielectric-Barrier Discharge Plasma Reactor</dc:title>
	<dc:creator>Istadi, Istadi</dc:creator>
	<dc:creator>Yudhistira, Ardian D.</dc:creator>
	<dc:creator>Anggoro, Didi D.</dc:creator>
	<dc:creator>Buchori, Luqman</dc:creator>
	<dc:subject xml:lang="en-US">plasma; electro-catalysis; biodiesel; transesterification; cracking; energetic electrons</dc:subject>
	<dc:description xml:lang="en-US">Biodiesel synthesis reaction routes from palm oil using plasma electro-catalysis process over Dielectric-Barrier Discharge (DBD) plasma reactor were studied. The study was focused on finding possible reaction mechanism route during plasma electro-catalysis process. The prediction was performed based on the changes of Gas Chromatography Mass Spectrometer (GC-MS) and Fourier Transform Infra Red (FT-IR) analyses to the biodiesel products with respect to time length of plasma treatment. It was found that main reaction mechanism occurred in the plasma electro-catalysis system was non-thermal pyrolysis rather than transesterification. The main reactions within the plasma treatment were due to collision between high energetic electrons (supplied from high voltage power supply through high voltage electrode) and the reaction mixtures. The high energetic electrons affected the electrons pair of covalent bonding to be excited or dissociated even ionized at higher energy. Therefore, this plasma electro-catalysis system was promising for biodiesel synthesis from vegetable oils due to only very short time reaction was needed, even no need a catalyst, no soap formation, and no glycerol by-product. This system could produce fatty acid methyl ester yield of 75.65% at 120 seconds and other possible chemicals, such as alkynes, alkanes, esters, carboxylic acid, and aldehydes. However, during the plasma process, the reaction mechanisms were still difficult to be controlled due the action of available high energetic electrons. The advanced studies on how to control the reaction mechanism selectively in the plasma electro-catalysis will be published elsewhere. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US">Directorate General of Higher Education (DIKTI) Republic of Indonesia|Hibah Kompetensi No. 314b-5/UN7.5/PG/2013</dc:contributor>
	<dc:date>2014-08-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/19452</dc:identifier>
	<dc:identifier>10.9767/bcrec.9.2.6090.111-120</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2014: BCREC Volume 9 Issue 2 Year 2014 (August 2014); 111-120</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/19452/9362</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2014 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>