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The Impact of Hydrogen Peroxide as An Oxidant for Solvent-free Liquid Phase Oxidation of Benzyl Alcohol using Au-Pd Supported Carbon and Titanium Catalysts

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2018) · pp. 373–385

DOI
10.9767/bcrec.13.2.1204.373-385
ISSN
1978-2993
Published
2018-08-01
Publisher
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Language
eng
License
creativecommons.org/licenses/by-sa/4.0

Abstract

The solvent free oxidation of benzyl alcohol was conducted employing Au and Pd supported catalysts, while utilizing hydrogen peroxide 35% (H2O2) as the oxidant, H2O2 is very cheap, mild, and an environment friendly reagent, which produced water as the only by-product. Various proportions of Au-Pd catalysts on carbon and titanium oxide activated as supports were synthesized through the use of sol immobilization catalyst synthesis technique. Characterization of the synthesized catalysts was performed using X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron Microscopy (FESEM), and Transmission Electron Microscopy (TEM). It was found that the synthesized Au-Pd/ activated carbon catalyst was beneficial for the solvent free oxidation of benzyl alcohol after its containing high surface area measuring 871 m2g-1. Analysis of the TEM data and particle dimension revealed smaller and narrower particle size of 1 wt%. Thus, the distribution of Au-Pd/C was attained. Carbon-supported bimetallic catalysts presented a higher conversion compared to catalysts that are supported titanium oxide (TiO2) for for the oxidation reaction of benzyl alcohol. It was determined that this technique was a suitable process for catalyst synthesis with high selectivity, same distribution of the particle size and activations.

Keywords

Collaboration network of the authors

40 authors · 104 co-authorship links · 6 across different organisations · showing the 40 most connected

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  • Universitas Syiah Kuala
  • University of Technology Malaysia
  • Chonnam National University
  • State University of Makassar
  • Affiliation unknown
  • Different organisations
  • Same organisation
  • Affiliation unknown
  • Thicker line = more joint articles · bigger circle = more articles
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Co-authorOrganisationJoint articles
Sharifah OsmanAffiliation unknown2
Norulhuda IsmailAffiliation unknown2
George Tan Geok ShimAffiliation unknown2
Bomi ShinChonnam National University1
Cut KhairunnisakUniversitas Syiah Kuala1
Rahmah JoharUniversitas Syiah Kuala1
Cut Morina ZubainurUniversitas Syiah Kuala1
Liza IndriyaniUniversitas Syiah Kuala1
Israa A. JazeelAffiliation unknown1
Attared F. HassanAffiliation unknown1
Ali AldoghachiAffiliation unknown1
Faris A. Jasim Al-DoghachiAffiliation unknown1
Surahim MohamadAffiliation unknown1
Mukhamad NurhadiAffiliation unknown1
Sin Yuan LaiAffiliation unknown1
Yubei GuoAffiliation unknown1
Chien Yong GohAffiliation unknown1
Alysa LauAffiliation unknown1
Abdulkareem Ghassan AlsultanAffiliation unknown1
Raja Mohamad Hafriz Raja ShahruzzamanAffiliation unknown1
Salmiaton AliAffiliation unknown1
Robiah YunusAffiliation unknown1
Hisyam IhsanAffiliation unknown1
Muhammad Ammar NaufalState University of Makassar1
Mohd Salleh AbuAffiliation unknown1
Rondiyah RondiyahAffiliation unknown1
Nurul ShidaAffiliation unknown1
Abdul Hakim Abd JalilAffiliation unknown1
Nor Hasniza IbrahimUniversity of Technology Malaysia1
Johari SurifUniversity of Technology Malaysia1
Low Suan EeAffiliation unknown1
Corrienna Abdul TalibAffiliation unknown1
Mohamad Ikram ZakariaAffiliation unknown1
Nik Abdul Hadi Noor NasranAffiliation unknown1
Najua Syuhada Ahmad AlhassoraAffiliation unknown1

Affiliations come from OpenAlex; journal OAI-PMH metadata carries none. Authors without an OpenAlex ID are matched by name, which can merge or split people.

Metadata source: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, first harvested 8 Nov 2026, last seen 8 Nov 2026.
Original metadata (oai_dc) 
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	<dc:title xml:lang="en-US">The Impact of Hydrogen Peroxide as An Oxidant for Solvent-free Liquid Phase Oxidation of Benzyl Alcohol using Au-Pd Supported Carbon and Titanium Catalysts</dc:title>
	<dc:creator>Sanaa Tareq, Sarhan</dc:creator>
	<dc:creator>Saiman, Mohd. Izham</dc:creator>
	<dc:creator>Yun Hin, Taufiq-Yap</dc:creator>
	<dc:creator>Abdullah, Abdul Halim</dc:creator>
	<dc:creator>Rashid, Umer</dc:creator>
	<dc:subject xml:lang="en-US">Benzyl Alcohol; Solvent Free Oxidation; Hydrogen Peroxide; Palladium and Gold Supported Catalyst</dc:subject>
	<dc:description xml:lang="en-US">The solvent free oxidation of benzyl alcohol was conducted employing Au and Pd supported catalysts, while utilizing hydrogen peroxide 35% (H2O2) as the oxidant, H2O2 is  very cheap, mild, and an environment friendly reagent, which produced water as the only by-product. Various proportions of Au-Pd catalysts on carbon and titanium oxide activated as supports were synthesized through the use of sol immobilization catalyst synthesis technique. Characterization of the synthesized catalysts was performed using X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron Microscopy (FESEM), and Transmission Electron Microscopy (TEM). It was found that the synthesized Au-Pd/ activated carbon catalyst was  beneficial for the solvent free oxidation of benzyl alcohol after its containing high surface area measuring 871 m2g-1. Analysis of the TEM data and particle dimension revealed smaller and narrower particle size of 1 wt%. Thus, the distribution of Au-Pd/C was attained. Carbon-supported bimetallic catalysts presented a higher conversion compared to catalysts that are supported titanium oxide (TiO2) for for the oxidation reaction of benzyl alcohol. It was determined that this technique was a suitable process for catalyst synthesis with high selectivity, same distribution of the particle size and activations. </dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US">Universiti Putra Malaysia</dc:contributor>
	<dc:date>2018-08-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/1204</dc:identifier>
	<dc:identifier>10.9767/bcrec.13.2.1204.373-385</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2018: BCREC Volume 13 Issue 2 Year 2018 (August 2018); 373-385</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/1204/1518</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2018 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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