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Metal-Organic Frameworks Based on Zinc(II) and Benzene-1,3,5-Tricarboxylate Modified Graphite: Fabrication and Application as an Anode Material in Lithium-Ion Batteries

Journal of Mathematical and Fundamental Sciences · Vol. 52 No. 1 (2020) · hlm. 81–97

DOI
10.5614/j.math.fund.sci.2020.52.1.6
ISSN
2338-5510, 2337-5760
Terbit
2020-04-28
Penerbit
Directorate for Research and Innovation (DRI) ITB
Bahasa
eng

Abstrak

This research was aimed at synthesizing metal-organic frameworks (MOFs) based on zinc(II) and a benzene-1,3,5-tricarboxylate (BTC) linker in combination with graphite as anode material in lithium-ion batteries. The MOFs were prepared using sonochemical and solvothermal methods, which led to different materials: [Zn3(BTC)2·12H2O] (MOF 1) and [Zn(BTC)·H2O·3DMF] (MOF 2). The produced materials were characterized by powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric/differential thermal analysis (TG/DTA), and a battery analyzer. Refinement of the XRD data was performed using the Rietica and Le Bail method. Sharp and intense peaks indicated that the materials had a high degree of crystallinity. The morphology of the materials as analyzed by SEM was cubic, with an average crystal size of 8.377 ± 4.276 µm for MOF 1 and a larger size of 16.351 ± 3.683 µm for MOF 2. MOF 1 was thermally stable up to 378.7 °C while MOF 2 remained stable up to 341.8 °C, as demonstrated by thermogravimetric analysis. The employment of the synthesized materials as anode in a lithium ion battery was proved to yield higher specific capacity and cycle stability compared to those using a graphite anode. The lithium-ion battery with 5 wt% MOF 1 exhibited the highest performance with an efficiency of 97.28%, and charge and discharge specific capacities of 123.792 and 120.421 mAh/g, respectively.

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  • IPB University
  • Universitas Amikom Yogyakarta
  • Universitas Wisnuwardhana Malang
  • Universitas Muhammadiyah Magelang
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Hery WinarsiAfiliasi tidak diketahui5
Yuniawan HidayatAfiliasi tidak diketahui4
Viona NataliaAfiliasi tidak diketahui4
Edy MeiyantoAfiliasi tidak diketahui3
Khoirina Dwi NugrahaningtyasAfiliasi tidak diketahui3
I. F. NurcahyoAfiliasi tidak diketahui3
Ema UtamiUniversitas Amikom Yogyakarta2
David AgustriawanAfiliasi tidak diketahui2
Fajar Rakhman WibowoAfiliasi tidak diketahui2
Hamzah FansuriAfiliasi tidak diketahui2
Teguh Endah SaraswatiAfiliasi tidak diketahui2
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Siwi Pramatama Mars WijayantiAfiliasi tidak diketahui2
Ratna Asmah SusidartiAfiliasi tidak diketahui2
Indri KusharyantiAfiliasi tidak diketahui2
Arif JumariAfiliasi tidak diketahui2
Eddy HeraldyAfiliasi tidak diketahui2
Agung Tri WijayantaAfiliasi tidak diketahui2
Sayekti WahyuningsihAfiliasi tidak diketahui2
Edi PramonoAfiliasi tidak diketahui2
Wisnu Ananta KusumaIPB University1
Annisa AnnisaIPB University1
Solikhin SolikhinAfiliasi tidak diketahui1
Uky YudatamaUniversitas Muhammadiyah Magelang1
Dwi Ekasari HarmadjiUniversitas Wisnuwardhana Malang1
Juliana JulianaAfiliasi tidak diketahui1
Dewiana NovitasariAfiliasi tidak diketahui1
Masduki AsbariAfiliasi tidak diketahui1
Kusrini KusriniUniversitas Amikom Yogyakarta1
KusriniAfiliasi tidak diketahui1
Riandy PutraAfiliasi tidak diketahui1
Bambang Heru SusantoAfiliasi tidak diketahui1
Ita PermadaniAfiliasi tidak diketahui1
Dhini A. PhasaAfiliasi tidak diketahui1
Andini W. PratiwiAfiliasi tidak diketahui1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journals.itb.ac.id/index.php/jmfs/oai, pertama di-harvest 9 Nov 2026, terakhir terlihat 9 Nov 2026.
Metadata asli (oai_dc) 
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en-US">Metal-Organic Frameworks Based on Zinc(II) and Benzene-1,3,5-Tricarboxylate Modified Graphite: Fabrication and Application as an Anode Material in Lithium-Ion Batteries</dc:title>
	<dc:creator>Lestari, Witri Wahyu</dc:creator>
	<dc:creator>Inayah, Wulan Cahya</dc:creator>
	<dc:creator>Rahmawati, Fitria</dc:creator>
	<dc:creator>Larasati, Larasati</dc:creator>
	<dc:creator>Purwanto, Agus</dc:creator>
	<dc:subject xml:lang="en-US">BTC</dc:subject>
	<dc:subject xml:lang="en-US">MOFs</dc:subject>
	<dc:subject xml:lang="en-US">graphite lithium-ion batteries</dc:subject>
	<dc:subject xml:lang="en-US">zinc(II)</dc:subject>
	<dc:description xml:lang="en-US">This research was aimed at synthesizing metal-organic frameworks (MOFs) based on zinc(II) and a benzene-1,3,5-tricarboxylate (BTC) linker in combination with graphite as anode material in lithium-ion batteries. The MOFs were prepared using sonochemical and solvothermal methods, which led to different materials: [Zn3(BTC)2·12H2O] (MOF 1) and [Zn(BTC)·H2O·3DMF] (MOF 2). The produced materials were characterized by powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric/differential thermal analysis (TG/DTA), and a battery analyzer. Refinement of the XRD data was performed using the Rietica and Le Bail method. Sharp and intense peaks indicated that the materials had a high degree of crystallinity. The morphology of the materials as analyzed by SEM was cubic, with an average crystal size of 8.377 ± 4.276 µm for MOF 1 and a larger size of 16.351 ± 3.683 µm for MOF 2. MOF 1 was thermally stable up to 378.7 °C while MOF 2 remained stable up to 341.8 °C, as demonstrated by thermogravimetric analysis. The employment of the synthesized materials as anode in a lithium ion battery was proved to yield higher specific capacity and cycle stability compared to those using a graphite anode. The lithium-ion battery with 5 wt% MOF 1 exhibited the highest performance with an efficiency of 97.28%, and charge and discharge specific capacities of 123.792 and 120.421 mAh/g, respectively.</dc:description>
	<dc:publisher xml:lang="en-US">Directorate for Research and Innovation (DRI) ITB</dc:publisher>
	<dc:date>2020-04-28</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journals.itb.ac.id/index.php/jmfs/article/view/8037</dc:identifier>
	<dc:identifier>10.5614/j.math.fund.sci.2020.52.1.6</dc:identifier>
	<dc:source xml:lang="en-US">Journal of Mathematical and Fundamental Sciences; Vol. 52 No. 1 (2020); 81-97</dc:source>
	<dc:source>2338-5510</dc:source>
	<dc:source>2337-5760</dc:source>
	<dc:source>10.5614/j.math.fund.sci.2020.52.1</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journals.itb.ac.id/index.php/jmfs/article/view/8037/4671</dc:relation>
</oai_dc:dc>