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Selective Conversion of 2-Methylfuran to 1,4-Pentanediol Catalyzed by Bimetallic Ni-Sn Alloy

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2019) · pp. 529–541

DOI
10.9767/bcrec.14.3.4347.529-541
ISSN
1978-2993
Published
2019-12-01
Publisher
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Language
eng
License
creativecommons.org/licenses/by-sa/4.0

Abstract

The selective conversion of 2-methylfuran (2-MeF) to 1,4-pentanediol (1,4-PeD) over bimetallic nickel-tin alloy catalysts in the ethanol/H2O solvent mixture was studied. By using bulk Ni-Sn(x); x = 3.0 and 1.5 catalysts, a maximum yield of 1,4-PeD (49%) was obtained at 94% conversion of 2-MeF. The dispersion of Ni-Sn(x) on the aluminium hydroxide (AlOH) or g-Al2O3 supports allowed to an outstanding yield of 1,4-PeD (up to 64%) at 433 K, 3.0 MPa of H2 within 12 h. Ni-Sn(3.0)/AlOH catalyst was found to be reusable and the treatment of the recovered Ni-Sn(3.0)/AlOH catalyst with H2 at 673 K for 1 h restored the catalyst’s original activity and selectivity.

Keywords

Collaboration network of the authors

40 authors · 96 co-authorship links · showing the 40 most connected

Hover or tap a name to highlight its co-authors. Double-click to open the author's page.

  • Sekolah Tinggi Agama Buddha Negeri Raden Wijaya Wonogiri
  • Universitas Muslim Indonesia
  • Affiliation unknown
  • Different organisations
  • Same organisation
  • Affiliation unknown
  • Thicker line = more joint articles · bigger circle = more articles
Show as table
Co-authorOrganisationJoint articles
Atina Sabila AzzahraAffiliation unknown8
Maria Dewi AstutiAffiliation unknown7
Rajif IryadiAffiliation unknown5
I Dewa Putu DarmaAffiliation unknown4
Pathur Razi AnsyahAffiliation unknown3
Eddie van EttenAffiliation unknown2
Shogo ShimazuAffiliation unknown2
Edi MikriantoAffiliation unknown2
Thea Seventina Desiani BodoiAffiliation unknown2
Gagus Ketut SunnardiantoAffiliation unknown2
Siti Fatimah HanumAffiliation unknown2
Ade Evriansyah LubisAffiliation unknown1
Ramadan GintingAffiliation unknown1
Mawardinur MawardinurAffiliation unknown1
Dinni Khairiah SipayungAffiliation unknown1
Devi Catur WinataAffiliation unknown1
Muhammad SyalehAffiliation unknown1
M.Or, MawardinurAffiliation unknown1
Pedo Manta KeliatAffiliation unknown1
Boby HelmiAffiliation unknown1
Rinaldi AdityaAffiliation unknown1
Yitiman TelaumbanuaAffiliation unknown1
Hardodi SihombingAffiliation unknown1
Sutrisno SutrisnoSekolah Tinggi Agama Buddha Negeri Raden Wijaya Wonogiri1
Aries MusnandarAffiliation unknown1
Diaya Uddeen Deab Mahmoud AlzitawiAffiliation unknown1
Heri YudionoAffiliation unknown1
Amalia HasnawatiAffiliation unknown1
Arsi Ciptaning TyasAffiliation unknown1
Risky Aji Yudha WiratamaAffiliation unknown1
Sulastri SulastriUniversitas Muslim Indonesia1
Oman SukmanaAffiliation unknown1
Anang KadarsahAffiliation unknown1
Dafiuddin SalimAffiliation unknown1
Marta DinataAffiliation unknown1

Affiliations come from OpenAlex; journal OAI-PMH metadata carries none. Authors without an OpenAlex ID are matched by name, which can merge or split people.

Metadata source: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, first harvested 8 Nov 2026, last seen 8 Nov 2026.
Original metadata (oai_dc) 
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	<dc:title xml:lang="en-US">Selective Conversion of 2-Methylfuran to 1,4-Pentanediol Catalyzed by Bimetallic Ni-Sn Alloy</dc:title>
	<dc:creator>Rodiansono, Rodiansono</dc:creator>
	<dc:creator>Maria Dewi, Astuti</dc:creator>
	<dc:creator>Husain, Sadang</dc:creator>
	<dc:creator>Nugroho, Agung</dc:creator>
	<dc:creator>Sutomo, Sutomo</dc:creator>
	<dc:subject xml:lang="en-US">Ni-Sn alloy catalysts; selective conversion; 2-methylfuran; 1,4-pentanediol; 2-methyltetrahydrofuran</dc:subject>
	<dc:description xml:lang="en-US">The selective conversion of 2-methylfuran (2-MeF) to 1,4-pentanediol (1,4-PeD) over bimetallic nickel-tin alloy catalysts in the ethanol/H2O solvent mixture was studied. By using bulk Ni-Sn(x); x = 3.0 and 1.5 catalysts, a maximum yield of 1,4-PeD (49%) was obtained at 94% conversion of 2-MeF. The dispersion of Ni-Sn(x) on the aluminium hydroxide (AlOH) or g-Al2O3 supports allowed to an outstanding yield of 1,4-PeD (up to 64%) at 433 K, 3.0 MPa of H2 within 12 h. Ni-Sn(3.0)/AlOH catalyst was found to be reusable and the treatment of the recovered Ni-Sn(3.0)/AlOH catalyst with H2 at 673 K for 1 h restored the catalyst’s original activity and selectivity. </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US">JSPS-DGHE through Joint Bilateral Research Project FY 2014-2017, KLN and International Publication Project of DGHE FY 2015-2016 under grant number of DIPA-023-04.1.673453/2016, and Penelitian Berbasis Kompetensi (PBK) FY 2017-2018 under grant number of DI</dc:contributor>
	<dc:date>2019-12-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/4347</dc:identifier>
	<dc:identifier>10.9767/bcrec.14.3.4347.529-541</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019); 529-541</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/4347/2636</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2019 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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