Melola Discovery

← Melola Discovery

Akses terbuka Jurnal SINTA 1

Catalytic Performance of Cu-Ni supported on Rice Husk Ash-derived SiO2 for the Hydrogenation of Ethylene Carbonate to Ethylene Glycol

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2025) · hlm. 89–98

DOI
10.9767/bcrec.20336
ISSN
1978-2993
Terbit
2025-04-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Ethylene glycol, a crucial compound extensively utilized in solvents, coolants, antifreeze, polyester fiber production, and as a natural gas-drying agent, can be synthesized via the hydrogenation of ethylene carbonate. In this study, the synthesis, characterization, and catalytic performance of Cu-Ni/SiO2 catalysts for this reaction, utilizing silica (SiO2) derived from rice husk ash, were investigated. Silica was impregnated with copper (Cu) and nickel (Ni) by varying the weight ratio (Cu:Ni = 10, 7:3, 3:7, 10) to prepare bimetallic catalysts. X-ray Diffraction (XRD) analysis confirmed the presence of both Cu and Ni phases in all the catalysts. The 3Cu7Ni/SiO2 catalyst displayed the lowest reduction temperature and the largest surface area (257.97 m²/g). The 7Cu3Ni/SiO2 catalyst exhibited the highest acidity (1.91 mmol/g) and superior metal dispersion, as confirmed by the Field Emission Scanning Electron Microscopy - Energy Dispersive X-Ray (FE-SEM-EDX) analysis. Catalytic activity was evaluated in a batch reactor under 40 bar H2 pressure at 150 °C for 3 h with a catalyst-to-ethylene carbonate ratio of 5:1. Among the catalysts examined, the 7Cu-3Ni/SiO2 composition demonstrated the highest catalytic performance, achieving 15.14% conversion of ethylene carbonate and 80.51% selectivity towards ethylene glycol. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Kata kunci

Jaringan kolaborasi para penulis

40 penulis · 160 tautan kepenulisan bersama · 1 lintas organisasi · menampilkan 40 yang paling banyak terhubung

Arahkan kursor atau ketuk sebuah nama untuk menyorot rekan penulisnya. Klik dua kali untuk membuka halaman penulis.

  • Universitas Hasyim Asy'ari
  • Tadulako University
  • Sebelas Maret University
  • Syarif Hidayatullah State Islamic University Jakarta
  • National Research and Innovation Agency
  • Hasanuddin University
  • Universitas Balikpapan
  • Organisasi lain
  • Afiliasi tidak diketahui
  • Organisasi berbeda
  • Organisasi sama
  • Afiliasi tidak diketahui
  • Garis lebih tebal = lebih banyak artikel bersama · lingkaran lebih besar = lebih banyak artikel
Tampilkan sebagai tabel
Rekan penulisOrganisasiArtikel bersama
Siti NurbaytiAfiliasi tidak diketahui13
Lisa AdhaniAfiliasi tidak diketahui7
Muhammad Al MuttaqiiAfiliasi tidak diketahui7
Nanda SaridewiAfiliasi tidak diketahui6
Adawiah AdawiahAfiliasi tidak diketahui4
Sudibyo SudibyoAfiliasi tidak diketahui4
Yulyani Nur AzizahAfiliasi tidak diketahui4
Hasanudin HasanudinAfiliasi tidak diketahui3
Sugeng PriyantoAfiliasi tidak diketahui3
Maja Pranata MarbunAfiliasi tidak diketahui3
Anny SulaswattyAfiliasi tidak diketahui3
Dede SukandarAfiliasi tidak diketahui3
Novia NoviaTadulako University2
Roni MaryanaAfiliasi tidak diketahui2
Wan Ryan AsriAfiliasi tidak diketahui2
Fitri HadiahAfiliasi tidak diketahui2
Abdul AzizSebelas Maret University2
Lenny MarlindaAfiliasi tidak diketahui2
Peri OktiarmiAfiliasi tidak diketahui2
Agustino ZulysAfiliasi tidak diketahui2
Nurhasni NurhasniSyarif Hidayatullah State Islamic University Jakarta2
Saeful RohmanAfiliasi tidak diketahui2
Vera PermatasariNational Research and Innovation Agency2
Muhammad RidwanHasanuddin University2
Badrul UlumAfiliasi tidak diketahui2
Hendrawati HendrawatiAfiliasi tidak diketahui2
Savitri SavitriAfiliasi tidak diketahui2
Ganjar SusiloUniversitas Balikpapan1
Sigit PriatmokoState University of Semarang1
Yeni Fitriana JayantiAfiliasi tidak diketahui1

Afiliasi berasal dari OpenAlex; metadata OAI-PMH jurnal tidak memuatnya. Penulis tanpa ID OpenAlex dicocokkan berdasarkan nama, sehingga dua orang bisa tergabung atau satu orang bisa terpisah.

Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en-US">Catalytic Performance of Cu-Ni supported on Rice Husk Ash-derived SiO2 for the Hydrogenation of Ethylene Carbonate to Ethylene Glycol</dc:title>
	<dc:creator>Maharani, Najiah Sephia</dc:creator>
	<dc:creator>Rahmawati, Novia Dwi</dc:creator>
	<dc:creator>Aziz, Isalmi</dc:creator>
	<dc:creator>Maryati, Yati</dc:creator>
	<dc:creator>Agustian, Egi</dc:creator>
	<dc:creator>Widjaya, Robert Ronal</dc:creator>
	<dc:creator>Yati, Indri</dc:creator>
	<dc:creator>Prasetyo, Joni</dc:creator>
	<dc:creator>Rinaldi, Nino</dc:creator>
	<dc:creator>Dwiatmoko, Adid Adep</dc:creator>
	<dc:subject xml:lang="en-US">Bimetallic Catalysts; Ethylene Carbonate; Ethylene Glycol; Hydrogenation; Silica</dc:subject>
	<dc:description xml:lang="en-US">Ethylene glycol, a crucial compound extensively utilized in solvents, coolants, antifreeze, polyester fiber production, and as a natural gas-drying agent, can be synthesized via the hydrogenation of ethylene carbonate. In this study, the synthesis, characterization, and catalytic performance of Cu-Ni/SiO2 catalysts for this reaction, utilizing silica (SiO2) derived from rice husk ash, were investigated. Silica was impregnated with copper (Cu) and nickel (Ni) by varying the weight ratio (Cu:Ni = 10, 7:3, 3:7, 10) to prepare bimetallic catalysts. X-ray Diffraction (XRD) analysis confirmed the presence of both Cu and Ni phases in all the catalysts. The 3Cu7Ni/SiO2 catalyst displayed the lowest reduction temperature and the largest surface area (257.97 m²/g). The 7Cu3Ni/SiO2 catalyst exhibited the highest acidity (1.91 mmol/g) and superior metal dispersion, as confirmed by the Field Emission Scanning Electron Microscopy - Energy Dispersive X-Ray (FE-SEM-EDX) analysis. Catalytic activity was evaluated in a batch reactor under 40 bar H2 pressure at 150 °C for 3 h with a catalyst-to-ethylene carbonate ratio of 5:1. Among the catalysts examined, the 7Cu-3Ni/SiO2 composition demonstrated the highest catalytic performance, achieving 15.14% conversion of ethylene carbonate and 80.51% selectivity towards ethylene glycol. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:date>2025-04-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/20336</dc:identifier>
	<dc:identifier>10.9767/bcrec.20336</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2025: BCREC Volume 20 Issue 1 Year 2025 (April 2025); 89-98</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/20336/9791</dc:relation>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/downloadSuppFile/20336/5635</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2025 by Authors, Published by BCREC Publishing Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>