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Cerium, Neodimium, and Lanthanum Leaching from Rare Earth Oxides (REO) using Hydrochloric Acid

Indonesian Journal of Chemical Science · Vol. 10 No. 2 (2021) · hlm. 82–87

DOI
10.15294/ijcs.v10i2.45818
ISSN
2502-6844, 2252-6951
Terbit
2021-09-01
Penerbit
Universitas Negeri Semarang
Bahasa
eng

Abstrak

Rare earth metal hydroxide (REOH) is a mixture of the elements lanthanide, yttrium, and scandium produced from the processing of monazite sand. This mixture has benefits in the modern technology industry, especially elements of Ce, La, and Nd. Separation of Ce, La, and Nd from the mixture has been carried out, but it has several drawbacks with the large use of chemicals that have an impact on the environment from the results of their processing waste and the length of time it takes, so the best solution is needed to overcome it. The perfect solution in the process of separating Ce, La, and Nd from REOH is leaching. Leaching is the extraction of acids with bases to form salt and water. This research begins with the REOH calcination process at a temperature of 1000⁰ C for 2 hours to evaporate volatiles and decompose the compounds. The results of calcination were leached using hydrochloric acid with a concentration variation of 0.3-1.2 M, temperature 30-75 ° C, a ratio of REO and solvent 1:5, and time variation of 5-20 minutes to optimize leaching efficiency. The results of leaching in residues were analyzed by XRF. The optimum leaching of the variation of the concentration of hydrochloric acid 1,2 M for 20 minutes resulted in the leaching efficiency of La and Nd respectively 33,297% dan 26,503%, and the leaching efficiency of Ce was 10,153% of the concentration of hydrochloric acid 0,9 M for 20 minutes. At a temperature variation of 75⁰ C and a time of 10 minutes, the leaching efficiency La and Ce were 55,87% dan 0,04%, respectively. The efficiency of Nd at 45⁰C for 20 minutes was 26,93%.

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  • State University of Semarang
  • Universiti Teknologi MARA
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Rekan penulisOrganisasiArtikel bersama
F. ‪Widhi MahatmantiAfiliasi tidak diketahui4
Harjono HarjonoAfiliasi tidak diketahui3
Sri WardaniState University of Semarang3
Endang SusilaningsihState University of Semarang2
M. DhiyaulkhaqState University of Semarang1
Nanik WijayatiState University of Semarang1
Kasmui KasmuiState University of Semarang1
D. NasekhahAfiliasi tidak diketahui1
M. H. IsmailUniversiti Teknologi MARA1
Nuni WidiartiState University of Semarang1
Budi AstutiState University of Semarang1
Sungkowo SungkowoState University of Semarang1
Yuan Maylia RosantiState University of Semarang1
Rojja Maysa RohmahState University of Semarang1
Shinta HildaState University of Semarang1
Syiva Zakia AuliaState University of Semarang1
Devitri SulistyaningrumState University of Semarang1
Sri NurhayatiState University of Semarang1
Eko Budi SusatyoState University of Semarang1
Sri Susilogati SumartiState University of Semarang1
Siti NurfaijahAfiliasi tidak diketahui1
Woro SumarniAfiliasi tidak diketahui1
Sri HaryaniState University of Semarang1
Siti Marfu'ahAfiliasi tidak diketahui1
Sudarmin SudarminState University of Semarang1
Delfris Ariya Pratama LadjidjiAfiliasi tidak diketahui1
Dimas Gilang RamadhaniAfiliasi tidak diketahui1
Agung Ade YuliantoAfiliasi tidak diketahui1
Kris MassoraAfiliasi tidak diketahui1
Holifiled WidastraAfiliasi tidak diketahui1
Hoirun NisaAfiliasi tidak diketahui1
Eko Budi SusatyoAfiliasi tidak diketahui1
Aris WijayantiAfiliasi tidak diketahui1
Sukarjo SukarjoAfiliasi tidak diketahui1
Irawati IrawatiAfiliasi tidak diketahui1
Indri RakhmawatiAfiliasi tidak diketahui1
Dinar Alghifari RamadhanAfiliasi tidak diketahui1

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Sumber metadata: OAI-PMH (metadata jurnal) https://journal.unnes.ac.id/sju/index.php/ijcs/oai, pertama di-harvest 5 Nov 2026, terakhir terlihat 8 Nov 2026.
Metadata asli (oai_dc)
<oai_dc:dc xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/  http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
	<dc:title xml:lang="en-US">Cerium, Neodimium, and Lanthanum Leaching from Rare Earth Oxides (REO) using Hydrochloric Acid</dc:title>
	<dc:creator>Aulia, Muhammad Azmi</dc:creator>
	<dc:creator>Kurniawan, Cepi</dc:creator>
	<dc:creator>Setyadji, Moch.</dc:creator>
	<dc:description xml:lang="en-US">Rare earth metal hydroxide (REOH) is a mixture of the elements lanthanide, yttrium, and scandium produced from the processing of monazite sand. This mixture has benefits in the modern technology industry, especially elements of Ce, La, and Nd. Separation of Ce, La, and Nd from the mixture has been carried out, but it has several drawbacks with the large use of chemicals that have an impact on the environment from the results of their processing waste and the length of time it takes, so the best solution is needed to overcome it. The perfect solution in the process of separating Ce, La, and Nd from REOH is leaching. Leaching is the extraction of acids with bases to form salt and water. This research begins with the REOH calcination process at a temperature of 1000⁰ C for 2 hours to evaporate volatiles and decompose the compounds. The results of calcination were leached using hydrochloric acid with a concentration variation of 0.3-1.2 M, temperature 30-75 ° C, a ratio of REO and solvent 1:5, and time variation of 5-20 minutes to optimize leaching efficiency. The results of leaching in residues were analyzed by XRF. The optimum leaching of the variation of the concentration of hydrochloric acid 1,2 M for 20 minutes resulted in the leaching efficiency of La and Nd respectively 33,297% dan 26,503%, and the leaching efficiency of Ce was 10,153% of the concentration of hydrochloric acid 0,9 M for 20 minutes. At a temperature variation of 75⁰ C and a time of 10 minutes, the leaching efficiency La and Ce were 55,87% dan 0,04%, respectively. The efficiency of Nd at 45⁰C for 20 minutes was 26,93%.</dc:description>
	<dc:publisher xml:lang="en-US">Universitas Negeri Semarang</dc:publisher>
	<dc:date>2021-09-01</dc:date>
	<dc:type>info:eu-repo/semantics/article</dc:type>
	<dc:type>info:eu-repo/semantics/publishedVersion</dc:type>
	<dc:type xml:lang="en-US">Peer-reviewed Article</dc:type>
	<dc:format>application/pdf</dc:format>
	<dc:identifier>https://journal.unnes.ac.id/sju/ijcs/article/view/45818</dc:identifier>
	<dc:identifier>10.15294/ijcs.v10i2.45818</dc:identifier>
	<dc:source xml:lang="en-US">Indonesian Journal of Chemical Science; Vol 10 No 2 (2021); 82-87</dc:source>
	<dc:source>2502-6844</dc:source>
	<dc:source>2252-6951</dc:source>
	<dc:source>10.15294/ijcs.v10i2</dc:source>
	<dc:language>eng</dc:language>
	<dc:relation>https://journal.unnes.ac.id/sju/ijcs/article/view/45818/19887</dc:relation>
	<dc:rights xml:lang="en-US">Copyright (c) 2021 Indonesian Journal of Chemical Science</dc:rights>
</oai_dc:dc>