Melola Discovery

← Melola Discovery

Akses terbuka Jurnal SINTA 1

High Acidity and Low Carbon-Coke Formation Affinity of Co-Ni/ZSM-5 Catalyst for Renewable Liquid Fuels Production through Simultaneous Cracking-Deoxygenation of Palm Oil

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2023) · hlm. 222–237

DOI
10.9767/bcrec.17974
ISSN
1978-2993
Terbit
2023-07-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

This study investigates the effect of chemically doped Co and Ni metals on ZSM-5 catalyst with respect to the catalysts’ characteristics and performance for palm oil cracking. Some characterization methods have been conducted to identify the physicochemical properties of the synthesized catalysts, including X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), N2-physisorption, NH3- and CO2-probed Temperature Programmed Desorption (NH3-TPD and CO2-TPD) methods. The deposited carbon-coke on the spent catalysts is analysed using simultaneous thermal gravimetric – differential scanning calorimetry (TG-DTG-DSC) analysis. The performance of catalysts was evaluated on palm oil cracking process in a continuous fixed-bed catalytic reactor at 450 °C. To determine the liquid product composition functional group and components, we used Attenuated Total Reflectance Fourier-transform Infrared Spectroscopy (ATR-FTIR) and batch distillation methods, respectively. We found that the Co metal chemically-doped on Ni/SM-5 catalyst, resulting the increase in the catalysts acidity and the decrease in catalysts basicity. The conversion of palm oil increases as the increase of the ratio of catalysts’ acidity to basicity. The highest triglyceride conversion (76.5%) was obtained on the 3Co-Ni/ZSM-5 with the yield of gasoline, kerosene, and diesel of 2.61%, 4.38%, and 61.75%, respectively. It was also found that the chemically doping Co metal on Ni/ZSM-5 catalyst decreased carbon-coke formation due to the low catalysts’ basicity. Overall, it is proven that the combination of Co and Ni, which chemically doped, on ZSM-5 catalyst has a good activity in palm oil conversion with low carbon-coke formation affinity and high acidity of catalyst.

Kata kunci

Jaringan kolaborasi para penulis

40 penulis · 114 tautan kepenulisan bersama · menampilkan 40 yang paling banyak terhubung

Arahkan kursor atau ketuk sebuah nama untuk menyorot rekan penulisnya. Klik dua kali untuk membuka halaman penulis.

  • Cenderawasih University
  • Afiliasi tidak diketahui
  • Organisasi berbeda
  • Organisasi sama
  • Afiliasi tidak diketahui
  • Garis lebih tebal = lebih banyak artikel bersama · lingkaran lebih besar = lebih banyak artikel
Tampilkan sebagai tabel
Rekan penulisOrganisasiArtikel bersama
Luqman BuchoriAfiliasi tidak diketahui19
Didi D. AnggoroAfiliasi tidak diketahui4
Purwanto PurwantoCenderawasih University4
Brilliant Umara Le MondeAfiliasi tidak diketahui3
I. IstadiAfiliasi tidak diketahui3
Nor Aishah Saidina AminAfiliasi tidak diketahui2
Udin MabruroAfiliasi tidak diketahui2
Bintang Ayu KalimantiniAfiliasi tidak diketahui2
Aji PrasetyaningrumAfiliasi tidak diketahui2
Nur RokhatiAfiliasi tidak diketahui2
Slamet SupriyadiAfiliasi tidak diketahui1
Hermawan HermawanAfiliasi tidak diketahui1
Aizah JamarudinAfiliasi tidak diketahui1
Muzakkir Mohammad ZainolAfiliasi tidak diketahui1
Abdull Hafidz HassanAfiliasi tidak diketahui1
Siti Norazian IsmailAfiliasi tidak diketahui1
Mohd AsmadiAfiliasi tidak diketahui1
Kamarul Ridwan ZainuddinAfiliasi tidak diketahui1
Nurul Asyikin YusofAfiliasi tidak diketahui1
Giveni Christina SilaenAfiliasi tidak diketahui1
Resti Nur UtamiAfiliasi tidak diketahui1
Dorothy Hoo Wei LingAfiliasi tidak diketahui1
Suherman SuhermanAfiliasi tidak diketahui1
N. A. S. AminAfiliasi tidak diketahui1
Nur HidayatiAfiliasi tidak diketahui1
Yayuk MundriyastutikAfiliasi tidak diketahui1
Inshani UtamiAfiliasi tidak diketahui1
Roikhatus SolikhahAfiliasi tidak diketahui1
Setia Budi SasongkoAfiliasi tidak diketahui1
Herawati OktaviantyAfiliasi tidak diketahui1
Ardian D. YudhistiraAfiliasi tidak diketahui1
Indro SumantriAfiliasi tidak diketahui1
Riko Rikardo PutraAfiliasi tidak diketahui1
Bambang PramudonoAfiliasi tidak diketahui1
Suherman SuhermanAfiliasi tidak diketahui1

Afiliasi berasal dari OpenAlex; metadata OAI-PMH jurnal tidak memuatnya. Penulis tanpa ID OpenAlex dicocokkan berdasarkan nama, sehingga dua orang bisa tergabung atau satu orang bisa terpisah.

Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en-US">High Acidity and Low Carbon-Coke Formation Affinity of Co-Ni/ZSM-5 Catalyst for Renewable Liquid Fuels Production through Simultaneous Cracking-Deoxygenation of Palm Oil</dc:title>
	<dc:creator>Istadi, Istadi</dc:creator>
	<dc:creator>Riyanto, Teguh</dc:creator>
	<dc:creator>Anggoro, Didi Dwi</dc:creator>
	<dc:creator>Pramana, Cokorda Satrya</dc:creator>
	<dc:creator>Ramadhani, Amalia Rizqi</dc:creator>
	<dc:subject xml:lang="en-US">Palm oil; Biofuels; Carbon-Coke formation; Cracking; Deoxygenation; Acidity; Basicity; Chemically doped</dc:subject>
	<dc:description xml:lang="en-US">This study investigates the effect of chemically doped Co and Ni metals on ZSM-5 catalyst with respect to the catalysts’ characteristics and performance for palm oil cracking. Some characterization methods have been conducted to identify the physicochemical properties of the synthesized catalysts, including X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), N2-physisorption, NH3- and CO2-probed Temperature Programmed Desorption (NH3-TPD and CO2-TPD) methods. The deposited carbon-coke on the spent catalysts is analysed using simultaneous thermal gravimetric – differential scanning calorimetry (TG-DTG-DSC) analysis. The performance of catalysts was evaluated on palm oil cracking process in a continuous fixed-bed catalytic reactor at 450 °C. To determine the liquid product composition functional group and components, we used Attenuated Total Reflectance Fourier-transform Infrared Spectroscopy (ATR-FTIR) and batch distillation methods, respectively. We found that the Co metal chemically-doped on Ni/SM-5 catalyst, resulting the increase in the catalysts acidity and the decrease in catalysts basicity. The conversion of palm oil increases as the increase of the ratio of catalysts’ acidity to basicity. The highest triglyceride conversion (76.5%) was obtained on the 3Co-Ni/ZSM-5 with the yield of gasoline, kerosene, and diesel of 2.61%, 4.38%, and 61.75%, respectively. It was also found that the chemically doping Co metal on Ni/ZSM-5 catalyst decreased carbon-coke formation due to the low catalysts’ basicity. Overall, it is proven that the combination of Co and Ni, which chemically doped, on ZSM-5 catalyst has a good activity in palm oil conversion with low carbon-coke formation affinity and high acidity of catalyst.</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2023-07-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/17974</dc:identifier>
	<dc:identifier>10.9767/bcrec.17974</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2023: BCREC Volume 18 Issue 2 Year 2023 (August 2023); 222-237</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/17974/8857</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2023 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>