The development of IPv6-based network architectures for Internet of Things (IoT) systems is a feasible approach to widen the horizon for more effective applications, but remains a challenge. Network routing needs to be effectively addressed in such environments of scarce computational and energy resources. The Internet Engineering Task Force (IETF) specified the IPv6 Routing Protocol for Low Power and Lossy Network (RPL) to provide a basic IPv6-based routing framework for IoT networks. However, the RPL design has the potential of extending its functionality to a further limit and incorporating the support of advanced routing mechanisms. These include multipath routing which has opened the doors for great improvements towards efficient energy balancing, load distribution, and even more. This paper fulfilled a need for an effective review of recent advancements in Internet of Things (IoT) networking. In particular, it presented an effective review and provided a taxonomy of the different multipath routing solutions enhancing the RPL protocol. The aim was to discover its current state and outline the importance of integrating such a mechanism into RPL to revive its potentiality to a wider range of IoT applications. This paper also discussed the latest research findings and provided some insights into plausible follow-up researches.