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Synthesis of Polymer Electrolyte Membrane based on Acid-Base complex pair and Its Characteristics

Journal of Mathematical and Fundamental Sciences · Vol. 46 No. 1 (2014) · hlm. 50–61

DOI
10.5614/j.math.fund.sci.2014.46.1.5
ISSN
2338-5510, 2337-5760
Terbit
2014-04-01
Penerbit
Directorate for Research and Innovation (DRI) ITB
Bahasa
eng

Abstrak

In this work, acid-base complex pair polymer electrolyte membranes on sulfonated polysulfone with 1H-benzotriazole were investigated. Polysulfone was sulfonated in 1,2-dichloroethane using the homogeneous method with trimethylsilyl chlorosulfonate as sulfonating agent. The monomer mole ratio between polysulfone and trimethysilyl chlorosulfonate was 1:1.5.The sulfonated polysulfone was added with 1H-benzotriazole at mole ratios of x = 0.5 and x =1. The proton transfer from 1H-benzotriazole to the sulfonated polysulfone was measured using FTIR. Thermo-gravimetry analysis showed that the samples were thermally stable up to approximately 250°C and the maximum proton conductivity was found to be 3.34 x 10-4 S cm-1 at 150°C.

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  • Padjadjaran University
  • University of Bengkulu
  • Fatih University
  • Sekolah Tinggi Farmasi Indonesia
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Umi BarorohSekolah Tinggi Farmasi Indonesia1
Adang FirmansyahAfiliasi tidak diketahui1
Deni DeniAfiliasi tidak diketahui1
Lina MaudyawatiAfiliasi tidak diketahui1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journals.itb.ac.id/index.php/jmfs/oai, pertama di-harvest 9 Nov 2026, terakhir terlihat 9 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Synthesis of Polymer Electrolyte Membrane based on Acid-Base complex pair and Its Characteristics</dc:title>
	<dc:creator>Gustian, Irfan</dc:creator>
	<dc:creator>Çelik, Sevim Ünugur</dc:creator>
	<dc:creator>Zainuddin, Ahmad</dc:creator>
	<dc:creator>Suratno, Wawang</dc:creator>
	<dc:creator>Bozkurt, Ayhan</dc:creator>
	<dc:creator>Siregar, Rustam Efendi</dc:creator>
	<dc:subject xml:lang="en-US">Sulfonated polysulfone</dc:subject>
	<dc:subject xml:lang="en-US">1H-benzotriazole</dc:subject>
	<dc:subject xml:lang="en-US">acid-base complex pair</dc:subject>
	<dc:subject xml:lang="en-US">homogeneous</dc:subject>
	<dc:subject xml:lang="en-US">polymer electrolyte membranes</dc:subject>
	<dc:subject xml:lang="en-US">proton conductivity.</dc:subject>
	<dc:description xml:lang="en-US">In this work, acid-base complex pair polymer electrolyte membranes on sulfonated polysulfone with 1H-benzotriazole were investigated. Polysulfone was sulfonated in 1,2-dichloroethane using the homogeneous method with trimethylsilyl chlorosulfonate as sulfonating agent. The monomer mole ratio between polysulfone and trimethysilyl chlorosulfonate was 1:1.5.The sulfonated polysulfone was added with 1H-benzotriazole at mole ratios of x = 0.5 and x =1. The proton transfer from 1H-benzotriazole to the sulfonated polysulfone was measured using FTIR. Thermo-gravimetry analysis showed that the samples were thermally stable up to approximately 250°C and the maximum proton conductivity was found to be 3.34 x 10-4 S cm-1 at 150°C.</dc:description>
	<dc:publisher xml:lang="en-US">Directorate for Research and Innovation (DRI) ITB</dc:publisher>
	<dc:date>2014-04-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journals.itb.ac.id/index.php/jmfs/article/view/816</dc:identifier>
	<dc:identifier>10.5614/j.math.fund.sci.2014.46.1.5</dc:identifier>
	<dc:source xml:lang="en-US">Journal of Mathematical and Fundamental Sciences; Vol. 46 No. 1 (2014); 50-61</dc:source>
	<dc:source>2338-5510</dc:source>
	<dc:source>2337-5760</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journals.itb.ac.id/index.php/jmfs/article/view/816/495</dc:relation>
</oai_dc:dc>