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Polyoxometalate Intercalated M2+/Al (M2+=Ni, Mg) Layered Double Hydroxide for Degradation of Methylene Blue

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2023) · pp. 210–221

DOI
10.9767/bcrec.17789
ISSN
1978-2993
Published
2023-07-30
Publisher
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Language
eng
License
creativecommons.org/licenses/by-sa/4.0

Abstract

The synthesis and characterization of M2+/Al (M2+=Ni, Mg) layered double hydroxide (LDH) and intercalated polyoxometalate is presented. We have reported the growth of polyoxometalate on Ni/Mg layered double hydroxide for degradation methylene blue (MB). By considering variables such as pH of dye solution, dye concentration, and time as degradation variables, the efficiency of organic dye degradation and degradation parameters of M2+/Al (M2+ = Ni, Mg) LDH and both composite LDH-polyoxometalate has been identified. X-Ray Diffraction (XRD), Fourier Transform Infra Red (FTIR), Scanning Electron Microscope (SEM), and Ultra Violet Diffuse Reflectance Spectroscopy (UV-DRS) spectroscopy confirmed the layered double hydroxide structure. XRD and FTIR analysis confirmed the single-phase of the as-made and polyoxometalate intercalated LDH. SEM images show the formation of aggregates of small various sizes. The material’s photodegradation was assessed through methylene blue (MB) degradation process. The result showed that NiAl-Si has a good degradation capacity for MB as compared to NiAl-Pw, MgAl-Si, and MgAl-PW. The result shows that LDH composite presents stability and has good photocatalytic activities toward the reduction of methylene blue. The FTIR measurement confirming the LDH composite structure reveals the materials used in the fifth regeneration. The activity of MB photodegradation pristine were NiAl (45%), MgAl (43%), NiAl-Pw (78%), NiAl-Si (85%), MgAl-Pw (58%), and MgAl-Si (75%), respectively. The LDH-polyoxometalate composite material’s capacity to successfully photodegrade, as measured by the percentage of degradation, revealed an increase in photodegradation catalysis and the ability of the LDH to regenerate. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Keywords

Collaboration network of the authors

40 authors · 159 co-authorship links · 6 across different organisations · showing the 40 most connected

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  • Sriwijaya University
  • Politeknik Kesehatan Kementerian Kesehatan Palembang
  • Universitas Palembang
  • Affiliation unknown
  • Different organisations
  • Same organisation
  • Affiliation unknown
  • Thicker line = more joint articles · bigger circle = more articles
Show as table
Co-authorOrganisationJoint articles
Neza Rahayu PalapaSriwijaya University21
Alfan WijayaSriwijaya University18
Amri AmriSriwijaya University15
Tarmizi TaherSriwijaya University12
Idha RoyaniSriwijaya University12
Nova YuliasariSriwijaya University9
Sahrul WibiyanSriwijaya University8
Patimah Mega Syah Bahar Nur SiregarSriwijaya University7
Muhammad SaidSriwijaya University5
Novie JuleantiSriwijaya University5
Arini Fousty BadriSriwijaya University5
Fitri Suryani ArsyadSriwijaya University5
Rohmatullaili RohmatullailiSriwijaya University5
Najma Annuria FithriSriwijaya University4
NormahSriwijaya University4
Eliza ElizaSriwijaya University4
Hilda ZulkifliSriwijaya University3
Yusuf Mathiinul HakimSriwijaya University3
Normah NormahSriwijaya University2
Maksuk MaksukPoliteknik Kesehatan Kementerian Kesehatan Palembang2
Tan MalakaSriwijaya University2
Abu UmayahSriwijaya University2
Elfita ElfitaSriwijaya University2
Zaqiya Artha ZaharaSriwijaya University2
Rahma Dinta AstutiSriwijaya University2
Hermansyah HermansyahSriwijaya University2
W WartonoAffiliation unknown1
RA SuwignyoSriwijaya University1
A NapoleonAffiliation unknown1
Haris KriswantoroUniversitas Palembang1
Benyamin LakitanSriwijaya University1
Andi WijayaSriwijaya University1
Laila HanumSriwijaya University1
Elda MelwitaSriwijaya University1

Affiliations come from OpenAlex; journal OAI-PMH metadata carries none. Authors without an OpenAlex ID are matched by name, which can merge or split people.

Metadata source: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, first harvested 8 Nov 2026, last seen 8 Nov 2026.
Original metadata (oai_dc) 
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	<dc:title xml:lang="en-US">Polyoxometalate Intercalated M2+/Al (M2+=Ni, Mg) Layered Double Hydroxide for Degradation of Methylene Blue</dc:title>
	<dc:creator>Hanifah, Yulizah</dc:creator>
	<dc:creator>Mohadi, Risfidian</dc:creator>
	<dc:creator>Mardiyanto, Mardiyanto</dc:creator>
	<dc:creator>Ahmad, Nur</dc:creator>
	<dc:creator>Suheryanto, Suheryanto</dc:creator>
	<dc:creator>Lesbani, Aldes</dc:creator>
	<dc:subject xml:lang="en-US">LDH; LDH-polyoxometalate; photocatalyst; methylene blue</dc:subject>
	<dc:description xml:lang="en-US">The synthesis and characterization of M2+/Al (M2+=Ni, Mg) layered double hydroxide (LDH) and intercalated polyoxometalate is presented. We have reported the growth of polyoxometalate on Ni/Mg layered double hydroxide for degradation methylene blue (MB). By considering variables such as pH of dye solution, dye concentration, and time as degradation variables, the efficiency of organic dye degradation and degradation parameters of M2+/Al (M2+ = Ni, Mg) LDH and both composite LDH-polyoxometalate has been identified. X-Ray Diffraction (XRD), Fourier Transform Infra Red (FTIR), Scanning Electron Microscope (SEM), and Ultra Violet Diffuse Reflectance Spectroscopy (UV-DRS) spectroscopy confirmed the layered double hydroxide structure. XRD and FTIR analysis confirmed the single-phase of the as-made and polyoxometalate intercalated LDH. SEM images show the formation of aggregates of small various sizes. The material’s photodegradation was assessed through methylene blue (MB) degradation process. The result showed that NiAl-Si has a good degradation capacity for MB as compared to NiAl-Pw, MgAl-Si, and MgAl-PW. The result shows that LDH composite presents stability and has good photocatalytic activities toward the reduction of methylene blue. The FTIR measurement confirming the LDH composite structure reveals the materials used in the fifth regeneration. The activity of MB photodegradation pristine were NiAl (45%), MgAl (43%), NiAl-Pw (78%), NiAl-Si (85%), MgAl-Pw (58%), and MgAl-Si (75%), respectively. The LDH-polyoxometalate composite material’s capacity to successfully photodegrade, as measured by the percentage of degradation, revealed an increase in photodegradation catalysis and the ability of the LDH to regenerate. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2023-07-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/17789</dc:identifier>
	<dc:identifier>10.9767/bcrec.17789</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2023: BCREC Volume 18 Issue 2 Year 2023 (August 2023); 210-221</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/17789/8856</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2023 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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