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Layer by Layer Composite Membranes of Alginate-Chitosan Crosslinked by Glutaraldehyde in Pervaporation Dehydration of Ethanol

International Journal of Renewable Energy Development : JRED · Vol. 5 No. 2 (2016) · hlm. 101–106

DOI
10.14710/ijred.5.2.101-106
ISSN
2252-4940
Terbit
2016-07-15
Penerbit
Center of Biomass & Renewable Energy (CBIORE)
Bahasa
eng

Abstrak

Hydrophilicity of membrane causing only water can pass through membrane. Pervaporation process using organophilic membrane has been offered as alternative for ethanol dehydration. This paper investigate pervaporation based biopolymer composite membrane from alginate-chitosan using layer by layer method prepared by glutaraldehyde as crosslinking agent and polyethersulfone (PES) as supported membrane. Characterization of crosslinked of composite membrane by FTIR helped in identification of sites for interaction between layers of membrane and support layer (PES). The SEM showed a multilayer structure and a distinct interface between the chitosan layer, the sodium alginate layer and the support layer. The coating sequence of membranes had an obvious influence on the pervaporation dehydration performance of membranes. For the dehydration of 95 wt% ethanol-water mixtures, a good performance of PES-chitosan-alginate-chitosan (PES/Chi/Alg/Chi) composite membrane was found in the pervaporation dehydration of ethanol. Article History: Received April 12nd, 2016; Received in revised form June 25th, 2016; Accepted July 1st, 2016; Available onlineHow to Cite This Article: Rokhati, N., Istirokhatun, T. and Samsudin, A.M. (2016) Layer by Layer Composite Membranes of Alginate-Chitosan Crosslinked by Glutaraldehyde in Pervaporation Dehydration of Ethanol. Int. Journal of Renewable Energy Development, 5(2), 101-106.http://dx.doi.org/10.14710/ijred.5.2.101-106

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  • Diponegoro University
  • Graz University of Technology
  • Sumatera Institute of Technology
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Rekan penulisOrganisasiArtikel bersama
Heru SusantoDiponegoro University4
Viktor HackerGraz University of Technology4
Michaela RoschgerGraz University of Technology3
I Nyoman WidiasaDiponegoro University2
Andri Cahyo KumoroDiponegoro University2
Didi Dwi AnggoroDiponegoro University2
Nor Basid Adiwibawa PrasetyaDiponegoro University2
Kharissa NasherDiponegoro University2
Dhiky WahyudiDiponegoro University2
Bambang PramudonoDiponegoro University2
Aprilina PurbasariDiponegoro University1
Ariestya Meta DeviDiponegoro University1
Lulluil MahsunnahDiponegoro University1
RatnawatiAfiliasi tidak diketahui1
Akbar NugrohoDiponegoro University1
Aji PrasetyaningrumDiponegoro University1
Teguh RiyantoDiponegoro University1
Widyah AnggrainiDiponegoro University1
Nasyriyatul Hana NovitaDiponegoro University1
Pertiwi AndaraniDiponegoro University1
Aininu NafiunisaDiponegoro University1
Nita AryantiDiponegoro University1
Susanto HeruDiponegoro University1
Alifia Rizki AdinaDiponegoro University1
Arnaldi DwilaksitaDiponegoro University1
Yunita FahniSumatera Institute of Technology1
Meike FitrianingtyasDiponegoro University1
Assalaam Umar AbdurahmanDiponegoro University1
Sigrid WolfGraz University of Technology1

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Sumber metadata: OAI-PMH (metadata jurnal) https://ijred.cbiore.id/index.php/ijred/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en-US">Layer by Layer Composite Membranes of Alginate-Chitosan Crosslinked by Glutaraldehyde in Pervaporation Dehydration of Ethanol</dc:title>
	<dc:creator>Rokhati, Nur</dc:creator>
	<dc:creator>Istirokhatun, Titik</dc:creator>
	<dc:creator>Samsudin, Asep Muhamad</dc:creator>
	<dc:subject xml:lang="en-US">alginate; chitosan; composite membrane; layer by layer; ethanol dehydration</dc:subject>
	<dc:description xml:lang="en-US">Hydrophilicity of membrane causing only water can pass through membrane. Pervaporation process using organophilic membrane has been offered as alternative for ethanol dehydration. This paper investigate pervaporation based biopolymer composite membrane from alginate-chitosan using layer by layer method prepared by glutaraldehyde as crosslinking agent and polyethersulfone (PES) as supported membrane. Characterization of crosslinked of composite membrane by FTIR helped in identification of sites for interaction between layers of membrane and support layer (PES). The SEM showed a multilayer structure and a distinct interface between the chitosan layer, the sodium alginate layer and the support layer. The coating sequence of membranes had an obvious influence on the pervaporation dehydration performance of membranes. For the dehydration of 95 wt% ethanol-water mixtures, a good performance of PES-chitosan-alginate-chitosan (PES/Chi/Alg/Chi) composite membrane was found in the pervaporation dehydration of ethanol. Article History: Received April 12nd , 2016; Received in revised form June 25th , 2016; Accepted July 1st , 2016; Available onlineHow to Cite This Article: Rokhati, N., Istirokhatun, T. and Samsudin, A.M. (2016) Layer by Layer Composite Membranes of Alginate-Chitosan Crosslinked by Glutaraldehyde in Pervaporation Dehydration of Ethanol. Int. Journal of Renewable Energy Development, 5(2), 101-106.http://dx.doi.org/10.14710/ijred.5.2.101-106 </dc:description>
	<dc:publisher xml:lang="en-US">Center of Biomass &amp; Renewable Energy (CBIORE)</dc:publisher>
	<dc:contributor xml:lang="en-US">BOPTN Diponegoro University 2014</dc:contributor>
	<dc:date>2016-07-15</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://ijred.cbiore.id/index.php/ijred/article/view/9972</dc:identifier>
	<dc:identifier>10.14710/ijred.5.2.101-106</dc:identifier>
	<dc:source xml:lang="en-US">International Journal of Renewable Energy Development; Vol 5, No 2 (2016): July 2016; 101-106</dc:source>
	<dc:source>2252-4940</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://ijred.cbiore.id/index.php/ijred/article/view/9972/pdf</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2016 International Journal of Renewable Energy Development</dc:rights>
</oai_dc:dc>