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Molecular Vibration and Physicochemical Performance of Proton-Conducting Solid Polymer Electrolyte Membrane based on CMC/PVA/CH3COONH4

Molekul: Jurnal Ilmiah Kimia · Vol. 19 No. 3 (2024) · hlm. 489–502

DOI
10.20884/1.jm.2024.19.3.11001
ISSN
2503-0310, 1907-9761
Terbit
2024-11-24
Penerbit
Universitas Jenderal Soedirman
Bahasa
eng

Abstrak

This work studied examined the influence of ammonium acetate (CH3COONH4) on CMC/PVA-based solid polymer electrolyte (SPE) membranes, focusing on molecular vibration, proton conductivity, and physicochemical properties. SPE membranes were prepared via the casting solution method with varying CH3COONH4 concentrations to determine the optimal proton conductivity. Various characterizations, including FTIR, EIS, XRD, and TGA, were performed. The optimal membrane condition was achieved with 10 wt-% CH3COONH4 in the CMC/PVA (80/20) blend, yielding proton conductivity of 3.93×10⁻⁴ S/cm and favorable mechanical, thermal, and crystallinity properties, making it suitable for proton-conducting polymer applications. Keywords: ammonium acetate, carboxymethyl cellulose, ionic conductivity, poly(vinyl alcohol), proton battery, solid electrolyte membrane

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  • National Research and Innovation Agency
  • Universitas Pertamina
  • Bandung Institute of Technology
  • Sunan Gunung Djati State Islamic University Bandung
  • Jenderal Soedirman University
  • Riau University
  • Institut Teknologi Indonesia
  • Organisasi lain
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  • Organisasi sama
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Rekan penulisOrganisasiArtikel bersama
Deana WahyuningrumBandung Institute of Technology3
Asep SupriadinSunan Gunung Djati State Islamic University Bandung2
Bunbun BundjaliBandung Institute of Technology2
I Made ArcanaBandung Institute of Technology2
Nurhayati NurhayatiRiau University2
Latifah HauliNational Research and Innovation Agency2
Putri Julpa MailaniRiau University2
Avi Waras SetyawatiInstitut Teknologi Indonesia2
Susi SulistiaNational Research and Innovation Agency2
Fuzi SuciatiNational Research and Innovation Agency2
Reza Audina PutriAndalas University2
Rista Siti MawarniNational Research and Innovation Agency2
Yenny MelianaNational Research and Innovation Agency2
Joelianingsih JoelianingsihInstitut Teknologi Indonesia2
Prillizya D'ura TamakoSunan Gunung Djati State Islamic University Bandung1
Mirna Ulfa FauziahSunan Gunung Djati State Islamic University Bandung1
Muhammad Ali ZulfikarBandung Institute of Technology1
Nelliza PutriUniversitas Pertamina1
Anggun Kirana Devi Shaenazha PutriUniversitas Pertamina1
Eng Paramita Jaya RatriUniversitas Pertamina1
Syiffa AssatyasUniversitas Pertamina1
Septhian MarnoPertamina (Indonesia)1
Eng Bayu PrabowoUniversitas Pertamina1
SudaryantoAfiliasi tidak diketahui1
Kartika SariJenderal Soedirman University1
Arifin Nur Muhammad HaryadiJenderal Soedirman University1
Nur - KhusaenahJenderal Soedirman University1

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Sumber metadata: OAI-PMH (metadata jurnal) https://jos.unsoed.ac.id/index.php/jm/oai, pertama di-harvest 9 Nov 2026, terakhir terlihat 9 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en-US"> Molecular Vibration and Physicochemical Performance of Proton-Conducting Solid Polymer Electrolyte Membrane based on CMC/PVA/CH3COONH4</dc:title>
	<dc:creator>Ndruru, Sun Theo Constan Lotebulo</dc:creator>
	<dc:creator>Rachmadhanti, Elvira Nur</dc:creator>
	<dc:creator>Fridarima, Shanny</dc:creator>
	<dc:creator>Berghuis, Nila Tanyela</dc:creator>
	<dc:creator>Prasetyo, Ridho</dc:creator>
	<dc:creator>Yulianti, Evi</dc:creator>
	<dc:creator>Hayati, Atika Trisna</dc:creator>
	<dc:creator>Adriana, Risda</dc:creator>
	<dc:creator>Siregar, Rabiyatul Adawiyah</dc:creator>
	<dc:creator>Sofyan, Muhammad Ihsan</dc:creator>
	<dc:creator>Sampora, Yulianti</dc:creator>
	<dc:creator>Annas, Dicky</dc:creator>
	<dc:creator>Madiabu, Muhammad Jihad</dc:creator>
	<dc:description xml:lang="en-US">This work studied examined the influence of ammonium acetate (CH3COONH4) on CMC/PVA-based solid polymer electrolyte (SPE) membranes, focusing on molecular vibration, proton conductivity, and physicochemical properties. SPE membranes were prepared via the casting solution method with varying CH3COONH4 concentrations to determine the optimal proton conductivity. Various characterizations, including FTIR, EIS, XRD, and TGA, were performed. The optimal membrane condition was achieved with 10 wt-% CH3COONH4 in the CMC/PVA (80/20) blend, yielding proton conductivity of 3.93×10⁻⁴ S/cm and favorable mechanical, thermal, and crystallinity properties, making it suitable for proton-conducting polymer applications.
Keywords: ammonium acetate, carboxymethyl cellulose, ionic conductivity, poly(vinyl alcohol),&amp;nbsp; proton battery,&amp;nbsp; solid electrolyte membrane</dc:description>
	<dc:publisher xml:lang="en-US">Universitas Jenderal Soedirman</dc:publisher>
	<dc:date>2024-11-24</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://jos.unsoed.ac.id/index.php/jm/article/view/11001</dc:identifier>
	<dc:identifier>10.20884/1.jm.2024.19.3.11001</dc:identifier>
	<dc:source xml:lang="en-US">Molekul; Vol 19 No 3 (2024); 489-502</dc:source>
	<dc:source>2503-0310</dc:source>
	<dc:source>1907-9761</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://jos.unsoed.ac.id/index.php/jm/article/view/11001/5945</dc:relation>
</oai_dc:dc>