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Catalytic Activities of Fe3+- and Zn2+-Natural Zeolite on the Direct Cyclisation-Acetylation of (R)-(+)-Citronellal

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2014) · pp. 128–135

DOI
10.9767/bcrec.9.2.5936.128-135
ISSN
1978-2993
Published
2014-08-30
Publisher
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Language
eng
License
creativecommons.org/licenses/by-sa/4.0

Abstract

Characterisation and catalytic ativities investigation of modified natural zeolite on cyclisation acetylation reaction of (R)-(+)-citronellal was performed. The experimental work involved isolation of (R)-(+)-citronellal from Java Citronella oil (Cymbopogon winterianus) by vacuum fractional distillation, determination of its enantiomer, preparation and characterisation of different catalysts i.e. H-natural zeolite (H-Za), Fe3+-natural zeolite (Fe3+-Za), and Zn2+-natural zeolite (Zn2+-Za), followed by examination of catalytic activity and selectivity. Isolated citronellal contained 88.21% ee of (R)-(+)-citronellal. The main products of cyclisation-acetylation of (R)-(+)-citronellal was IPA (isopulegyl acetate) and NIPA (neo-isopulegyl acetate). Although the highest yield of IPA and NIPA was obtained by Fe3+-Za catalyst (78.69%) at 80oC and 120 min, the stereoselectivity of Fe3+-Za slightly lower than that of Zn2+-Za. Structure elucidation of citronellal and products was carried out by means of GC and GC-MS. Lewis acidity plays the role of acetyl ionic formation from acetic anhydride. The Activity and stereoselectivity of catalysts depended on Lewis acidity and cation distribution on the catalyst surface. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

Keywords

Collaboration network of the authors

40 authors · 146 co-authorship links · 8 across different organisations · showing the 40 most connected

Hover or tap a name to highlight its co-authors. Double-click to open the author's page.

  • State University of Semarang
  • Universitas Sains Al-Qur'an
  • University of Mataram
  • Universiti Sains Islam Malaysia
  • Affiliation unknown
  • Different organisations
  • Same organisation
  • Affiliation unknown
  • Thicker line = more joint articles · bigger circle = more articles
Show as table
Co-authorOrganisationJoint articles
Wega TrisunaryantiAffiliation unknown11
Yuli Prasetyo AdhiAffiliation unknown5
Nanik WijayatiState University of Semarang5
Eko Budi SusatyoAffiliation unknown4
Woro SumarniState University of Semarang4
Muhyidin MuhyidinUniversity of Mataram4
Kusoro SiadiAffiliation unknown4
Supartono SupartonoAffiliation unknown4
Sudarmin SudarminAffiliation unknown4
Dante AlighiriState University of Semarang3
Endang SusilaningsihState University of Semarang3
Sri MursitiAffiliation unknown3
Dyah Ayu FatmawatiAffiliation unknown3
Tri HandayaniAffiliation unknown2
Nugrahaningsih WHAffiliation unknown2
Saffanah Binti Mohd Ab AzidAffiliation unknown2
Adrian Maulana ZakyAffiliation unknown2
Sabila AisyahAffiliation unknown2
Bella PermatasariAffiliation unknown2
Dyah Rini IndriyantiAffiliation unknown2
Tjahyo SubrotoAffiliation unknown2
Ersanghono KusumoAffiliation unknown2
Harjono HarjonoAffiliation unknown2
Bowo NurcahyoAffiliation unknown2
Murbangun NuswowatiState University of Semarang2
Sri HaryaniAffiliation unknown2
Nur RahmawatiAffiliation unknown2
Cahyarani ParamestiAffiliation unknown2
Savitri LarasatiAffiliation unknown2
Nugroho Raka SantosoAffiliation unknown2
Endah SuarsihAffiliation unknown2
Sri JuminiUniversitas Sains Al-Qur'an1
Sutikno MadnasriState University of Semarang1
Yatim Md NadrahUniversiti Sains Islam Malaysia1
H HamzahAffiliation unknown1
F FatiatunUniversitas Sains Al-Qur'an1

Affiliations come from OpenAlex; journal OAI-PMH metadata carries none. Authors without an OpenAlex ID are matched by name, which can merge or split people.

Metadata source: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, first harvested 8 Nov 2026, last seen 8 Nov 2026.
Original metadata (oai_dc) 
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	<dc:title xml:lang="en-US">Catalytic Activities of Fe3+- and Zn2+-Natural Zeolite on the Direct Cyclisation-Acetylation of (R)-(+)-Citronellal</dc:title>
	<dc:creator>Cahyono, Edy</dc:creator>
	<dc:creator>Muchalal, M.</dc:creator>
	<dc:creator>Triyono, Triyono</dc:creator>
	<dc:creator>Pranowo, Harno Dwi</dc:creator>
	<dc:subject xml:lang="en-US">(R)-(+)-citronellal; isopulegyl acetate; Fe3+ and Zn2+-natural zeolite</dc:subject>
	<dc:description xml:lang="en-US">Characterisation and catalytic ativities investigation of modified natural zeolite on cyclisation acetylation reaction of (R)-(+)-citronellal was performed. The experimental work involved isolation of (R)-(+)-citronellal from Java Citronella oil (Cymbopogon winterianus) by vacuum fractional distillation, determination of its enantiomer, preparation and characterisation of different catalysts i.e. H-natural zeolite (H-Za), Fe3+-natural zeolite (Fe3+-Za), and Zn2+-natural zeolite (Zn2+-Za), followed by examination of catalytic activity and selectivity. Isolated citronellal contained 88.21% ee of (R)-(+)-citronellal. The main products of cyclisation-acetylation of (R)-(+)-citronellal was IPA (isopulegyl acetate) and NIPA (neo-isopulegyl acetate). Although the highest yield of IPA and NIPA was obtained by Fe3+-Za catalyst (78.69%) at 80oC and 120 min, the stereoselectivity of Fe3+-Za slightly lower than that of Zn2+-Za. Structure elucidation of citronellal and products was carried out by means of GC and GC-MS. Lewis acidity plays the role of acetyl ionic formation from acetic anhydride. The Activity and stereoselectivity of catalysts depended on Lewis acidity and cation distribution on the catalyst surface. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)</dc:description>
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	<dc:date>2014-08-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
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	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/19456</dc:identifier>
	<dc:identifier>10.9767/bcrec.9.2.5936.128-135</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2014: BCREC Volume 9 Issue 2 Year 2014 (August 2014); 128-135</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/19456/9364</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2014 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
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