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Enhanced Microwave Absorbing Characteristics of Cerium Barium Ferrite Composite: Effect of Sintering Temperature Variation

Molekul: Jurnal Ilmiah Kimia · Vol. 20 No. 3 (2025) · hlm. 563–572

DOI
10.20884/1.jm.2025.20.3.17825
ISSN
2503-0310, 1907-9761
Terbit
2025-11-24
Penerbit
Universitas Jenderal Soedirman
Bahasa
eng

Abstrak

ABSTRACT. Cerium barium ferrite composites (CeBFCs) with improved microwave absorbance in the X-band spectral region are advantageous for varied advanced applications. Thus, the influence of various sintering temperatures on the microwave-absorbing traits of CeBFCs was evaluated. The main objective was to enhance the selective microwave absorption of BFC by modifying its magnetic properties through the substitution of Fe³⁺ with Ce³⁺ in the lattice structures. Four composites of CeBF were synthesized via mechanical alloying and sintered at 600, 800, 1000, and 1100°C. The produced samples were analyzed using XRD, VSM, and VNA to determine their microstructures, magnetic properties, and microwave reflection loss at X-band frequencies. XRD results revealed a significant promotion in forming a more pure crystalline barium hexaferrite phase at sintering temperatures higher than 800°C. This structural enhancement could directly influence the magnetic properties of the specimens with a progressive increase in the saturation magnetization with rising sintering temperature. In addition, the sintering temperature variation effectively modulated the electromagnetic properties (complex relative permeability and permittivity) that are vital for impedance matching and optimal wave absorption. The composite sintered at 1000°C displayed an optimal microwave absorption, indicating the lowest reflection loss within the X-band. The obtained products were shown to attenuate and dissipate surplus electromagnetic energy within the 8-12 GHz frequency range. The observed superior performance of the composites was ascribed to a balanced interplay between the magnetic and dielectric losses, leading to efficient impedance matching. It was affirmed that careful tuning of the sintering temperature can improve the crystalline phases, magnetic, electromagnetic, and microwave absorption properties of the proposed CeBFCs. Keywords: Cerium barium ferrite, Microwave absorption, Reflection loss, Sintering temperature, X-band

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  • Jenderal Soedirman University
  • Riau University
  • National Research and Innovation Agency
  • Nara Institute of Science and Technology
  • Universitas Riau Indonesia
  • University of Technology Malaysia
  • State University of Jakarta
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Rekan penulisOrganisasiArtikel bersama
Muhammad AlqaafNara Institute of Science and Technology9
Yogi RamadhaniJenderal Soedirman University8
Madya Ardi WicaksonoJenderal Soedirman University5
Syafrudin Rais AkhdanNara Institute of Science and Technology5
Haris Budi WidodoJenderal Soedirman University4
Rahmondia Nanda SetiadiRiau University4
Ariep Soelaiman SetiadiJenderal Soedirman University2
Wahyu SiswandariJenderal Soedirman University2
Vira Annisa RosandiRiau University2
Zulkarnain JalilUniversitas Syiah Kuala2
Alfin ChrisantyJenderal Soedirman University1
Pangestu F. WibowoJenderal Soedirman University1
Fibra R. FirmandaJenderal Soedirman University1
Muhammad Rifqi KurniawanJenderal Soedirman University1
Arif Pujo RiyantoJenderal Soedirman University1
Muhammad Syaiful AliimJenderal Soedirman University1
Muhammad Irham AkbarJenderal Soedirman University1
Tengku EmrinaldiRiau University1
DefriantoUniversitas Riau Indonesia1
Sultan Fiddunya FiddunyaUniversitas Riau Indonesia1
Febyola AswandiRiau University1
Beny AgustirandyAfiliasi tidak diketahui1
Dina MaryaniRiau University1
Maria Rosariana GeaRiau University1
Leonardus Riski NainggolanRiau University1
Siti Rahmawati IbmarRiau University1
Sumi KomalaRiau University1
Yanuar YanuarRiau University1
Nadratul HanifahRiau University1

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Sumber metadata: OAI-PMH (metadata jurnal) https://jos.unsoed.ac.id/index.php/jm/oai, pertama di-harvest 9 Nov 2026, terakhir terlihat 9 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en-US"> Enhanced Microwave Absorbing Characteristics of Cerium Barium Ferrite Composite: Effect of Sintering Temperature Variation</dc:title>
	<dc:creator>Widanarto, Wahyu</dc:creator>
	<dc:creator>Tamtowi, Tomy</dc:creator>
	<dc:creator>Effendi, Mukhtar</dc:creator>
	<dc:creator>Rahmawati, Dina</dc:creator>
	<dc:creator>Supriyanti, Retno</dc:creator>
	<dc:creator>Ghoshal, Sib Krishna</dc:creator>
	<dc:creator>Kurniawan, Candra</dc:creator>
	<dc:creator>Jatmika, Jumaeda</dc:creator>
	<dc:creator>Handoko, Erfan</dc:creator>
	<dc:creator>Umar, Lazuardi</dc:creator>
	<dc:creator>Alaydrus, Mudrik</dc:creator>
	<dc:description xml:lang="en-US">ABSTRACT. Cerium barium ferrite composites (CeBFCs) with improved microwave absorbance in the X-band spectral region are advantageous for varied advanced applications. Thus, the influence of various sintering temperatures on the microwave-absorbing traits of CeBFCs was evaluated. The main objective was to enhance the selective microwave absorption of BFC by modifying its magnetic properties through the substitution of Fe³⁺ with Ce³⁺ in the lattice structures. Four composites of CeBF were synthesized via mechanical alloying and sintered at 600, 800, 1000, and 1100°C. The produced samples were analyzed using XRD, VSM, and VNA to determine their microstructures, magnetic properties, and microwave reflection loss at X-band frequencies. XRD results revealed a significant promotion in forming a more pure crystalline barium hexaferrite phase at sintering temperatures higher than 800°C. This structural enhancement could directly influence the magnetic properties of the specimens with a progressive increase in the saturation magnetization with rising sintering temperature. In addition, the sintering temperature variation effectively modulated the electromagnetic properties (complex relative permeability and permittivity) that are vital for impedance matching and optimal wave absorption. The composite sintered at 1000°C displayed an optimal microwave absorption, indicating the lowest reflection loss within the X-band. The obtained products were shown to attenuate and dissipate surplus electromagnetic energy within the 8-12 GHz frequency range. The observed superior performance of the composites was ascribed to a balanced interplay between the magnetic and dielectric losses, leading to efficient impedance matching. It was affirmed that careful tuning of the sintering temperature can improve the crystalline phases, magnetic, electromagnetic, and microwave absorption properties of the proposed CeBFCs.
&amp;nbsp;
Keywords: Cerium barium ferrite, Microwave absorption, Reflection loss, Sintering temperature, X-band</dc:description>
	<dc:publisher xml:lang="en-US">Universitas Jenderal Soedirman</dc:publisher>
	<dc:date>2025-11-24</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US">Peer-reviewed Article</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://jos.unsoed.ac.id/index.php/jm/article/view/17825</dc:identifier>
	<dc:identifier>10.20884/1.jm.2025.20.3.17825</dc:identifier>
	<dc:source xml:lang="en-US">Molekul; Vol 20 No 3 (2025); 563-572</dc:source>
	<dc:source>2503-0310</dc:source>
	<dc:source>1907-9761</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://jos.unsoed.ac.id/index.php/jm/article/view/17825/7538</dc:relation>
</oai_dc:dc>