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Alternatif Pembuatan Biodiesel Melalui Transesterifikasi Minyak Castor (Ricinus communis) Menggunakan Katalis Campuran Cangkang Telur Ayam dan Kaolin

VALENSI · Vol. ume No. 1 (2017) · hlm. 1–10

DOI
10.15408/jkv.v3i1.4778
ISSN
2548-3013, 2460-6065
Terbit
2017-05-31
Penerbit
Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University
Bahasa
eng

Abstrak

Biodiesel was produced by transesterification of castor oil (Ricinus communis) using a catalyst of CaO and kaolin (CaO / kaolin) had been performed. CaO was obtained from the calcination of eggshell. Castor oil is selected as biodiesel feedstock because it belongs to non-food oil and easy to cultivate. In general, the research method aims to comprise the CaO / Kaolin catalysts with a ratio of 15 mmol CaO per 1 gram of kaolin activated using impregnation method and biodiesel produced through transesterification of castor oil using the catalyst at 65 ºC for 8 hours with ratio of castor oil: methanol: catalyst (1: 15: 5% w / w). The reaction is carried out on the reflux system. The XRD analysis show the presence of silica and potassium aluminum silicate hydroxide in the catalyst. The EDS results show the catalyst-forming components CaO and silica. The FTIR analysis results show the absorption peak in the functional group forming the methyl ester compound. Based on the characterization of GC-MS, the largest methyl ester components contained in biodiesel are methyl risinoleate, methyl elaidat, methyl stearate, methyl linoleate, and methyl palmitate. The overall conversion of castor oil to methyl ester using CaO / kaolin catalyst is 97.36%. The largest component in castor oil is risinoleic acid, has been successfully converted to methyl risinoleate by 74.75%.DOI: http://dx.doi.org/10.15408/jkv.v0i0.4778

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  • Sunan Gunung Djati State Islamic University Bandung
  • Bandung Institute of Technology
  • Universitas Halu Oleo
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Rekan penulisOrganisasiArtikel bersama
Dede SuhendarSunan Gunung Djati State Islamic University Bandung2
Citra Deliana Dewi SundariSunan Gunung Djati State Islamic University Bandung2
Atthar Luqman IvansyahBandung Institute of Technology2
Frida Aziz DamayantiSunan Gunung Djati State Islamic University Bandung1
Fiona Putri SeptianiSunan Gunung Djati State Islamic University Bandung1
Agung WahanaSunan Gunung Djati State Islamic University Bandung1
Tina Dewi RosahdiSunan Gunung Djati State Islamic University Bandung1
Athar Luqman IvansyahAfiliasi tidak diketahui1
Adi Bungsu PribadiSunan Gunung Djati State Islamic University Bandung1
Ahmad HidayatUniversitas Halu Oleo1
Eko Prabowo HadisantosoSunan Gunung Djati State Islamic University Bandung1
Ani Sri WahyuniSunan Gunung Djati State Islamic University Bandung1
Yusuf RohmatullohSunan Gunung Djati State Islamic University Bandung1
Ginawanti Maulida GunawanSunan Gunung Djati State Islamic University Bandung1

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Sumber metadata: OAI-PMH (metadata jurnal) http://journal.uinjkt.ac.id/index.php/valensi/oai, pertama di-harvest 10 Nov 2026, terakhir terlihat 10 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en">Alternatif Pembuatan Biodiesel Melalui Transesterifikasi Minyak Castor (Ricinus communis) Menggunakan Katalis Campuran Cangkang Telur Ayam dan Kaolin</dc:title>
	<dc:creator xml:lang="en">Setiadji, Soni</dc:creator>
	<dc:creator xml:lang="en">B, Nila Tanyela</dc:creator>
	<dc:creator xml:lang="en">Sudiartati, Tety</dc:creator>
	<dc:creator xml:lang="en">Prabowo, Eko</dc:creator>
	<dc:creator xml:lang="en">N, Bebeh Wahid</dc:creator>
	<dc:subject xml:lang="en">Biodiesel</dc:subject>
	<dc:subject xml:lang="en">transesterification</dc:subject>
	<dc:subject xml:lang="en">castor oil</dc:subject>
	<dc:subject xml:lang="en">catalyst</dc:subject>
	<dc:subject xml:lang="en">impregnation</dc:subject>
	<dc:description xml:lang="en">Biodiesel was produced by transesterification of castor oil (Ricinus communis) using a catalyst of CaO and kaolin (CaO / kaolin) had been performed. CaO was obtained from the calcination of eggshell. Castor oil is selected as biodiesel feedstock because it belongs to non-food oil and easy to cultivate. In general, the research method aims to comprise the CaO / Kaolin catalysts with a ratio of 15 mmol CaO per 1 gram of kaolin activated using impregnation method and biodiesel produced through transesterification of castor oil using the catalyst at 65 ºC for 8 hours with ratio of castor oil: methanol: catalyst (1: 15: 5% w / w). The reaction is carried out on the reflux system. The XRD analysis show the presence of silica and potassium aluminum silicate hydroxide in the catalyst. The EDS results show the catalyst-forming components CaO and silica. The FTIR analysis results show the absorption peak in the functional group forming the methyl ester compound. Based on the characterization of GC-MS, the largest methyl ester components contained in biodiesel are methyl risinoleate, methyl elaidat, methyl stearate, methyl linoleate, and methyl palmitate. The overall conversion of castor oil to methyl ester using CaO / kaolin catalyst is 97.36%. The largest component in castor oil is risinoleic acid, has been successfully converted to methyl risinoleate by 74.75%.DOI: http://dx.doi.org/10.15408/jkv.v0i0.4778</dc:description>
	<dc:publisher xml:lang="en">Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University</dc:publisher>
	<dc:date>2017-05-31</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.uinjkt.ac.id/index.php/valensi/article/view/4778</dc:identifier>
	<dc:identifier>10.15408/jkv.v3i1.4778</dc:identifier>
	<dc:source xml:lang="en">Jurnal Kimia Valensi; Jurnal Kimia VALENSI Volume 3, No. 1, Mei 2017; 1-10</dc:source>
	<dc:source>2548-3013</dc:source>
	<dc:source>2460-6065</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.uinjkt.ac.id/index.php/valensi/article/view/4778/pdf_1</dc:relation>
	<dc:rights xml:lang="en">Copyright (c) 2019 Soni Setiadji, Nila Tanyela B, Tety Sudiartati, Eko Prabowo, Bebeh Wahid N</dc:rights>
</oai_dc:dc>