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Self-Polymerization Reaction of Epoxidized Oleic Acid: Kinetic and Product Characterization

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2023) · hlm. 386–397

DOI
10.9767/bcrec.19251
ISSN
1978-2993
Terbit
2023-10-15
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Epoxidized oleic acid can be transformed into vegetable oil-based polyesters through a self-polymerization reaction. This study aims to develop the kinetic model for the polymerization reaction between epoxide and carboxyl groups and the product characterization regarding its functional groups, molecular weight, and thermal stability. The polymerization reaction was carried out at the temperature of 120–180 °C for 2–6 h with the highest conversion of oxirane number up to 97%. Kinetic study showed one-step reaction model between oxirane and carboxylic group gives the activation energy value of 34.71 kJ/mol. Furthermore, the two simultaneous reaction model with further reaction between oxirane group and hydroxyl group also taken into account. The later provides a better agreement between the experimental data and the calculated conversion value. The activation energy values in the first and second steps are 38.61 and 26.00 kJ/mol, respectively. The product characterization showed that adding adipic acid did not significantly affect the polymer's molecular weight and thermal stability. The polydisperse characteristics of the poly(oleic acid) produced in this study enable poly(oleic acid) to be used as a lubricant, a polymer additive, or a precursor to produce polymers with higher molecular weights by taking advantage of the accessibility of OH groups. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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  • Universitas Gadjah Mada
  • Universitas Ahmad Dahlan
  • State University of Semarang
  • Sebelas Maret University
  • National Nuclear Energy Agency of Indonesia
  • Islamic University of Indonesia
  • Diponegoro University
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Rekan penulisOrganisasiArtikel bersama
Budhijanto BudhijantoUniversitas Gadjah Mada7
Eko Agus SuyonoUniversitas Gadjah Mada6
Siti JamilatunUniversitas Ahmad Dahlan4
Eni BudiyatiMuhammadiyah University of Surakarta4
Wusana Agung WibowoSebelas Maret University4
Rochim Bakti CahyonoUniversitas Gadjah Mada4
Hadiyanto HadiyantoDiponegoro University3
Ratna Dewi KusumaningtyasState University of Semarang3
Muhammad Mufti AzisUniversitas Gadjah Mada3
Suryo PurwonoUniversitas Gadjah Mada3
Ulfah Juniarti SiregarIPB University2
Lucia Tri SuwantiUniversitas Airlangga2
Tia ErfiantiUniversitas Gadjah Mada2
Meutia Ermina ToifUniversitas Gadjah Mada2
Muslikhin HidayatUniversitas Gadjah Mada2
Retno RingganiUniversitas Gadjah Mada2
Hartini HartiniUniversitas Halu Oleo2
Yeni ElisthatianaUniversitas Ahmad Dahlan1
Siti Nurhalizatul AiniUniversitas Ahmad Dahlan1
Ilham MufandiKhon Kaen University1
Kris Tri BasukiNational Nuclear Energy Agency of Indonesia1
Deni SwantomoNational Nuclear Energy Agency of Indonesia1
Rahman SudiyoUniversitas Gadjah Mada1
Imam Novrizal AjiState University of Semarang1
Imam PrasetyoUniversitas Gadjah Mada1
Dhea Atika RisnawatiSekolah Tinggi Teknologi Bontang1
Nova Yoga PradanaUniversitas Gadjah Mada1
Daffa Dewa SaputraUniversitas Gadjah Mada1
Hardaning PranamudaAfiliasi tidak diketahui1
Sugianto TandioAfiliasi tidak diketahui1
Teguh AriyantoUniversitas Gadjah Mada1
Dwi Indah LestariSebelas Maret University1
Ahmad Tawfiequrrahman YuliansyahUniversitas Gadjah Mada1
Andhika Puspito NugrohoUniversitas Gadjah Mada1
Angga Puja AsianduUniversitas Gadjah Mada1
R. RochmadiUniversitas Gadjah Mada1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Self-Polymerization Reaction of Epoxidized Oleic Acid: Kinetic and Product Characterization</dc:title>
	<dc:creator>Sawitri, Dyah Retno</dc:creator>
	<dc:creator>Mulyono, Panut</dc:creator>
	<dc:creator>Rochmadi, Rochmadi</dc:creator>
	<dc:creator>Budiman, Arief</dc:creator>
	<dc:subject xml:lang="en-US">Poly(oleic acid); Step-growth Polymerization Kinetic; Ring-opening polymerization; Vegetable Oil-based Polyester</dc:subject>
	<dc:description xml:lang="en-US">Epoxidized oleic acid can be transformed into vegetable oil-based polyesters through a self-polymerization reaction. This study aims to develop the kinetic model for the polymerization reaction between epoxide and carboxyl groups and the product characterization regarding its functional groups, molecular weight, and thermal stability. The polymerization reaction was carried out at the temperature of 120–180 °C for 2–6 h with the highest conversion of oxirane number up to 97%. Kinetic study showed one-step reaction model between oxirane and carboxylic group gives the activation energy value of 34.71 kJ/mol. Furthermore, the two simultaneous reaction model with further reaction between oxirane group and hydroxyl group also taken into account. The later provides a better agreement between the experimental data and the calculated conversion value. The activation energy values in the first and second steps are 38.61 and 26.00 kJ/mol, respectively. The product characterization showed that adding adipic acid did not significantly affect the polymer's molecular weight and thermal stability. The polydisperse characteristics of the poly(oleic acid) produced in this study enable poly(oleic acid) to be used as a lubricant, a polymer additive, or a precursor to produce polymers with higher molecular weights by taking advantage of the accessibility of OH groups. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2023-10-15</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/19251</dc:identifier>
	<dc:identifier>10.9767/bcrec.19251</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2023: BCREC Volume 18 Issue 3 Year 2023 (October 2023); 386-397</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/19251/9636</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/19251/4809</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/19251/4810</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/19251/4811</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2023 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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