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Catalytic Activities of Fe3+- and Zn2+-Natural Zeolite on the Direct Cyclisation-Acetylation of (R)-(+)-Citronellal

Bulletin of Chemical Reaction Engineering & Catalysis · Vol. ume (2014) · hlm. 128–135

DOI
10.9767/bcrec.9.2.5936.128-135
ISSN
1978-2993
Terbit
2014-08-30
Penerbit
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Bahasa
eng
Lisensi
creativecommons.org/licenses/by-sa/4.0

Abstrak

Characterisation and catalytic ativities investigation of modified natural zeolite on cyclisation acetylation reaction of (R)-(+)-citronellal was performed. The experimental work involved isolation of (R)-(+)-citronellal from Java Citronella oil (Cymbopogon winterianus) by vacuum fractional distillation, determination of its enantiomer, preparation and characterisation of different catalysts i.e. H-natural zeolite (H-Za), Fe3+-natural zeolite (Fe3+-Za), and Zn2+-natural zeolite (Zn2+-Za), followed by examination of catalytic activity and selectivity. Isolated citronellal contained 88.21% ee of (R)-(+)-citronellal. The main products of cyclisation-acetylation of (R)-(+)-citronellal was IPA (isopulegyl acetate) and NIPA (neo-isopulegyl acetate). Although the highest yield of IPA and NIPA was obtained by Fe3+-Za catalyst (78.69%) at 80oC and 120 min, the stereoselectivity of Fe3+-Za slightly lower than that of Zn2+-Za. Structure elucidation of citronellal and products was carried out by means of GC and GC-MS. Lewis acidity plays the role of acetyl ionic formation from acetic anhydride. The Activity and stereoselectivity of catalysts depended on Lewis acidity and cation distribution on the catalyst surface. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

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  • State University of Semarang
  • Universitas Sains Al-Qur'an
  • University of Mataram
  • Universiti Sains Islam Malaysia
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Rekan penulisOrganisasiArtikel bersama
Wega TrisunaryantiAfiliasi tidak diketahui11
Yuli Prasetyo AdhiAfiliasi tidak diketahui5
Nanik WijayatiState University of Semarang5
Eko Budi SusatyoAfiliasi tidak diketahui4
Woro SumarniState University of Semarang4
Muhyidin MuhyidinUniversity of Mataram4
Kusoro SiadiAfiliasi tidak diketahui4
Supartono SupartonoAfiliasi tidak diketahui4
Sudarmin SudarminAfiliasi tidak diketahui4
Dante AlighiriState University of Semarang3
Endang SusilaningsihState University of Semarang3
Sri MursitiAfiliasi tidak diketahui3
Dyah Ayu FatmawatiAfiliasi tidak diketahui3
Tri HandayaniAfiliasi tidak diketahui2
Nugrahaningsih WHAfiliasi tidak diketahui2
Saffanah Binti Mohd Ab AzidAfiliasi tidak diketahui2
Adrian Maulana ZakyAfiliasi tidak diketahui2
Sabila AisyahAfiliasi tidak diketahui2
Bella PermatasariAfiliasi tidak diketahui2
Dyah Rini IndriyantiAfiliasi tidak diketahui2
Tjahyo SubrotoAfiliasi tidak diketahui2
Ersanghono KusumoAfiliasi tidak diketahui2
Harjono HarjonoAfiliasi tidak diketahui2
Bowo NurcahyoAfiliasi tidak diketahui2
Murbangun NuswowatiState University of Semarang2
Sri HaryaniAfiliasi tidak diketahui2
Nur RahmawatiAfiliasi tidak diketahui2
Cahyarani ParamestiAfiliasi tidak diketahui2
Savitri LarasatiAfiliasi tidak diketahui2
Nugroho Raka SantosoAfiliasi tidak diketahui2
Endah SuarsihAfiliasi tidak diketahui2
Sri JuminiUniversitas Sains Al-Qur'an1
Sutikno MadnasriState University of Semarang1
Yatim Md NadrahUniversiti Sains Islam Malaysia1
H HamzahAfiliasi tidak diketahui1
F FatiatunUniversitas Sains Al-Qur'an1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.bcrec.id/index.php/bcrec/oai, pertama di-harvest 8 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc) 
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en-US">Catalytic Activities of Fe3+- and Zn2+-Natural Zeolite on the Direct Cyclisation-Acetylation of (R)-(+)-Citronellal</dc:title>
	<dc:creator>Cahyono, Edy</dc:creator>
	<dc:creator>Muchalal, M.</dc:creator>
	<dc:creator>Triyono, Triyono</dc:creator>
	<dc:creator>Pranowo, Harno Dwi</dc:creator>
	<dc:subject xml:lang="en-US">(R)-(+)-citronellal; isopulegyl acetate; Fe3+ and Zn2+-natural zeolite</dc:subject>
	<dc:description xml:lang="en-US">Characterisation and catalytic ativities investigation of modified natural zeolite on cyclisation acetylation reaction of (R)-(+)-citronellal was performed. The experimental work involved isolation of (R)-(+)-citronellal from Java Citronella oil (Cymbopogon winterianus) by vacuum fractional distillation, determination of its enantiomer, preparation and characterisation of different catalysts i.e. H-natural zeolite (H-Za), Fe3+-natural zeolite (Fe3+-Za), and Zn2+-natural zeolite (Zn2+-Za), followed by examination of catalytic activity and selectivity. Isolated citronellal contained 88.21% ee of (R)-(+)-citronellal. The main products of cyclisation-acetylation of (R)-(+)-citronellal was IPA (isopulegyl acetate) and NIPA (neo-isopulegyl acetate). Although the highest yield of IPA and NIPA was obtained by Fe3+-Za catalyst (78.69%) at 80oC and 120 min, the stereoselectivity of Fe3+-Za slightly lower than that of Zn2+-Za. Structure elucidation of citronellal and products was carried out by means of GC and GC-MS. Lewis acidity plays the role of acetyl ionic formation from acetic anhydride. The Activity and stereoselectivity of catalysts depended on Lewis acidity and cation distribution on the catalyst surface. © 2014 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)</dc:description>
	<dc:publisher xml:lang="en-US">Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)</dc:publisher>
	<dc:contributor xml:lang="en-US"></dc:contributor>
	<dc:date>2014-08-30</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US"></dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.bcrec.id/index.php/bcrec/article/view/19456</dc:identifier>
	<dc:identifier>10.9767/bcrec.9.2.5936.128-135</dc:identifier>
	<dc:source xml:lang="en-US">Bulletin of Chemical Reaction Engineering &amp; Catalysis; 2014: BCREC Volume 9 Issue 2 Year 2014 (August 2014); 128-135</dc:source>
	<dc:source>1978-2993</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.bcrec.id/index.php/bcrec/article/view/19456/9364</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2014 by Authors, Published by BCREC Group</dc:rights>
	<dc:rights xml:lang="en-US">https://creativecommons.org/licenses/by-sa/4.0</dc:rights>
</oai_dc:dc>