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Kinetic and Thermodynamics of Methylene Blue Adsorption onto Zero Valent Iron Supported on Mesoporous Silica

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2016) · pp. 250–261

DOI
10.9767/bcrec.11.2.443.250-261
ISSN
1978-2993
Published
2016-08-20
Publisher
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Language
eng
License
creativecommons.org/licenses/by-sa/4.0

Abstract

Zero valent iron supported on mesoporous silicanano particles (NZVI/MSNs) was prepared by the aqueous phase borohydride reduction methods. Prior to the reduction, mesoporous silica nanoparticles (MSNs) were prepared through the activation of fumed silica with concentrated HCl by refluxing at 90 °C. FTIR, XRD, FESEM, EDX and BET were used to characterize theadsorbents prepared. BET surface areas of MSNs, NZVI, and NZVI/MSNs were 126, 41, and 72 m2/g for, respectively. The performance of NZVI/MSNs as adsorbent was examined by adsorption of methylene blue (MB), performed in series of batch experiments. In the kinetic studies, pseudo first order and pseudo second order kinetic models were examined. The pseudo second order equation provided the best fit with the experimental data. Thermodynamic studies indicated that the adsorption process is endothermic with ΔH° was 90.53 kJ/mol. Positive ΔS° (300 J/mol) and negative ΔG° (-6.42 kJ/mol) was recorded, indicating the spontaneous of the adsorption process and naturally favorable.

Keywords

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19 authors · 72 co-authorship links

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Co-authorOrganisationJoint articles
Dedy KurniantoAffiliation unknown2
Tia ErfiantiAffiliation unknown2
Rehan Zainol AbidinAffiliation unknown1
Gaanty Pragas ManiamAffiliation unknown1
Eko Agus SuyonoAffiliation unknown1
Ria AmeliaAffiliation unknown1
Witia ArdipeniAffiliation unknown1
Na’imatul MufidaAffiliation unknown1
Siti MudrikahAffiliation unknown1
Renata Adaranyssa Egistha PutriAffiliation unknown1
Arief BudimanAffiliation unknown1
Eko Agus SuyonoAffiliation unknown1
Brilian Ryan SadewoAffiliation unknown1
Khalid Erlangga KarilanataAffiliation unknown1

Affiliations come from OpenAlex; journal OAI-PMH metadata carries none. Authors without an OpenAlex ID are matched by name, which can merge or split people.

Metadata source: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, first harvested 8 Nov 2026, last seen 8 Nov 2026.
Original metadata (oai_dc) 
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	<dc:title xml:lang="en-US">Kinetic and Thermodynamics of Methylene Blue Adsorption onto Zero Valent Iron Supported on Mesoporous Silica</dc:title>
	<dc:creator>Hameed, Atyaf Khalid</dc:creator>
	<dc:creator>Dewayanto, Nugroho</dc:creator>
	<dc:creator>Dongyun, Du</dc:creator>
	<dc:creator>Nordin, Mohd Ridzuan</dc:creator>
	<dc:creator>Ab Rahim, Mohd Hasbi</dc:creator>
	<dc:subject xml:lang="en-US">Zero valent iron; Adsorption kinetics, Adsorption Thermodynamics; Methylene blue; Mesoporous silica</dc:subject>
	<dc:description xml:lang="en-US">Zero valent iron supported on mesoporous silicanano particles (NZVI/MSNs) was prepared by the aqueous phase borohydride reduction methods. Prior to the reduction, mesoporous silica nanoparticles (MSNs) were prepared through the activation of fumed silica with concentrated HCl by refluxing at 90 °C. FTIR, XRD, FESEM, EDX and BET were used to characterize theadsorbents prepared. BET surface areas of MSNs, NZVI, and NZVI/MSNs were 126, 41, and 72 m2/g for, respectively. The performance of NZVI/MSNs as adsorbent was examined by adsorption of methylene blue (MB), performed in series of batch experiments. In the kinetic studies, pseudo first order and pseudo second order kinetic models were examined. The pseudo second order equation provided the best fit with the experimental data. Thermodynamic studies indicated that the adsorption process is endothermic with ΔH° was 90.53 kJ/mol. Positive ΔS° (300 J/mol) and negative ΔG° (-6.42 kJ/mol) was recorded, indicating the spontaneous of the adsorption process and naturally favorable. </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US"></dc:contributor>
	<dc:date>2016-08-20</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/443</dc:identifier>
	<dc:identifier>10.9767/bcrec.11.2.443.250-261</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2016: BCREC Volume 11 Issue 2 Year 2016 (August 2016); 250-261</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/443/433</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2016 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>