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Photocatalytic Degradation of Methylene Blue and Methyl Orange by Y-PTC Metal-Organic Framework

VALENSI · Vol. ume No. 2 (2021) · hlm. 129–141

DOI
10.15408/jkv.v7i2.22267
ISSN
2548-3013, 2460-6065
Terbit
2021-11-23
Penerbit
Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University
Bahasa
eng

Abstrak

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.

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  • Syarif Hidayatullah State Islamic University Jakarta
  • University of Indonesia
  • Bandung Institute of Technology
  • National Research and Innovation Agency
  • Pertamina (Indonesia)
  • Badan Pengkajian dan Penerapan Teknologi
  • Jenderal Soedirman University
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Rekan penulisOrganisasiArtikel bersama
Nanda SaridewiSyarif Hidayatullah State Islamic University Jakarta13
Dede SukandarSyarif Hidayatullah State Islamic University Jakarta8
Siti NurbaytiSyarif Hidayatullah State Islamic University Jakarta8
Isalmi AzizSyarif Hidayatullah State Islamic University Jakarta6
Sri KomalaSyarif Hidayatullah State Islamic University Jakarta5
Jarnuzi GunlazuardiUniversity of Indonesia5
Muhammad Shofyan GunawanSyarif Hidayatullah State Islamic University Jakarta4
Latifah TulhusnaSyarif Hidayatullah State Islamic University Jakarta4
Rizkha FadhillaSyarif Hidayatullah State Islamic University Jakarta4
Wulandari OktaviaSyarif Hidayatullah State Islamic University Jakarta3
Farhan Maulana AzharSyarif Hidayatullah State Islamic University Jakarta3
Risma Nur FitriaSyarif Hidayatullah State Islamic University Jakarta3
Nurhasni NurhasniSyarif Hidayatullah State Islamic University Jakarta3
Selviana RustantiSyarif Hidayatullah State Islamic University Jakarta2
Uly Fitria BaleSyarif Hidayatullah State Islamic University Jakarta2
Rizka FadhillaSyarif Hidayatullah State Islamic University Jakarta2
Fitri Nur RamadhanSyarif Hidayatullah State Islamic University Jakarta2
Wahyudin WahyudinNational Research and Innovation Agency2
Rizka HadriyaniSyarif Hidayatullah State Islamic University Jakarta2
Leni AndriyaniSyarif Hidayatullah State Islamic University Jakarta2
Farhah Syahidatul MalaSyarif Hidayatullah State Islamic University Jakarta2
Nur MahrunnisaSyarif Hidayatullah State Islamic University Jakarta2
Mella DefaniaUniversity of Indonesia2
Lailatul BadriyahSyarif Hidayatullah State Islamic University Jakarta1
Wawan RustyawanPertamina (Indonesia)1
Ridla BakriUniversity of Indonesia1
Saeful RohmanBadan Pengkajian dan Penerapan Teknologi1
Shella FitriaSyarif Hidayatullah State Islamic University Jakarta1
Salman FarishiNational Research and Innovation Agency1
Yulyani Nur AzizahSyarif Hidayatullah State Islamic University Jakarta1
Puji LestariJenderal Soedirman University1
Yoki YulizarUniversity of Indonesia1
Eka Fitriani AhmadBandung Institute of Technology1
Katharina OginawatiBandung Institute of Technology1
Julinton SianturiFreie Universität Berlin1
Muhammad Miftahul MunirBandung Institute of Technology1
Anna MuawanahSyarif Hidayatullah State Islamic University Jakarta1

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Sumber metadata: OAI-PMH (metadata jurnal) http://journal.uinjkt.ac.id/index.php/valensi/oai, pertama di-harvest 10 Nov 2026, terakhir terlihat 10 Nov 2026.
Metadata asli (oai_dc) 
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en">Photocatalytic Degradation of Methylene Blue and Methyl Orange by  Y-PTC Metal-Organic Framework</dc:title>
	<dc:creator xml:lang="en">Adawiah, Adawiah</dc:creator>
	<dc:creator xml:lang="en">Yudhi, Muhammad Derry Luthfi</dc:creator>
	<dc:creator xml:lang="en">Zulys, Agustino</dc:creator>
	<dc:subject xml:lang="en">Metal-organic framework</dc:subject>
	<dc:subject xml:lang="en">yttrium-perylene</dc:subject>
	<dc:subject xml:lang="en">methylene blue</dc:subject>
	<dc:subject xml:lang="en">methyl orange</dc:subject>
	<dc:description xml:lang="en">The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.</dc:description>
	<dc:publisher xml:lang="en">Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University</dc:publisher>
	<dc:date>2021-11-23</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.uinjkt.ac.id/index.php/valensi/article/view/22267</dc:identifier>
	<dc:identifier>10.15408/jkv.v7i2.22267</dc:identifier>
	<dc:source xml:lang="en">Jurnal Kimia Valensi; Jurnal Kimia VALENSI Volume 7, No. 2, November 2021; 129-141</dc:source>
	<dc:source>2548-3013</dc:source>
	<dc:source>2460-6065</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.uinjkt.ac.id/index.php/valensi/article/view/22267/pdf</dc:relation>
	<dc:rights xml:lang="en">Copyright (c) 2021 Agustino Zulys</dc:rights>
</oai_dc:dc>