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Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application

International Journal of Renewable Energy Development : JRED · Vol. 6 No. 2 (2017) · hlm. 165–170

DOI
10.14710/ijred.2017.13338
ISSN
2252-4940
Terbit
2017-06-25
Penerbit
Center of Biomass & Renewable Energy (CBIORE)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Direct methanol fuel cell (DMFC) is one of several types of fuel cells that use proton exchange membrane (PEM) as a liaison between the reaction at the cathode and anode. Polyether-ether ketone (PEEK) is one of the aromatic polymer that can be applied in DMFC because of its characteristics that are resistant to DMFC environment. The polymer is also quite easy in the sulfonation process using concentrated sulfuric acid. However the role of polyether-ether ketone as DMFC membrane material is still lack of advantage due to its low conductivity and therefore the modification is required to increase the value of proton conductivity of the membrane. The purpose of this experiment is to modify the membrane (sPEEK) with the addition of cyclodextrins-silica, additive variation charge of 2%, 6% and 10%, time and temperature were fixed at 4 hours and 65oC. The results showed the best results of membrane sPEEK was obtained at the addition of -cyclodextrin -silica 10% with the membrane characteristics of ion exchange capacity of 2.19 meq / g polymer, the degree of sulfonation of 81%, methanol permeability of 3.09 x 10-9 cm2 / s and water uptake membrane of 64%.Article History: Received January 18th 2017; Received in revised form April 21st 2017; Accepted June 22nd 2017; Available onlineHow to Cite This Article: Kusworo, T.D., Hakim, M.F. and Hadiyanto, H. (2017) Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application. International Journal of Renewable Energy Development, 6(2), 165-170.https://doi.org/10.14710/ijred.6.2.165-170

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  • Diponegoro University
  • Muhammadiyah University of Surakarta
  • State University of Semarang
  • Universitas Gadjah Mada
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  • University of Shahrood
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Rekan penulisOrganisasiArtikel bersama
Widayat WidayatDiponegoro University5
Marcelinus ChristwardanaInstitut Teknologi Indonesia5
Kusmiyati KusmiyatiMuhammadiyah University of Surakarta4
Arief Taufik BudimanUniversitas Gadjah Mada3
Abdullah AbdullahDiponegoro University2
Dessy AriyantiDiponegoro University2
Muhamad Maulana Azimatun NurDiponegoro University2
Apsari Puspita AiniDiponegoro University2
Mohammad Hossein AhmadiUniversity of Shahrood2
Andri Cahyo KumoroDiponegoro University2
Rita Dwi RatnaniUniversitas Wahid Hasyim1
W. WidiyantoDiponegoro University1
M. A. AdhiState University of Semarang1
Fira RahmawatiAfiliasi tidak diketahui1
Kamilah Pathun Ni’mahAfiliasi tidak diketahui1
Prima Astuti HandayaniState University of Semarang1
Ratna Dewi KusumaningtyasState University of Semarang1
Imam Novrizal AjiState University of Semarang1
Dani Puji UtomoDiponegoro University1
Adalia VedaDiponegoro University1
Rafi MafazanDiponegoro University1
Meitri Bella PuspaDiponegoro University1
Dita Aulia AzizahDiponegoro University1
Sri Puji LestariDiponegoro University1
Indro SumantriDiponegoro University1
Sakina Tunissa AnarkiMuhammadiyah University of Surakarta1
Sabda Wahyu NugrohoMuhammadiyah University of Surakarta1
Reistu WidiastutikMuhammadiyah University of Surakarta1
Heri SutantoDiponegoro University1
Fatkhiyatus Sa’adahDiponegoro University1
Ilham AlkianDiponegoro University1
Sri Rezki Mardiah SyamDiponegoro University1
B. BudiyonoDiponegoro University1
Hamid HamidDiponegoro University1
Ganang Dwi HartantoDiponegoro University1
Siti JamilatunUniversitas Ahmad Dahlan1
Budhijanto BudhijantoUniversitas Gadjah Mada1

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Sumber metadata: OAI-PMH (metadata jurnal) https://ijred.cbiore.id/index.php/ijred/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application</dc:title>
	<dc:creator>Kusworo, Tutuk Djoko</dc:creator>
	<dc:creator>Hakim, Muhammad Fahmi</dc:creator>
	<dc:creator>Hadiyanto, H</dc:creator>
	<dc:subject xml:lang="en-US">Direct Methanol Fuel Cell, Poly(ether ether ketone), cyclodextrin-silica, sulfonation, ionic conductivity</dc:subject>
	<dc:description xml:lang="en-US">Direct methanol fuel cell (DMFC) is one of several types of fuel cells that use proton exchange membrane  (PEM) as a liaison between the reaction at the cathode and anode. Polyether-ether ketone (PEEK) is one of the aromatic polymer that can be applied in DMFC because of its characteristics that are resistant to DMFC environment. The polymer is also quite easy in the sulfonation process using concentrated sulfuric acid. However the role of polyether-ether ketone as DMFC membrane material is still lack of advantage due to its low conductivity and therefore the modification is required to increase the value of proton conductivity of the membrane. The purpose of this experiment is to modify the membrane (sPEEK) with the addition of cyclodextrins-silica, additive variation charge of 2%, 6% and 10%, time and temperature were fixed at 4 hours and 65oC. The results showed the best results of membrane sPEEK was obtained at the addition of -cyclodextrin -silica 10% with the membrane characteristics of ion exchange capacity of 2.19 meq / g polymer, the degree of sulfonation of 81%, methanol permeability of 3.09 x 10-9 cm2 / s and water uptake membrane of 64%.Article History: Received January 18th 2017; Received in revised form April 21st 2017; Accepted June 22nd 2017; Available onlineHow to Cite This Article: Kusworo, T.D., Hakim, M.F. and Hadiyanto, H. (2017) Enhancement of Hybrid SPEEK Based Polymer–Cyclodextrin-Silica Inorganic Membrane for Direct Methanol Fuel Cell Application. International Journal of Renewable Energy Development, 6(2), 165-170.https://doi.org/10.14710/ijred.6.2.165-170</dc:description>
	<dc:publisher xml:lang="en-US">Center of Biomass &amp; Renewable Energy (CBIORE)</dc:publisher>
	<dc:contributor xml:lang="en-US"></dc:contributor>
	<dc:date>2017-06-25</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://ijred.cbiore.id/index.php/ijred/article/view/13338</dc:identifier>
	<dc:identifier>10.14710/ijred.2017.13338</dc:identifier>
	<dc:source xml:lang="en-US">International Journal of Renewable Energy Development; Vol 6, No 2 (2017): July 2017; 165-170</dc:source>
	<dc:source>2252-4940</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://ijred.cbiore.id/index.php/ijred/article/view/13338/pdf</dc:relation>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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