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Application of PAN/α-Fe2O3-Bentonite as A Photocatalytic Membrane for The Photodegradation of Methylene Blue

VALENSI · Vol. ume No. 1 (2023) · hlm. 22–29

DOI
10.15408/jkv.v9i1.28635
ISSN
2548-3013, 2460-6065
Terbit
2023-05-31
Penerbit
Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University
Bahasa
eng

Abstrak

The intricate molecular structure of the dyes in wastewater makes it difficult to biodegrade, which could harm the environment. Currently, semiconductor-based photocatalytic methods are being developed to remove dyes from water. In this study, the α-Fe2O3-bentonite photocatalyst was synthesized by mechanical milling and immobilized in polyacrylonitrile (PAN) membrane by phase inversion. Analysis of the composition and surface morphology of the synthesized samples was carried out by FTIR, XRD, and EDX. The performance of the photocatalytic membrane was studied by investigating the removal of methylene blue (MB). Photocatalytic membrane with 2% α-Fe2O3-bentonite had the best performance in removing MB (10 ppm) that reached 99.84% at pH 11.5 with an irradiation time of 300 minutes under direct sunlight. The reuse cycle of the photocatalytic membrane was also carried out and the results showed that there is no significant change in the photodegradation efficiency after 3 cycles. Photocatalyst immobilization on PAN membranes is proven to overcome the post-recovery problem of photocatalysts and making easier to reuse. The photocatalyst membrane synthesized in this study can be used as an alternative for removing dyes from water.

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  • IPB University
  • Syarif Hidayatullah State Islamic University Jakarta
  • National Research and Innovation Agency
  • Krida Wacana Christian University
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Rekan penulisOrganisasiArtikel bersama
Purwantiningsih SugitaIPB University2
Pipih SuptijahIPB University1
Kiagus DahlanIPB University1
Anjarsari AnjarsariIPB University1
Isalmi AzizSyarif Hidayatullah State Islamic University Jakarta1
Adid Adep DwiatmokoNational Research and Innovation Agency1
Dimas AndriantoIPB University1
Dzikri Anfasa FirdausIPB University1
Siti NikmatinIPB University1
Santi PuspitasariAfiliasi tidak diketahui1
Adi CifriadiIPB University1
Asron Ferdian FalaahAfiliasi tidak diketahui1
Usman WijayaKrida Wacana Christian University1
Mala NurilmalaIPB University1
Charlena CharlenaIPB University1
Prima SohetiIPB University1

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Sumber metadata: OAI-PMH (metadata jurnal) http://journal.uinjkt.ac.id/index.php/valensi/oai, pertama di-harvest 10 Nov 2026, terakhir terlihat 10 Nov 2026.
Metadata asli (oai_dc)
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	<dc:title xml:lang="en">Application of PAN/α-Fe2O3-Bentonite as A Photocatalytic Membrane for The Photodegradation of Methylene Blue</dc:title>
	<dc:creator xml:lang="en">Sitompul, Dina Wardani</dc:creator>
	<dc:creator xml:lang="en">Kemala, Tetty</dc:creator>
	<dc:creator xml:lang="en">Darmawan, Noviyan</dc:creator>
	<dc:subject xml:lang="en">α-Fe2O3</dc:subject>
	<dc:subject xml:lang="en">bentonite</dc:subject>
	<dc:subject xml:lang="en">photocatalyst membrane</dc:subject>
	<dc:subject xml:lang="en">methylene blue</dc:subject>
	<dc:description xml:lang="en">The intricate molecular structure of the dyes in wastewater makes it difficult to biodegrade, which could harm the environment. Currently, semiconductor-based photocatalytic methods are being developed to remove dyes from water. In this study, the α-Fe2O3-bentonite photocatalyst was synthesized by mechanical milling and immobilized in polyacrylonitrile (PAN) membrane by phase inversion. Analysis of the composition and surface morphology of the synthesized samples was carried out by FTIR, XRD, and EDX. The performance of the photocatalytic membrane was studied by investigating the removal of methylene blue (MB). Photocatalytic membrane with 2% α-Fe2O3-bentonite had the best performance in removing MB (10 ppm) that reached 99.84% at pH 11.5 with an irradiation time of 300 minutes under direct sunlight. The reuse cycle of the photocatalytic membrane was also carried out and the results showed that there is no significant change in the photodegradation efficiency after 3 cycles. Photocatalyst immobilization on PAN membranes is proven to overcome the post-recovery problem of photocatalysts and making easier to reuse. The photocatalyst membrane synthesized in this study can be used as an alternative for removing dyes from water.</dc:description>
	<dc:publisher xml:lang="en">Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University</dc:publisher>
	<dc:date>2023-05-31</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.uinjkt.ac.id/index.php/valensi/article/view/28635</dc:identifier>
	<dc:identifier>10.15408/jkv.v9i1.28635</dc:identifier>
	<dc:source xml:lang="en">Jurnal Kimia Valensi; Jurnal Kimia VALENSI Volume 9, No. 1, May 2023; 22-29</dc:source>
	<dc:source>2548-3013</dc:source>
	<dc:source>2460-6065</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.uinjkt.ac.id/index.php/valensi/article/view/28635/pdf</dc:relation>
	<dc:rights xml:lang="en">Copyright (c) 2023 Dina Wardani Sitompul, Tetty Kemala, Noviyan Darmawan</dc:rights>
</oai_dc:dc>