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Performance of Modified Natural Zeolites by Sodium Hydroxide Treatments in The Esterification of Glycerol and Oleic Acid

VALENSI · Vol. ume No. 2 (2019) · hlm. 236–241

DOI
10.15408/jkv.v5i2.9976
ISSN
2548-3013, 2460-6065
Terbit
2019-11-30
Penerbit
Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University
Bahasa
eng

Abstrak

Esterification is the reaction of the formation of an ester compound by reacting an alcohol compound and carboxylic acid. In this study, the performance of zeolite-based catalysts has been studied for esterification reactions. Modification of zeolite pore size was done to be hierarchical zeolite, with the aim of increasing the catalytic properties of zeolite. The modification was carried out by desilication by sodium hydroxide treatment with a variation of 0.1; 0.3; 0.5 M. The resulting catalyst was then characterized using BET and XRD. Furthermore, the catalyst was tested for activity for esterification of fatty acids and glycerol and the product was analyzed using GC-MS. Zeolite modification with sodium hydroxide has been proven to improve catalyst performance, without changing their crystal structure. The best catalytic activity was obtained on the catalyst with sodium hydroxide treatment of 0.3 M, resulting glycerol conversion of 92% and selectivity to monoglycerides of 74%.

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  • Syarif Hidayatullah State Islamic University Jakarta
  • National Research and Innovation Agency
  • Indonesian Institute of Sciences
  • Sriwijaya University
  • National Nuclear Energy Agency of Indonesia
  • University of Indonesia
  • Badan Pengkajian dan Penerapan Teknologi
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Rekan penulisOrganisasiArtikel bersama
Adawiah AdawiahSyarif Hidayatullah State Islamic University Jakarta6
Isalmi AzizSyarif Hidayatullah State Islamic University Jakarta6
Joni PrasetyoNational Research and Innovation Agency6
Egi AgustianNational Research and Innovation Agency6
Robert Ronal WidjayaNational Research and Innovation Agency6
Nani RadiastutiSyarif Hidayatullah State Islamic University Jakarta5
Sandra HermantoSyarif Hidayatullah State Islamic University Jakarta5
Anna MuawanahSyarif Hidayatullah State Islamic University Jakarta5
Eka Rizki AmeliaSyarif Hidayatullah State Islamic University Jakarta4
Siti NurbaytiSyarif Hidayatullah State Islamic University Jakarta4
La Ode SumarlinSyarif Hidayatullah State Islamic University Jakarta3
Hasanudin HasanudinSriwijaya University3
Muhammad Al MuttaqiiNational Research and Innovation Agency3
Nanda SaridewiSyarif Hidayatullah State Islamic University Jakarta3
Sabar Pangihutan SimanungkalitIndonesian Institute of Sciences3
Anis KristianiNational Research and Innovation Agency3
Ahmad FathoniSyarif Hidayatullah State Islamic University Jakarta2
Roni MaryanaIndonesian Institute of Sciences2
Wan Ryan AsriSriwijaya University2
Fitri HadiahSriwijaya University2
Novia NoviaSriwijaya University2
Agustino ZulysUniversity of Indonesia2
Nurhasni NurhasniSyarif Hidayatullah State Islamic University Jakarta2
Ira JayanegaraBadan Pengkajian dan Penerapan Teknologi2
Adeng HudayaSyarif Hidayatullah State Islamic University Jakarta2
Tarso RudianaUniversitas Mathla'ul Anwar Banten2
Lisa AdhaniUniversitas Bhayangkara Jakarta Raya2
Yulyani Nur AzizahSyarif Hidayatullah State Islamic University Jakarta2
Teguh WahyonoNational Nuclear Energy Agency of Indonesia1
Widhi KurniawanUniversitas Halu Oleo1
Rista Kurnia DewiSyarif Hidayatullah State Islamic University Jakarta1
Sihono SihonoNational Nuclear Energy Agency of Indonesia1
Eka Nur'azmi YuniraAfiliasi tidak diketahui1

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Sumber metadata: OAI-PMH (metadata jurnal) http://journal.uinjkt.ac.id/index.php/valensi/oai, pertama di-harvest 10 Nov 2026, terakhir terlihat 10 Nov 2026.
Metadata asli (oai_dc) 
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	<dc:title xml:lang="en">Performance of Modified Natural Zeolites by Sodium Hydroxide Treatments in The Esterification of Glycerol and Oleic Acid</dc:title>
	<dc:creator xml:lang="en">Fauzi, Rizky Achmad</dc:creator>
	<dc:creator xml:lang="en">Tursiloadi, Silvester</dc:creator>
	<dc:creator xml:lang="en">Dwiatmoko, Adid Adep</dc:creator>
	<dc:creator xml:lang="en">Sukandar, Dede</dc:creator>
	<dc:creator xml:lang="en">Aulia, Fauzan</dc:creator>
	<dc:creator xml:lang="en">Rinaldi, Nino</dc:creator>
	<dc:creator xml:lang="en">Sudiyarmanto, Sudiyarmanto</dc:creator>
	<dc:subject xml:lang="en">Esterification</dc:subject>
	<dc:subject xml:lang="en">zeolite</dc:subject>
	<dc:subject xml:lang="en">desilication</dc:subject>
	<dc:subject xml:lang="en">oleic acid</dc:subject>
	<dc:subject xml:lang="en">monoglyceride</dc:subject>
	<dc:description xml:lang="en">Esterification is the reaction of the formation of an ester compound by reacting an alcohol compound and carboxylic acid. In this study, the performance of zeolite-based catalysts has been studied for esterification reactions. Modification of zeolite pore size was done to be hierarchical zeolite, with the aim of increasing the catalytic properties of zeolite. The modification was carried out by desilication by sodium hydroxide treatment with a variation of 0.1; 0.3; 0.5 M. The resulting catalyst was then characterized using BET and XRD. Furthermore, the catalyst was tested for activity for esterification of fatty acids and glycerol and the product was analyzed using GC-MS. Zeolite modification with sodium hydroxide has been proven to improve catalyst performance, without changing their crystal structure. The best catalytic activity was obtained on the catalyst with sodium hydroxide treatment of 0.3 M, resulting glycerol conversion of 92% and selectivity to monoglycerides of 74%.</dc:description>
	<dc:publisher xml:lang="en">Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University</dc:publisher>
	<dc:date>2019-11-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.uinjkt.ac.id/index.php/valensi/article/view/9976</dc:identifier>
	<dc:identifier>10.15408/jkv.v5i2.9976</dc:identifier>
	<dc:source xml:lang="en">Jurnal Kimia Valensi; Jurnal Kimia VALENSI Volume 5, No. 2, November 2019; 236-241</dc:source>
	<dc:source>2548-3013</dc:source>
	<dc:source>2460-6065</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.uinjkt.ac.id/index.php/valensi/article/view/9976/pdf</dc:relation>
	<dc:rights xml:lang="en">Copyright (c) 2019 Rizky Achmad Fauzi, Silvester Tursiloadi, Adid Adep Dwiatmoko, Dede Sukandar, Fauzan Aulia, Nino Rinaldi, Sudiyarmanto Sudiyarmanto</dc:rights>
</oai_dc:dc>