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Enhanced Hydrogen Storage Capacity Over Electro-synthesized HKUST-1

Journal of Mathematical and Fundamental Sciences · Vol. 49 No. 3 (2017) · hlm. 213–224

DOI
10.5614/j.math.fund.sci.2017.49.3.1
ISSN
2338-5510, 2337-5760
Terbit
2017-12-13
Penerbit
Directorate for Research and Innovation (DRI) ITB
Bahasa
eng

Abstrak

HKUST-1 [Cu3(1,3,5-BTC)2] (BTC = 1,3,5-benzene-tri-carboxylate) was synthesized using an electrochemical method and tested for hydrogen storage. The obtained material showed a remarkably higher hydrogen uptake over reported HKUST-1 and reached until 4.75 wt% at room temperature and low pressure up to 1.2 bar. This yield was compared to HKUST-1 obtained from the solvothermal method, which showed a hydrogen uptake of only 1.19 wt%. Enhancement of hydrogen sorption of the electro-synthesized product was due to the more appropriate surface area and pore size, effected by the preferable physical interaction between the hydrogen gasses and the copper ions as unsaturated metal centers in the frameworks of HKUST-1.

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  • Sebelas Maret University
  • National Nuclear Energy Agency of Indonesia
  • Institut Teknologi Sepuluh Nopember
  • Padjadjaran University
  • University of Indonesia
  • Bandung Institute of Technology
  • Leipzig University
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Rekan penulisOrganisasiArtikel bersama
Wisnu Ari AdiNational Nuclear Energy Agency of Indonesia3
A. InsaniNational Nuclear Energy Agency of Indonesia2
Fajar Rakhman WibowoSebelas Maret University2
Hamzah FansuriInstitut Teknologi Sepuluh Nopember2
Teguh Endah SaraswatiSebelas Maret University2
Jeesica Hermayanti PratamaInstitut Teknologi Sepuluh Nopember2
Fitria RahmawatiSebelas Maret University2
Rohmad SigitNational Nuclear Energy Agency of Indonesia1
Bambang SoegijonoUniversity of Indonesia1
Riandy PutraSebelas Maret University1
Bambang Heru SusantoUniversity of Indonesia1
Rino R. MuktiBandung Institute of Technology1
Melani Puji PuspitasariSebelas Maret University1
Roshid Adi NugrohoSebelas Maret University1
Yusnadia KemalaSebelas Maret University1
Rujito S. R. SuharbiansahLeipzig University1
Sayekti WahyuningsihSebelas Maret University1
Widyan Muhammad NaufalSebelas Maret University1
Yudha Prawira BudimanPadjadjaran University1
Yessi PermanaBandung Institute of Technology1
Ubed Sonai Fahruddin ArroziState University of Malang1
Muhamad R. S. SidikPadjadjaran University1
Irwan KurniaPadjadjaran University1
Wirawan CiptonugrohoSebelas Maret University1
Triyanda GunawanInstitut Teknologi Sepuluh Nopember1
Burhan Fatkhur RahmanSebelas Maret University1
Fauziyah AzhariSebelas Maret University1
Nurul WidiastutiInstitut Teknologi Sepuluh Nopember1
Desi Suci HandayaniSebelas Maret University1
Shinta Amelia PutriSebelas Maret University1
Anggia Putri GustamiAfiliasi tidak diketahui1
Viona NataliaSebelas Maret University1
Agus PurwantoSebelas Maret University1
Larasati LarasatiUniversitas Gadjah Mada1
Wulan Cahya InayahSebelas Maret University1
Agus PurwantoSebelas Maret University1
Dendy DendySebelas Maret University1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journals.itb.ac.id/index.php/jmfs/oai, pertama di-harvest 9 Nov 2026, terakhir terlihat 9 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US">Enhanced Hydrogen Storage Capacity Over Electro-synthesized HKUST-1</dc:title>
	<dc:creator>Lestari, Witri Wahyu</dc:creator>
	<dc:creator>Adreane, Marisa</dc:creator>
	<dc:creator>Suwarno, Hadi</dc:creator>
	<dc:subject xml:lang="en-US">Copper(II)</dc:subject>
	<dc:subject xml:lang="en-US">H3BTC</dc:subject>
	<dc:subject xml:lang="en-US">electrosynthesis</dc:subject>
	<dc:subject xml:lang="en-US">HKUST-1</dc:subject>
	<dc:subject xml:lang="en-US">hydrogen storage</dc:subject>
	<dc:subject xml:lang="en-US">solvothermal</dc:subject>
	<dc:description xml:lang="en-US">HKUST-1 [Cu3(1,3,5-BTC)2] (BTC = 1,3,5-benzene-tri-carboxylate) was synthesized using an electrochemical method and tested for hydrogen storage. The obtained material showed a remarkably higher hydrogen uptake over reported HKUST-1 and reached until 4.75 wt% at room temperature and low pressure up to 1.2 bar. This yield was compared to HKUST-1 obtained from the solvothermal method, which showed a hydrogen uptake of only 1.19 wt%. Enhancement of hydrogen sorption of the electro-synthesized product was due to the more appropriate surface area and pore size, effected by the preferable physical interaction between the hydrogen gasses and the copper ions as unsaturated metal centers in the frameworks of HKUST-1.</dc:description>
	<dc:publisher xml:lang="en-US">Directorate for Research and Innovation (DRI) ITB</dc:publisher>
	<dc:date>2017-12-13</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journals.itb.ac.id/index.php/jmfs/article/view/2398</dc:identifier>
	<dc:identifier>10.5614/j.math.fund.sci.2017.49.3.1</dc:identifier>
	<dc:source xml:lang="en-US">Journal of Mathematical and Fundamental Sciences; Vol. 49 No. 3 (2017); 213-224</dc:source>
	<dc:source>2338-5510</dc:source>
	<dc:source>2337-5760</dc:source>
	<dc:source>10.5614//j.math.fund.sci.2016.49.3</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journals.itb.ac.id/index.php/jmfs/article/view/2398/2804</dc:relation>
</oai_dc:dc>